公开(公告)号：US07144512B2

公开(公告)日：2006-12-05

申请号：US10623044

申请日：2003-07-18

申请人： Qi Qu ,  Paul H. Javora ,  Joel L. Boles ,  Sandra L. Berry

发明人： Qi Qu ,  Paul H. Javora ,  Joel L. Boles ,  Sandra L. Berry

IPC分类号： B01D15/00

CPC分类号： E21B21/068 ,  B01D19/04 ,  B01J45/00 ,  Y10S210/912

摘要： A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and non-zinc heavy metals; and (ii) calcium and zinc. The chelant contains a functional group selected from the group —CO2H or —PO(OH)R20 or a salt or ester thereof, —C(O)—, —OE, —SE, —N═C(R2)R3, EO—N═C(R2)R3, —N(R2)R3, and —N(C(O)R1)R2 group optionally substituted with a —COOH or —PO(OH)R20 or a salt or ester thereof, —SE or —OE group, wherein R2 and R3 are independently selected from E or forms, with nitrogen, phosphorous, oxygen or sulfur, a heterocyclic ring; E is R1 or —H; R1 is a C1–C30 alkyl or aralkyl group or a derivative thereof and R20 is —OH or R1.

摘要翻译： 通过使用能够区分（i）铁和非锌重金属的有机螯合剂回收完井盐水溶液的方法; 和（ii）钙和锌。 螯合剂含有选自-CO 2 H或-PO（OH）R 20的官能团或其盐或酯，-C（O） - ， -OE，-SE，-NC（R 2）R 3，EO-NC（R 2）R 3， -N（R 2）R 3，和-N（C（O）R 1）R 2， 任选被-COOH或-PO（OH）R 20或其盐或酯取代的-SE或-OE基团，其中R 2和R 3， 独立地选自E或其形式，具有氮，磷，氧或硫，杂环; E是R 1或-H; R 1是C 1 -C 30烷基或芳烷基或其衍生物，R 20是 - OH或R 1。

公开(公告)号：US20090114394A1

公开(公告)日：2009-05-07

申请号：US12345505

申请日：2008-12-29

申请人： Paul H. Javora ,  Brian B. Beall ,  Mark A. Vorderburggen ,  Qi Qu ,  Sandra L. Berry

发明人： Paul H. Javora ,  Brian B. Beall ,  Mark A. Vorderburggen ,  Qi Qu ,  Sandra L. Berry

IPC分类号： E21B37/08 ,  C09K8/52

CPC分类号： C09K8/52 ,  C09K8/524 ,  Y10S507/905 ,  Y10S507/929

摘要： Fluid producing or injecting wells may be treated with a water-in-oil emulsion for the removal or inhibition of unwanted particulates, including pipe dope, asphaltenes and paraffins. In addition, such emulsions are effective in the displacement of oil base drilling muds and/or residues from such muds from wells. The emulsion may also be used to break the interfacial and/or rheological properties of oil base mud and synthetic oil base mud filter cakes, and act as a demulsifier to break the water-in-oil emulsion present in such oil base and synthetic oil base muds. The water-in-oil emulsions may optionally contain a dispersing agent as well as a surfactant.

摘要翻译： 流体生产或注入井可用油包水乳液处理，以除去或抑制不需要的颗粒，包括管道涂料，沥青质和石蜡。 此外，这种乳液在油井钻井泥浆和/或来自井的这种泥浆的残留物的位移中是有效的。 该乳液也可用于破坏油基泥浆和合成油基泥浆滤饼的界面和/或流变性能，并且用作破乳剂以破坏这种油基和合成油基中存在的油包水乳液 泥土 油包水乳液可以任选地含有分散剂以及表面活性剂。

公开(公告)号：US07481273B2

公开(公告)日：2009-01-27

申请号：US11820085

申请日：2007-06-18

申请人： Paul H. Javora ,  Brian B. Beall ,  Mark A. Vorderburggen ,  Qi Qu ,  Sandra L. Berry

发明人： Paul H. Javora ,  Brian B. Beall ,  Mark A. Vorderburggen ,  Qi Qu ,  Sandra L. Berry

IPC分类号： E21B37/00 ,  C09K8/52

CPC分类号： C09K8/52 ,  C09K8/524 ,  Y10S507/905 ,  Y10S507/929

摘要： Fluid producing or injecting wells may be treated with a water-in-oil emulsion for the removal or inhibition of unwanted particulates, including pipe dope, asphaltenes and paraffins. In addition, such emulsions are effective in the displacement of oil base drilling muds and/or residues from such muds from wells. The emulsion may also be used to break the interfacial and/or rheological properties of oil base mud and synthetic oil base mud filter cakes, and act as a demulsifier to break the water-in-oil emulsion present in such oil base and synthetic oil base muds. The water-in-oil emulsions may optionally contain a dispersing agent as well as a surfactant.

