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    Multiple material golf club head with a polymer insert face
    7.
    发明授权
    Multiple material golf club head with a polymer insert face 有权
    具有聚合物插入面的多种材料高尔夫球杆头

    公开(公告)号：US06336869B1

    公开(公告)日：2002-01-08

    申请号：US09679036

    申请日：2000-10-04

    申请人： Ronald K. Hettinger ,  Richard C. Helmstetter ,  J. Neil Hall ,  Augustin W. Rollinson ,  Kamal Sarkar ,  Joshua G. Breier ,  John G. Guard ,  Pijush K. Dewanjee

    发明人： Ronald K. Hettinger ,  Richard C. Helmstetter ,  J. Neil Hall ,  Augustin W. Rollinson ,  Kamal Sarkar ,  Joshua G. Breier ,  John G. Guard ,  Pijush K. Dewanjee

    IPC分类号： A63B5304

    CPC分类号： A63B53/04 ,  A63B53/0466 ,  A63B53/0487 ,  A63B60/00 ,  A63B60/54 ,  A63B2053/0416 ,  A63B2053/0441 ,  A63B2209/00 ,  Y10S273/08

    摘要： The present invention is a golf club (30) having a club head main body (34) with a hollow interior (49), a support layer 41 defining a depth of a recess (38), a polymer insert (40) in the recess (38), an isolation layer (52) and a weight body (50). The polymer insert (40) is composed of a thermosetting polyurethane material having a Shore D hardness in the range of 42 to 55, and a Bayshore rebound in the range of 51 to 60. The preferred thermosetting polyurethane material is formed from a p-phenylene diisocyanate prepolymer and a curing agent. The golf club (30) is preferably a putter, however, it may be a wood or an iron. The particular thermosetting polyurethane provides a soft striking face for feel and a good rebound for distance. The weight body (50) is preferably composed of a tungsten alloy, and the isolation layer (52) is preferably composed of a thermoplastic polyurethane.

    摘要翻译： 本发明是一种具有球杆头主体（34）的高尔夫球杆（30），其具有中空的内部（49），限定凹部（38）的深度的支撑层41，凹部中的聚合物插入件（40） （38），隔离层（52）和重量体（50）。 聚合物插入物（40）由肖氏D硬度在42至55范围内的热固性聚氨酯材料和51至60范围内的贝氏反弹组成。优选的热固性聚氨酯材料由对亚苯基 二异氰酸酯预聚物和固化剂。 高尔夫球杆（30）优选为推杆，但是也可以是木头或铁杆。 特定的热固性聚氨酯提供了柔软的触感面以及远距离的良好反弹。 重量体（50）优选由钨合金构成，隔离层（52）优选由热塑性聚氨酯构成。

    Cross-linked thermoplastic polyurethane/polyurea and method of making same
    8.
    发明授权
    Cross-linked thermoplastic polyurethane/polyurea and method of making same 有权
    交联热塑性聚氨酯/聚脲及其制造方法

    公开(公告)号：US07417094B2

    公开(公告)日：2008-08-26

    申请号：US10992907

    申请日：2004-11-18

    申请人： Pijush K. Dewanjee ,  John G. Guard

    发明人： Pijush K. Dewanjee ,  John G. Guard

    IPC分类号： C08G18/08

    CPC分类号： C08G18/0895 ,  C08G18/3814 ,  C08G18/7671 ,  C08L75/02

    摘要： A cross-linked thermoplastic polyurea is formed by heating a mixture containing a thermoplastic urethane base material, a monomeric and/or polymeric di-isocyanate comprising between 1 to 10% of the total weight of the mixture, and a diamine comprising between 1 to 10% of the total weight of the mixture. A thermoplastic polyurethane may be formed by substituting hydroquinone for the diamine. The mixture is heated to a temperature within the range of 250° F. to 550° F. The heated mixture, which is flowable, is then injected into at least one injection molding device. The mixture is then cured at a temperature between 150° F. to 250° F. for a period of time between 2 and 36 hours. The cross-linked thermoplastic polyurethane/polyurea retains the excellent flowability characteristics of a thermoplastic urethane while the same time exhibits good abrasion, tensile strength, rebound, and compression set characteristics which are similar to those found in thermoset urethanes.

