公开(公告)号：US09663612B2

公开(公告)日：2017-05-30

申请号：US14722699

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Kathy Woody ,  Hui Huang ,  Ting He ,  Wei Wang ,  Chenjun Shi ,  Yue Wu

IPC分类号： C08G75/00 ,  C08G61/12 ,  H01L51/00 ,  H01L51/42

CPC分类号： C08G61/126 ,  C08G2261/12 ,  C08G2261/1426 ,  C08G2261/1428 ,  C08G2261/146 ,  C08G2261/149 ,  C08G2261/18 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

摘要： A process of polymerizing wherein the stoichiometric ratio of (f+g)≈(h+i) and f, g, h and i are not equal to 0. Additionally, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. In addition, x and y can be different from each other and independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R7 and R8 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR9R10 where R9 and R10 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.

公开(公告)号：US09673398B2

公开(公告)日：2017-06-06

申请号：US14722774

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC分类号： C08G75/00 ,  H01L51/00 ,  H01L51/42

CPC分类号： H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

摘要： A polymer having a monomer repeat unit comprising wherein Ar is an aryl group.

公开(公告)号：US09527963B2

公开(公告)日：2016-12-27

申请号：US14722650

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC分类号： C08G75/06 ,  C07D495/04 ,  C08G61/12 ,  A61K31/4162 ,  C07B59/00

CPC分类号： C08G75/06 ,  A61K31/4162 ,  C07B59/002 ,  C07D495/04 ,  C08G61/123

摘要： A process of dissolving 3-fluoro-4,6-dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. A brominating step then occurs to the 2,3-difluorothieno[3,4-b]thiophene to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene is then debrominated and polymerized to The stoichiometric ratio of (f+g)≈h and f, g and h are not equal to 0. Additionally, in this embodiment R1, R2, R3 and R4 are independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical.

摘要翻译： 将3-氟-4,6-二氢噻吩并[3,4-b]噻吩溶解在溶剂中以产生溶液的方法。 然后将引发剂加入到溶液中以产生引发的溶液，然后向引发的溶液中加入氟化物，得到2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩。 然后用氧化剂氧化2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩，得到2,3-二氟噻吩并[3,4-b]噻吩。 然后在2,3-二氟噻吩并[3,4-b]噻吩中发生溴化步骤，生成4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩。 然后将4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩脱溴并聚合成（f + g）≈h的化学计量比，f，g和h不等于0.另外， 在该实施方案中，R 1，R 2，R 3和R 4独立地选自烷基，烷氧基，芳基及其组合，并且其中R 1，R 2，R 3和R 4的组合不完全相同。

公开(公告)号：US20150344608A1

公开(公告)日：2015-12-03

申请号：US14722864

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC分类号： C08F228/06 ,  H01L51/00

CPC分类号： C08F228/06 ,  H01L51/0036 ,  H01L51/0043 ,  Y02E10/549

摘要： A polymer having two different sets of repeat units consisting essentially of: In this polymer, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Also the combination of R1, R2, R3 and R4 are not all identical and n and o are greater than 1.

摘要翻译： 具有两个不同组的重复单元的聚合物基本上由以下组成：在该聚合物中，R 1，R 2，R 3和R 4可以独立地选自烷基，烷氧基，芳基及其组合。 R1，R2，R3和R4的组合也不完全相同，n和o大于1。

公开(公告)号：US20140151657A1

公开(公告)日：2014-06-05

申请号：US14084358

申请日：2013-11-19

申请人： Solarmer Energy, Inc. ,  Phillips 66 Company

发明人： Wei Wang ,  Chenjun Shi ,  Ruby Chen ,  Jun Yang ,  Yue Wu ,  Hui Huang ,  Kathy Woody ,  Joe Bullock ,  Amit Palkar ,  Ting He

IPC分类号： H01L51/42

CPC分类号： H01L51/0043 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

摘要： Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

摘要翻译： 呋喃，噻吩和硒吩衍生的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物的组合物，合成和应用，即聚[（4,8- （5-（2-乙基己基）硒吩-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） -3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-15），聚[（4,8-双（5-（2-乙基己基）硒吩-2-基） 1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩） （CS-16），聚[（4,8-双（5-（2-乙基己基）呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩 ）-2,6-二基-2-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩）-2-羧酸酯-2,6-二基（CS-18）和聚[ 4,5-双（5-己基呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） 公开了3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-24）。 此外，讨论了由衍生化的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物构成的有机太阳能电池。

公开(公告)号：US09783634B2

公开(公告)日：2017-10-10

申请号：US14640184

申请日：2015-03-06

申请人： Phillips 66 Company ,  Solarmer Energy, Inc.