摘要翻译： 流体生产或注入井可用油包水乳液处理，以除去或抑制不需要的颗粒，包括管道涂料，沥青质和石蜡。 此外，这种乳液在油井钻井泥浆和/或来自井的这种泥浆的残留物的位移中是有效的。 该乳液也可用于破坏油基泥浆和合成油基泥浆滤饼的界面和/或流变性能，并且用作破乳剂以破坏这种油基和合成油基中存在的油包水乳液 泥土 油包水乳液可以任选地含有分散剂以及表面活性剂。

公开(公告)号：US07674384B2

公开(公告)日：2010-03-09

申请号：US11701888

申请日：2007-02-02

申请人： Paul H. Javora ,  Qi Qu

发明人： Paul H. Javora ,  Qi Qu

IPC分类号： B01D15/00 ,  E21B43/34

CPC分类号： E21B21/068 ,  B01D19/04 ,  B01J45/00 ,  Y10S210/912

摘要： A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and non-zinc heavy metals; and (ii) calcium and zinc. The chelant contains a functional group selected from the group —CO2H or —PO(R21)R20 or a salt or ester thereof, —C(O)—, —OE, —SE, —N═C(R2)R3, EO—N═C(R2)R3, —N(R2)R3, and —N(C(O)R1)R2 group optionally substituted with a —COOH or —PO(R21)R20 or a salt or ester thereof, —SE or —OE group, wherein R2 and R3 are independently selected from E or forms, with nitrogen, phosphorous, oxygen or sulfur, a heterocyclic ring; E is R1 or —H; R1 is a C1-C30 alkyl or aralkyl group or a derivative thereof and R20 and R21 are independently selected from —OH, —OR1 and R1.

摘要翻译： 通过使用能够区分（i）铁和非锌重金属的有机螯合剂回收完井盐水溶液的方法; 和（ii）钙和锌。 螯合剂含有选自-CO 2 H或-PO（R 21）R 20的官能团或其盐或酯，-C（O） - ， - OE，-SE，-N = C（R 2）R 3，EO- N = C（R2）R3，-N（R2）R3和-N（C（O）R1）任选被-COOH或-PO（R21）R20取代的R2基团或其盐或酯，-SE或 -OE基，其中R2和R3独立地选自E或与氮，磷，氧或硫形成，杂环; E为R1或-H; R1是C1-C30烷基或芳烷基或其衍生物，R20和R21独立地选自-OH，-OR1和R1。

公开(公告)号：US07762332B2

公开(公告)日：2010-07-27

申请号：US11589461

申请日：2006-10-30

申请人： Cristian A. Lopez ,  Xiaolan Wang ,  Qi Qu ,  Paul H. Javora

发明人： Cristian A. Lopez ,  Xiaolan Wang ,  Qi Qu ,  Paul H. Javora

IPC分类号： E21B36/00 ,  E21B43/24 ,  C09K8/68

CPC分类号： E21B36/003 ,  C09K8/592

摘要： A thermal insulating packer fluid contains at least one water superabsorbent polymer and optionally water and/or brine, and a viscosifying polymer. The composition is capable of inhibiting unwanted heat loss from production tubing or uncontrolled heat transfer to outer annuli. The viscosity of the composition is sufficient to reduce the convection flow velocity within the annulus.

摘要翻译： 绝热封隔器流体包含至少一种水超吸收性聚合物和任选的水和/或盐水，以及增粘聚合物。 该组合物能够抑制生产管道不期望的热损失或不受控制的热传递至外环。 组合物的粘度足以降低环形空间内的对流流速。

公开(公告)号：US20080210428A1

公开(公告)日：2008-09-04

申请号：US11731388

申请日：2007-03-30

申请人： Paul H. Javora ,  Qi Qu ,  Brian B. Beall ,  Leonard J. Kalfayan

发明人： Paul H. Javora ,  Qi Qu ,  Brian B. Beall ,  Leonard J. Kalfayan

IPC分类号： E21B37/06

CPC分类号： C09K8/52

摘要： A filter cake deposited by a drilling fluid, drill-in fluid or fluid loss control pill may be removed from a wellbore by introducing into the wellbore a dispersing agent of an organic amino phosphonic acid, ester or salt. The dispersing agent forms a dispersion containing at least a portion of the drilled solids. The dispersing agent may be introduced into the wellbore as a component of a filter cake removal treatment fluid or either prior to or after introduction of the filter cake removal treatment fluid.

