公开(公告)号：US20120122665A1

公开(公告)日：2012-05-17

申请号：US13381394

申请日：2010-06-15

申请人： Priscilla Avenier ,  Sylvie Lacombe ,  Jean Claude Jumas ,  Josette Olivier-Fourcade

发明人： Priscilla Avenier ,  Sylvie Lacombe ,  Jean Claude Jumas ,  Josette Olivier-Fourcade

IPC分类号： B01J27/185 ,  B01J27/186

CPC分类号： B01J23/626 ,  B01J23/644 ,  B01J23/6445 ,  B01J27/1856 ,  B01J27/186 ,  B01J35/002 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/24 ,  B01J37/28 ,  C10G35/09 ,  C10G2300/70

摘要： The invention concerns a catalyst comprising at least one metal M from group VIII, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. In 119Sn Mössbauer spectroscopy, the catalyst in the reduced form has a signal with a quadripole splitting value in the range 0 to 0.45 mm/s and an isomer shift, IS, in the range 1.5 to 2.4 mm/s with respect to CaSnO3, said signal representing in the range 1% to 30% of the total area of the signals.

摘要翻译： 本发明涉及一种催化剂，其包含至少一种第VIII族金属M，锡，磷促进剂，卤代化合物，多孔载体和至少一种选自由镓，铟，铊，砷，锑和 铋。 在119SnMössbauer光谱学中，还原形式的催化剂具有在0至0.45mm / s范围内的四极分裂值和相对于CaSnO 3在1.5至2.4mm / s范围内的异构体移动IS的信号，所述 信号表示信号总面积的1％至30％。

公开(公告)号：US20120178979A1

公开(公告)日：2012-07-12

申请号：US13381281

申请日：2010-06-15

申请人： Priscilla Avenier ,  Sylvie Lacombe ,  Herve Cauffriez

发明人： Priscilla Avenier ,  Sylvie Lacombe ,  Herve Cauffriez

IPC分类号： C07C15/02 ,  B01J27/186 ,  B01J37/08 ,  B01J27/185

CPC分类号： B01J23/626 ,  B01J23/644 ,  B01J23/6445 ,  B01J27/1856 ,  B01J27/186 ,  B01J35/002 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/24 ,  B01J37/28 ,  C10G35/09 ,  C10G2300/70

摘要： The invention concerns a process for preparing a catalyst comprising at least one metal M from the platinum group, tin, a phosphorus promoter, a halogenated compound, a porous support and at least one promoter X1 selected from the group constituted by gallium, indium, thallium, arsenic, antimony and bismuth. The promoter or promoters X1 and the phosphorus are introduced during one or more sub-steps a1) or a2), the sub-step a1) corresponding to synthesis of the precursor of the main oxide and sub-step a2) corresponding to shaping the support. The tin is introduced during at least one of sub-steps a1) and a2). The product is dried and calcined before depositing at least one metal M from the platinum group. The ensemble is then dried in a stream of neutral gas or a stream of gas containing oxygen, and then is dried. The invention also concerns the use of a catalyst obtained by said process in catalytic reforming or aromatics production reactions.

摘要翻译： 本发明涉及一种制备催化剂的方法，所述催化剂包含至少一种来自铂族的金属M，锡，磷促进剂，卤代化合物，多孔载体和至少一种选自镓，铟，铊 ，砷，锑和铋。 在一个或多个子步骤a1）或a2）期间引入启动子或启动子X1和磷，对应于主氧化物的前体的合成的子步骤a1）和对应于形成载体的子步骤a2） 。 在子步骤a1）和a2）中的至少一个中引入锡。 在从铂族中沉积至少一种金属M之前，将产物干燥并煅烧。 然后将所述组合体在中性气体流或含氧气流中干燥，然后干燥。 本发明还涉及通过所述方法在催化重整或芳烃生产反应中获得的催化剂的用途。