发明人： Shuangxi Wang ,  Chenjun Shi ,  Ruby Chen ,  Junlian Zhang ,  Wei Wang ,  Yue Wu ,  Hui Huang ,  Amit Palkar ,  Ting He

IPC分类号： H01L21/02 ,  C08G61/12 ,  H01L51/00 ,  C07D409/02 ,  C07D495/04 ,  H01L51/42

CPC分类号： C08G61/126 ,  C07D409/02 ,  C07D495/04 ,  C08G2261/12 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/1426 ,  C08G2261/1428 ,  C08G2261/146 ,  C08G2261/149 ,  C08G2261/18 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/42 ,  H01L51/4253 ,  H01L2251/308 ,  Y02E10/50 ,  Y02E10/549 ,  Y02P70/521

摘要： A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.

公开(公告)号：US09711727B2

公开(公告)日：2017-07-18

申请号：US14722573

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Kathy Woody ,  Hui Huang ,  Ting He ,  Wei Wang ,  Chenjun Shi ,  Yue Wu

IPC分类号： C08G75/00 ,  H01L51/00 ,  H01L51/42

CPC分类号： H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

摘要： A polymer having at least four different repeat units comprising: In this polymer R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. Additionally, in this polymer, m, n, o and p can be greater than 1. x and y are different from each other and can be independently selected from the group consisting of: of alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, of alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl, substituted alkyls, aryls and substituted aryls, where R7 and R8 are independently selected from the group consisting of H, of alkyl group, alkoxy group, aryl groups, —NR9R10 where R9 and R10 are independently selected from the group consisting of H, of alkyl group, alkoxy group, aryl groups.

公开(公告)号：US20150349261A1

公开(公告)日：2015-12-03

申请号：US14722774

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC分类号： H01L51/00 ,  C08G75/10

CPC分类号： H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

摘要： A polymer having a monomer repeat unit comprising wherein Ar is an aryl group.

摘要翻译： 具有单体重复单元的聚合物，其中Ar是芳基。

公开(公告)号：US20130214213A1

公开(公告)日：2013-08-22

申请号：US13764919

申请日：2013-02-12

申请人： Solarmer Energy, Inc. ,  Phillips 66 Company

发明人： Shuangxi Wang ,  Chenjun Shi ,  Ruby Chen ,  Junlian Zhang ,  Hui Huang ,  Yue Wu ,  Wei Wang ,  Amit Palkar ,  Ting He

IPC分类号： H01L51/00

CPC分类号： C08G61/126 ,  C07D409/02 ,  C07D495/04 ,  C08G2261/12 ,  C08G2261/124 ,  C08G2261/1412 ,  C08G2261/1426 ,  C08G2261/1428 ,  C08G2261/146 ,  C08G2261/149 ,  C08G2261/18 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/42 ,  H01L51/4253 ,  H01L2251/308 ,  Y02E10/50 ,  Y02E10/549 ,  Y02P70/521

摘要： A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.

公开(公告)号：US20150344616A1

公开(公告)日：2015-12-03

申请号：US14722699

申请日：2015-05-27

申请人： PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

发明人： Kathy Woody ,  Hui Huang ,  Ting He ,  Wei Wang ,  Chenjun Shi ,  Yue Wu

IPC分类号： C08G61/12 ,  H01L51/00

CPC分类号： C08G61/126 ,  C08G2261/12 ,  C08G2261/1426 ,  C08G2261/1428 ,  C08G2261/146 ,  C08G2261/149 ,  C08G2261/18 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

摘要： A process of polymerizing wherein the stoichiometric ratio of (f+g)≈(h+i) and f, g, h and i are not equal to 0. Additionally, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. In addition, x and y can be different from each other and independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R7 and R8 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR9R10 where R9 and R10 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.

摘要翻译： （f + g）≈（h + i）和f，g，h和i的化学计量比不等于0的聚合过程。另外，R 1，R 2，R 3和R 4可以独立地选自 由烷基，烷氧基，芳基及其组合组成，其中R1，R2，R3和R4的组合不完全相同。 此外，x和y可以彼此不同并且独立地选自：烷基，烷氧基，芳基，其中y = 1-3，其中y = 0-12，其中R 5选自 由H，烷基，烷氧基，芳基组成的基团，其中R 6选自H，烷基，烷氧基，芳基，其中R 7和R 8独立地选自H，烷基 烷氧基，芳基，-NR 9 R 10，其中R 9和R 10独立地选自H，烷基，烷氧基，芳基。