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公开(公告)号：US4883689A
公开(公告)日：1989-11-28
申请号：US267009
申请日：1988-11-04
Applicant: Peter S. Gradeff
Inventor： Peter S. Gradeff
Abstract: Described is a method of treating wood using compositions comprising an organic solution (non-aqueous solution) of one or more lanthanide derivatives. Also described is a composition comprising wood and lanthanides or lanthanide derivatives. In one embodiment, the treatment occurs under vacuum.
Abstract translation: 描述了使用包含一种或多种镧系元素衍生物的有机溶液（非水溶液）的组合物来处理木材的方法。 还描述了包含木材和镧系元素或镧系元素衍生物的组合物。 在一个实施方案中，处理发生在真空下。
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公开(公告)号：US4489000A
公开(公告)日：1984-12-18
申请号：US521787
申请日：1983-08-09
Applicant: Peter S. Gradeff , Fred G. Schreiber
Inventor： Peter S. Gradeff , Fred G. Schreiber
Abstract: A process is provided for preparing ceric alkoxides, which comprises reacting ceric ammonium nitrate with an alcohol, including a lower aliphatic alcohol, under anhydrous conditions in the presence of an anhydrous base at a temperature within the range from about -30.degree. C. to about 200.degree. C. but preferably from 0.degree. to about 150.degree. C. until ceric alkoxide and the nitrate salt of the base are formed; ceric alkoxides of higher alcohols can be prepared by transetherification of the resulting ceric alkoxide with the higher alcohol, either simultaneously or sequentially, at a temperature within the range from about -30.degree. C. to about 200.degree. C., thereby displacing the lower aliphatic alcohol and forming the ceric alkoxide of the higher alcohol, while distilling off free lower aliphatic alcohol in the course of the transetherification, to drive it towards completion; the nitrates formed during the reaction can be separated from the reaction mixture and the alkoxides isolated pure or as complexes with the alcohol, or in some cases the alkoxides can be used without separation from the reaction mixture in the presence of the nitrates.
Abstract translation: 提供了一种用于制备二氧化铈的方法，其包括在无水条件下，在无水碱存在下，在约-30℃至约约30℃的温度下，使硝酸铈铵与包括低级脂族醇在内的醇反应 200℃，但优选0℃至150℃，直到形成了铈醇盐和碱的硝酸盐; 高级醇的高级醇的烷氧基化物可以通过在约-30℃至约200℃的温度范围内同时或依次地将所得的高级醇与高级醇进行酯交换来制备，从而将低级脂族 酒精和形成高级醇的二氧化铈，同时在脱碳过程中蒸馏出游离的低级脂族醇，使其完成; 在反应过程中形成的硝酸盐可以从反应混合物中分离出来，并且醇盐被分离为纯的或与醇的复合物，或在某些情况下，在硝酸盐存在下，可以不从反应混合物中分离出醇盐。
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3.发明授权Lanthanide impregnated wood composition and method for permanently depositing water insoluble lanthanide derivatives into wood materials 失效镧系浸渍木材组合物和将水不溶性镧系元素永久沉积到木材中的方法
公开(公告)号：US4973501A
公开(公告)日：1990-11-27
申请号：US349442
申请日：1989-05-09
Applicant: Peter S. Gradeff
Inventor： Peter S. Gradeff
IPC: B27K3/32
CPC classification number: B27K3/32 , Y10T428/662
Abstract: Described is a wood composition and a method for its preparation by treating wood with a first aqueous solution comprising one or more lanthanide derivatives, optionally rinsing with water and finally treating the wood with a second aqueous solution comprising one or more bases or one or more acid salts thereby precipitating a water-insoluble lanthanide complex within the wood. In addition, the method may be practiced by reversing the order of the treatment steps.
Abstract translation: 描述了木材组合物及其制备方法，该方法通过用包含一种或多种镧系元素衍生物的第一水溶液处理木材，任选地用水漂洗，最后用包含一种或多种碱或一种或多种酸的第二水溶液处理木材 盐，从而沉淀木材中的不溶于水的镧系元素络合物。 此外，可以通过颠倒治疗步骤的顺序来实施该方法。
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4.发明授权
公开(公告)号：US4800072A
公开(公告)日：1989-01-24
申请号：US143978
申请日：1988-01-14
Applicant: Peter S. Gradeff , Fred G. Schreiber
Inventor： Peter S. Gradeff , Fred G. Schreiber
IPC: C01F17/00 , C07C31/28 , C07C215/08 , C07C215/12 , C07F7/08 , C06B1/04
CPC classification number: C07C215/12 , C01F17/0012 , C07C215/08 , C07C31/28 , C07F7/0836
Abstract: A procedure for preparing anhydrous cerous nitrate ammonium nitrate complex comprising treating dried anhydrous ceric hexanitro ammonium complex (ceric ammonium nitrate) with a reducing agent such as ammonia whereby Ce.sup.+4 is reduced to Ce.sup.+3 under anhydrous conditions. The resulting Ce.sup.+3 species, a complex of Ce.sup.+3 nitrate and ammonia nitrate, can be used as a source of anhydrous Ce.sup.+3 ions.