    摘要翻译： 交联的热塑性聚脲通过加热含有热塑性氨基甲酸酯基材料，包含混合物总重量的1至10％的单体和/或聚合二异氰酸酯的混合物和包含1至10个 混合物总重量的百分比。 可以通过用氢醌代替二胺来形成热塑性聚氨酯。 将混合物加热到250°F至550°F范围内的温度。然后将可流动的加热混合物注入至少一个注射成型装置中。 然后将混合物在150°F至250°F的温度下固化2至36小时之间的时间。 交联的热塑性聚氨酯/聚脲保留了热塑性聚氨酯的优异的流动性特征，同时表现出与热固性聚氨酯中发现的相似的良好的耐磨性，拉伸强度，回弹和压缩变形特性。

    Cross-linked thermoplastic polyurethane/polyurea and method of making same
    9.
    发明授权
    Cross-linked thermoplastic polyurethane/polyurea and method of making same 有权
    交联热塑性聚氨酯/聚脲及其制造方法

    公开(公告)号：US07540990B1

    公开(公告)日：2009-06-02

    申请号：US12260279

    申请日：2008-10-29

    申请人： Pijush K. Dewanjee ,  John G. Guard

    发明人： Pijush K. Dewanjee ,  John G. Guard

    IPC分类号： B29C45/14 ,  B29B7/30 ,  A63B37/12

    CPC分类号： C08G18/0895 ,  C08G18/324 ,  C08G18/3814 ,  C08G18/7671 ,  C08G2120/00 ,  C08G2310/00 ,  C08G2380/00 ,  C08G2410/00 ,  C08L75/04 ,  C08L2666/20

    摘要： A process for forming a cross-linked thermoplastic polymer is disclosed herein. The cross-linked thermoplastic polymer is formed by heating a first mixture containing a thermoplastic urethane base material, a monomeric diisocyanate comprising between 1 to 10% of the total weight of the first mixture, and a second mixture of a first diamine and a second diamine comprising between 1 to 10% of the total weight of a total reaction product. The heated first mixture, which is flowable, is injected into at least one injection molding device, with the second mixture injected at predetermined intervals to create a homogeneous reaction product.

    摘要翻译： 本文公开了形成交联热塑性聚合物的方法。 交联的热塑性聚合物通过加热含有热塑性氨基甲酸酯基材料的第一混合物，包含第一混合物总重量的1至10％的单体二异氰酸酯和第一二胺和第二二胺的第二混合物 占总反应产物总重量的1至10％。 可加热的第一混合物可流动地注入至少一个注射成型装置中，第二混合物以预定间隔注入以产生均匀的反应产物。

    Cross-linked thermoplastic polyurethane/polyurea and method of making same
    10.
    发明授权
    Cross-linked thermoplastic polyurethane/polyurea and method of making same 有权
    交联热塑性聚氨酯/聚脲及其制造方法

    公开(公告)号：US08003747B2

    公开(公告)日：2011-08-23

    申请号：US12184394

    申请日：2008-08-01

    申请人： Pijush K. Dewanjee ,  John G. Guard

    发明人： Pijush K. Dewanjee ,  John G. Guard

    IPC分类号： C08G18/08

    CPC分类号： C08G18/0895 ,  C08G18/3814 ,  C08G18/7671 ,  C08L75/02

    摘要： A cross-linked thermoplastic polyurea is formed by heating a mixture containing a thermoplastic urethane base material, a monomeric and/or polymeric di-isocyanate comprising between 1 to 10% of the total weight of the mixture, and a diamine comprising between 1 to 10% of the total weight of the mixture. A thermoplastic polyurethane may be formed by substituting hydroquinone for the diamine. The mixture is heated to a temperature within the range of 250° F. to 550° F. The heated mixture, which is flowable, is then injected into at least one injection molding device. The mixture is then cured at a temperature between 150° F. to 250° F. for a period of time between 2 and 36 hours. The cross-linked thermoplastic polyurethane/polyurea retains the excellent flowability characteristics of a thermoplastic urethane while the same time exhibits good abrasion, tensile strength, rebound, and compression set characteristics which are similar to those found in thermoset urethanes.

    摘要翻译： 交联的热塑性聚脲通过加热含有热塑性氨基甲酸酯基材料，单体和/或聚合二异氰酸酯的混合物形成，所述二异氰酸酯占混合物总重量的1至10％，和包含1至10 混合物总重量的百分比。 可以通过用氢醌代替二胺来形成热塑性聚氨酯。 将混合物加热到250°F至550°F范围内的温度。然后将可流动的加热混合物注入至少一个注射成型装置中。 然后将混合物在150°F至250°F的温度下固化2至36小时之间的时间。 交联的热塑性聚氨酯/聚脲保留了热塑性聚氨酯的优异的流动性特征，同时表现出与热固性聚氨酯中发现的相似的良好的耐磨性，拉伸强度，回弹和压缩变形特性。