公开(公告)号：US20140114031A1

公开(公告)日：2014-04-24

申请号：US14137531

申请日：2013-12-20

申请人： Prime Polymer Co., Ltd.

发明人： Hideki BANDO ,  Yasuo SATOH ,  Takashi YUKITA ,  Yasuyuki HARADA ,  Yoshiho SONOBE ,  Yasushi TOHI ,  Yusuke SEKIOKA ,  Masao SUZUKI ,  Daisuke TANIFUJI

IPC分类号： C08F4/6592

CPC分类号： C08F4/65927 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/11 ,  C08F2500/10 ,  C08F2500/24 ,  C08F210/14 ,  C08F210/08

摘要： Metallocene compounds of the invention are useful as olefin polymerization catalysts or catalyst components. Olefin polymerization processes of the invention involve an olefin polymerization catalyst containing the metallocene compound. In detail, the olefin polymerization catalysts can catalyze with high polymerization activity the production of olefin polymers having high melt tension, excellent mechanical strength and good particle properties, and the olefin polymerization processes involve the catalysts. Ethylene polymers according to the invention are obtained by the polymerization processes and have higher processability and easy-opening properties and particularly excellent mechanical strength compared to conventional ethylene polymers. Thermoplastic resin compositions of the invention contain the ethylene polymers. In more detail, shaped articles or films are obtained from the ethylene polymers or the thermoplastic resin compositions containing the ethylene polymers, and laminate films include the films.According to the invention, a single or plural kinds of bridged metallocene compounds having differing cyclopentadienyl-derived groups afford macromonomers that are a source of long-chain branches and simultaneously catalyze the repolymerization of the macromonomers into olefin polymers having a large number of long-chain branches, small neck-in in the T-die extrusion, small take-up surge and superior mechanical strength. The olefin polymerization catalysts and the polymerization processes can efficiently produce the olefin polymers.

摘要翻译： 本发明的茂金属化合物可用作烯烃聚合催化剂或催化剂组分。 本发明的烯烃聚合方法包括含有茂金属化合物的烯烃聚合催化剂。 详细地，烯烃聚合催化剂可以以高聚合活性催化生产具有高熔体张力，优异的机械强度和良好的颗粒性能的烯烃聚合物，并且烯烃聚合方法涉及催化剂。 根据本发明的乙烯聚合物通过聚合方法获得，并且与常规的乙烯聚合物相比具有更高的加工性和易开启性以及特别优异的机械强度。 本发明的热塑性树脂组合物含有乙烯聚合物。 更详细地，从乙烯聚合物或含有乙烯聚合物的热塑性树脂组合物获得成型制品或膜，层压膜包括膜。 根据本发明，具有不同的环戊二烯基衍生基团的单种或多种桥连茂金属化合物提供大分子单体，其是长链支链的来源，并同时催化大分子单体重新聚合成具有大量长链的烯烃聚合物 分支机构，T型模具挤出中的小口径，小的卷取浪涌和优异的机械强度。 烯烃聚合催化剂和聚合方法可以有效地生产烯烃聚合物。