Abstract translation: 制备无水硝酸硝酸铵硝酸铵络合物的方法，包括用还原剂如氨处理无水硫酸铈铵络合物（硝酸铈铵），由此Ce + 4在无水条件下还原为Ce + 3。 所得到的Ce + 3物质，Ce + 3硝酸盐和硝酸铵的络合物可用作无水Ce + 3离子的来源。
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公开(公告)号：US4492655A
公开(公告)日：1985-01-08
申请号：US604756
申请日：1984-04-27
Applicant: Peter S. Gradeff , Fred G. Schreiber
Inventor： Peter S. Gradeff , Fred G. Schreiber
IPC: C07F5/00
CPC classification number: C07F5/00
Abstract: A process is provided for preparing tricyclopentadienyl cerium as well as the mono and dicyclopentadienyl cerium intermediates which comprises slowly adding alkali metal cyclopentadienide to a solution of ceric ammonium nitrate, forming, in sequence, and stepwise, monocyclopentadienyl cerium dinitrate, dicyclopentadienyl cerium mononitrate, and tricyclopentadienyl cerium.
Abstract translation: 提供了一种制备三环戊二烯基铈以及单环和二环戊二烯基铈中间体的方法，其中包括向硝酸铈铵溶液中缓慢加入环戊二烯酸碱金属，依次逐步形成单环戊二烯基二硝基硝酸铈，二环戊二烯一硝酸铈一硝酸二苯酯和三环戊二烯基 铈。
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Patent Agency Ranking6.发明授权Process for the preparation of p-hydroxy-benzyl-nitriles and corresponding amines 失效制备对羟基 - 苄基腈和相应的胺的方法
公开(公告)号：US4388250A
公开(公告)日：1983-06-14
申请号：US358397
申请日：1982-03-15
Applicant: Leon Farber , Peter S. Gradeff
Inventor： Leon Farber , Peter S. Gradeff
IPC: C07C255/53 , C07C121/75 , C07C87/28
CPC classification number: C07C255/00
Abstract: A process is provided for the preparation of p-hydroxy-benzyl-nitriles starting from the corresponding p-hydroxy-benzaldehyde, first reducing the p-hydroxy-benzaldehyde to the p-hydroxy-benzyl amine, a primary amine, with hydrogen in the presence of aqueous ammonia, preferably with the addition of small amounts of lower alkyl alcohol; and Raney nickel catalyst at low pressure; and then converting the amine to the p-hydroxy-benzyl-nitrile by reaction with sodium cyanide at elevated temperature; the first stage, the reduction, is applicable also to o- and m-hydroxy benzaldehydes.
Abstract translation: 提供从相应的对羟基 - 苯甲醛开始制备对羟基 - 苄基腈的方法，首先将对羟基苯甲醛还原成对羟基 - 苄基胺，伯胺，在 氨水的存在，优选加入少量的低级烷基醇; 和拉尼镍催化剂在低压下; 然后通过与氰化钠在升高的温度下反应将胺转化成对羟基 - 苄基腈; 第一阶段的还原也适用于邻羟基苯甲醛和间羟基苯甲醛。
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7.发明授权
公开(公告)号：US4041083A
公开(公告)日：1977-08-09
申请号：US728346
申请日：1976-09-30
Applicant: Peter S. Gradeff , Giuseppe Formica
Inventor： Peter S. Gradeff , Giuseppe Formica
IPC: C07C29/136 , B01J23/00 , B01J23/86 , B01J25/00 , B01J25/02 , C07B61/00 , C07C20060101 , C07C27/00 , C07C29/00 , C07C29/14 , C07C29/145 , C07C33/02 , C07C33/025 , C07C33/05 , C07C33/28 , C07C33/34 , C07C35/02 , C07C35/08 , C07C67/00
CPC classification number: C07C403/02 , C07C29/145 , C07C403/08 , C07C2101/14 , C07C2101/16
Abstract: A process is provided for the selective hydrogenation of the keto group of selected nonconjugated ketones in the presence of chromium-promoted Raney nickel, a strong base selected from the group consisting of alkali metal hydroxides and alcoholates, and methanol or ethanol, with, preferably, a small amount of water, and a small amount of nitrogen base, such as ammonia or an amine.