摘要翻译： 通过将钻井液，钻入流体或流体损失控制丸沉积的滤饼可以通过向井筒中引入有机氨基膦酸酯或盐的分散剂而从井筒中除去。 分散剂形成含有至少一部分钻孔固体的分散体。 可以将分散剂作为滤饼除去处理流体的组分或在引入滤饼去除处理流体之前或之后引入井眼。

公开(公告)号：US08136596B2

公开(公告)日：2012-03-20

申请号：US12788357

申请日：2010-05-27

申请人： Cristian A. Lopez ,  Xiaolan Wang ,  Qi Qu ,  Paul H. Javora

发明人： Cristian A. Lopez ,  Xiaolan Wang ,  Qi Qu ,  Paul H. Javora

IPC分类号： E21B36/00 ,  C09K8/10

CPC分类号： E21B36/003 ,  C09K8/592

摘要： A thermal insulating packer fluid contains at least one water superabsorbent polymer and optionally water and/or brine, and a viscosifying polymer. The composition is capable of inhibiting unwanted heat loss from production tubing or uncontrolled heat transfer to outer annuli. The viscosity of the composition is sufficient to reduce the convection flow velocity within the annulus.

摘要翻译： 绝热封隔器流体包含至少一种水超吸收性聚合物和任选的水和/或盐水，以及增粘聚合物。 该组合物能够抑制生产管道不期望的热损失或不受控制的热传递至外环。 组合物的粘度足以降低环形空间内的对流流速。

公开(公告)号：US07172703B2

公开(公告)日：2007-02-06

申请号：US11145281

申请日：2005-06-03

申请人： Paul H. Javora ,  Qi Qu

发明人： Paul H. Javora ,  Qi Qu

IPC分类号： B01D15/00

CPC分类号： E21B21/068 ,  B01D19/04 ,  B01J45/00 ,  C02F1/28 ,  C02F1/66 ,  C02F1/683 ,  C02F1/72 ,  C02F9/00 ,  C02F2101/20 ,  C02F2103/08 ,  Y10S210/912

摘要： A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and/or non-zinc heavy metals; and (ii) calcium and zinc. The chelant is of the formula: and may be either a neutral compound, a corresponding salt, or a corresponding quaternary salt, wherein: D is F—A (Y3)u(Y4)v; R is independently selected from Cp or CpC(O); Cp is a C1–C36 hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; each A is independently selected from —N and —P; Y1 is independently selected from J, —[(F)—A(J)]wY6 and R; J, R1, Y2, Y3, Y4, Y5 and Y6 are independently selected from the group consisting of —H, R, —(F)nCO2Z and —(CH2)nPO(OZ)2; each F is independently selected from a C1–C12 hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2 groups; Z is —H or a balanced counterion of an alkali or alkaline earth metal or NH4+; m is 0 to 7; n is 1 to 7; r+s+t is 1 or 2; u+v is 1 or 2; and w is 0 to 7 provided when m is 0, no more than one of R1, Y1, Y2 and Y5 can be —H.

公开(公告)号：US20090221455A1

公开(公告)日：2009-09-03

申请号：US12040427

申请日：2008-02-29

申请人： Mingjie Ke ,  Qi Qu ,  Joel L. Boles

发明人： Mingjie Ke ,  Qi Qu ,  Joel L. Boles

IPC分类号： C09K8/54

CPC分类号： C09K8/54 ,  C23F11/04 ,  C23F11/122

摘要： An acid treatment composition is provided including a corrosion inhibitor and an optional corrosion inhibitor intensifier in an acidic solution. More specifically, the composition includes a propargylalcohol alkoxylated compound. Methods for treating wells with these acid treatment compositions are also provided that help control corrosion of the steel used in the wells during the acid treatment.

摘要翻译： 在酸性溶液中提供含有腐蚀抑制剂和任选的防腐剂增强剂的酸处理组合物。 更具体地，组合物包括炔丙醇烷氧基化化合物。 还提供了使用这些酸处理组合物处理孔的方法，其有助于控制在酸处理期间在孔中使用的钢的腐蚀。

公开(公告)号：US20090131285A1

公开(公告)日：2009-05-21

申请号：US12271667

申请日：2008-11-14

申请人： Xiaolan Wang ,  Qi Qu ,  Joel L. Boles

发明人： Xiaolan Wang ,  Qi Qu ,  Joel L. Boles

IPC分类号： C09K8/60

CPC分类号： C09K8/72

摘要： An oil or gas well penetrating a subterranean formation, such as a carbonate formation, is treated with a well treatment fluid which contains an organic ester. The fluid may be an oil-in-water emulsion of the organic ester and an emulsifier or a homogeneous solution of organic ester and a water/mutual solvent solution. Acid is produced in-situ by hydrolysis of the organic ester.

摘要翻译： 穿透地下地层（如碳酸盐岩层）的油井或气井用含有有机酯的井处理液处理。 流体可以是有机酯的水包油乳液和乳化剂或有机酯和水/互溶剂溶液的均匀溶液。 通过水解有机酯原位产生酸。