Abstract translation: 提供了在铬促进的阮内镍（选自碱金属氢氧化物和醇化物的强碱，以及甲醇或乙醇）的存在下，选择性氢化选择性非共轭酮的酮基的方法， 少量的水和少量的氮碱，如氨或胺。
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公开(公告)号：US5106959A
公开(公告)日：1992-04-21
申请号：US681832
申请日：1991-04-08
Applicant: Peter S. Gradeff , Kenan Yunlu
Inventor： Peter S. Gradeff , Kenan Yunlu
CPC classification number: C07F7/084 , C03C1/00 , C07F7/0836 , C08G18/222 , C08G77/58
Abstract: Ceric hydrocarbyl silyloxides are provided, as well as a process for preparing them, which comprises reacting ceric ammonium nitrate with a hydrocarbyl silanol, including a lower aliphatic silanol, under anhydrous conditions in the presence of an anhydrous base at a temperature within the range from about -30.degree. C. to about 200.degree. C. but preferably from 0.degree. to about 150.degree. C. until ceric hydrocarbyl silyloxide and the nitrate salt of the base are formed; the nitrates formed during the reaction can be separated from the reaction mixture and the ceric hydrocarbyl silyloxides isolated pure or as complexes with the solvent, or in some cases the ceric hydrocarbyl silyloxides can be used without separation from the reaction mixture in the presence of the nitrates.
Abstract translation: 提供了Ceric烃基甲硅烷氧基化物，以及其制备方法，其包括使硝酸铈铵与含有低级脂族硅烷醇的烃基硅烷醇在无水条件下，在无水碱存在下，在约 -30℃至约200℃，但优选0℃至约150℃，直到形成硅烷基甲硅烷基氧化物和碱的硝酸盐; 在反应过程中形成的硝酸盐可以从反应混合物中分离出来，并且分离纯的或与溶剂复合的铈烃基甲硅烷氧基，或者在某些情况下，可以在硝酸盐存在下不用分离反应混合物使用铈烃基甲硅烷氧基 。
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9.发明授权Alkoxy-type derivative compounds and process for preparing alkoxy-type derivatives of trivalent Group 3b metals 失效烷氧基衍生化合物和制备三元组3B金属的烷氧基衍生物的方法
公开(公告)号：US5099006A
公开(公告)日：1992-03-24
申请号：US280541
申请日：1988-12-08
Applicant: Peter S. Gradeff , Heiko Mauermann , Kenan Yunlu , Carlos M. Ramirez
Inventor： Peter S. Gradeff , Heiko Mauermann , Kenan Yunlu , Carlos M. Ramirez
IPC: C07C29/70 , C01F17/00 , C07C31/02 , C07C31/28 , C07C213/00 , C07C215/08 , C07C215/24 , C07F5/00 , C07F7/02 , C07F7/08
CPC classification number: C01F17/00 , C07C215/08 , C07C31/28 , C07F5/003 , C07F7/0836 , C07F7/0858 , Y02P20/582
Abstract: Alkoxy-type derivative compounds are a process for preparing alkoxy-type derivatives of trivalent Group 3b metals, e.g., cerium (III), such as alkoxides, siloxides or alkanolatoamines from an anhydrous complex of trivalent Group 3b metals, e.g. cerium ammonium nitrate complex, in the presence of an alcohol, silanol or alkanolamine and a base or by employing the complex and alkali salts of the alcohol, silanol, or alkanolamine.
Abstract translation: 烷氧基型衍生物化合物是制备三价第3b族金属的烷氧基型衍生物的方法，例如来自三价第3b族金属的无水络合物的三（III）族，例如醇盐，硅氧烷化物或链烷醇胺。 硝酸铈铵络合物，在醇，硅烷醇或链烷醇胺和碱的存在下，或通过使用醇，硅烷醇或链烷醇胺的络合物和碱金属盐。
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10.发明授权
公开(公告)号：US5017695A
公开(公告)日：1991-05-21
申请号：US128245
申请日：1987-12-03
Applicant: Peter S. Gradeff , Kenan Yunlu
Inventor： Peter S. Gradeff , Kenan Yunlu
CPC classification number: C07F7/084 , C03C1/00 , C07F7/0836 , C08G18/222 , C08G77/58
Abstract: Ceric hydrocarbyl silyloxides are provided, as well as a process for preparing them, which comprises reacting ceric ammonium nitrate with a hydrocarbyl silanol, including a lower aliphatic silanol, under anhydrous conditions in the presence of an anhydrous base at a temperature within the range from about -30.degree. C. to about 200.degree. C. but preferably from 0.degree. to about 150.degree. C. until ceric hydrocarbyl silyloxide and the nitrate salt of the base are formed; the nitrates formed during the reaction can be separated from the reaction mixture and the ceric hydrocarbyl silyloxides isolated pure or as complexes with the solvent, or in some cases the ceric hydrocarbyl silyloxides can be used without separation from the reaction mixture in the presence of the nitrates.
Abstract translation: 提供了Ceric烃基甲硅烷氧基化物，以及其制备方法，其包括使硝酸铈铵与含有低级脂族硅烷醇的烃基硅烷醇在无水条件下，在无水碱存在下，在约 -30℃至约200℃，但优选0℃至约150℃，直到形成硅烷基甲硅烷基氧化物和碱的硝酸盐; 在反应过程中形成的硝酸盐可以从反应混合物中分离出来，并且分离纯的或与溶剂复合的铈烃基甲硅烷氧基，或者在某些情况下，可以在硝酸盐存在下不用分离反应混合物使用铈烃基甲硅烷氧基 。
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