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1.发明授权Two-step hydrotreatment of a feed derived from a renewable source using a first, metallic, catalyst and a second, sulphurized, catalyst 失效使用第一种金属催化剂和第二种硫化催化剂对来自可再生能源的原料进行两步加氢处理公开(公告)号：US08674151B2
公开(公告)日：2014-03-18
申请号：US12664136
申请日：2008-06-03
CPC分类号： C10G3/42 , C07C1/2078 , C10G3/46 , C10G3/47 , C10G3/48 , C10G3/50 , C10G45/08 , C10G51/02 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , C11C3/123 , Y02P30/20
摘要： The invention describes a two-step process for hydrotreatment of a feed derived from a renewable source, comprising: a) a first step, termed a mild pre-hydrogenation step, operating in the presence of a first, metallic, catalyst comprising an active hydrodehydrogenating phase constituted by at least one metal from group VIII and/or at least one metal from group VIB and an amorphous mineral support; and b) a second step, termed the second treatment step, operating in the presence of a second, sulphurized, catalyst comprising an active hydrodehydrogenating phase constituted by at least one non-noble metal from group VIII and/or at least one metal from group VIB and an amorphous mineral support.
摘要翻译： 本发明描述了用于加氢处理源自可再生源的进料的两步法，该方法包括：a）第一步骤，称为温和预氢化步骤，在第一金属催化剂存在下操作，其包含活性氢化氢 由至少一种来自第VIII族的金属和/或至少一种来自VIB族的金属和无定形矿物载体构成; 和b）称为第二处理步骤的第二步骤，在第二种硫化催化剂存在下操作，该催化剂包含由至少一种来自第VIII族的非贵金属和/或至少一种来自基团的金属构成的活性氢化氢化相 VIB和无定形矿物支持。
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2.发明申请PRODUCTION OF VAPOUR-CRACKING LOADS WITH A HIGH YIELD OF THE RESULTING ETHYLENE, PROPYLENE AND POLYMERS BY HYDROPROCESSING OF VEGETABLE OILS 有权通过植物油的水解生产具有高分子量乙烯，丙烯和聚合物的蒸气破碎负荷公开(公告)号：US20100292517A1
公开(公告)日：2010-11-18
申请号：US12664132
申请日：2008-06-03
IPC分类号： C07C4/04
CPC分类号： C10G9/36 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/08 , C10G47/04 , C10G47/06 , C10G69/06 , C10G2300/1003 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1055 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/20 , C11C3/123 , C11C3/126 , Y02P30/20 , Y02P30/42
摘要： The invention describes a process for treatment of a feedstock that is obtained from a renewable source that comprises a hydrotreatment stage in the presence of at least one fixed-bed catalyst, whereby said catalyst comprises a hydro-dehydrogenating function and an amorphous substrate, at a temperature of between 50 and 450° C., at a pressure of between 1 MPa and 10 MPa, at an hourly volumetric flow rate of between 0.1 h−1 and 10 h−1, and in the presence of a total quantity of hydrogen that is mixed with the feedstock such that the hydrogen/feedstock ratio is between 50 and 1000 Nm3 of hydrogen/m3 of feedstock, followed by a separation from the hydrotreated effluent that is obtained from stage a) of hydrogen, gases, and at least one liquid hydrocarbon effluent that consists of at least 50% linear n-paraffins, and a steam-cracking of at least one portion of the liquid hydrocarbon effluent that is obtained from stage b).
摘要翻译： 本发明描述了一种处理从可再生来源获得的原料的方法，该方法包括在至少一种固定床催化剂存在下的加氢处理阶段，由此所述催化剂包含加氢脱氢功能和非晶基质， 温度为50-450℃，压力为1MPa至10MPa，小时体积流速为0.1h-1至10h-1，在总氢存在下， 与原料混合使得氢/原料比为50至1000Nm 3的氢/ m3原料，然后与从氢气，气体和至少一种液体的a）段获得的加氢处理流出物分离 由至少50％线性正链烷烃组成的碳氢化合物流出物，以及从阶段b）获得的液体烃流出物的至少一部分的蒸汽裂解。
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3.发明授权Production of vapour-cracking loads with a high yield of the resulting ethylene, propylene and polymers by hydroprocessing of vegetable oils 有权通过植物油的加氢处理，生成乙烯，丙烯和聚合物的高产率的蒸汽裂解负荷公开(公告)号：US08692040B2
公开(公告)日：2014-04-08
申请号：US12664132
申请日：2008-06-03
IPC分类号： C07C1/00
CPC分类号： C10G9/36 , C10G3/46 , C10G3/50 , C10G3/54 , C10G45/08 , C10G47/04 , C10G47/06 , C10G69/06 , C10G2300/1003 , C10G2300/1014 , C10G2300/1018 , C10G2300/1044 , C10G2300/1055 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/20 , C11C3/123 , C11C3/126 , Y02P30/20 , Y02P30/42
摘要： The invention describes a process for treatment of a feedstock that is obtained from a renewable source that comprises a hydrotreatment stage in the presence of at least one fixed-bed catalyst, whereby said catalyst comprises a hydro-dehydrogenating function and an amorphous substrate, at a temperature of between 50 and 450° C., at a pressure of between 1 MPa and 10 MPa, at an hourly volumetric flow rate of between 0.1 h−1 and 10 h−1, and in the presence of a total quantity of hydrogen that is mixed with the feedstock such that the hydrogen/feedstock ratio is between 50 and 1000 Nm3 of hydrogen/m3 of feedstock, followed by a separation from the hydrotreated effluent that is obtained from stage a) of hydrogen, gases, and at least one liquid hydrocarbon effluent that consists of at least 50% linear n-paraffins, and a steam-cracking of at least one portion of the liquid hydrocarbon effluent that is obtained from stage b).
摘要翻译： 本发明描述了一种处理从可再生来源获得的原料的方法，该方法包括在至少一种固定床催化剂存在下的加氢处理阶段，由此所述催化剂包含加氢脱氢功能和非晶基质， 温度为50-450℃，压力为1MPa至10MPa，小时体积流速为0.1h-1至10h-1，在总氢存在下， 与原料混合使得氢/原料比为50至1000Nm 3的氢/ m3原料，然后与从氢气，气体和至少一种液体的a）段获得的加氢处理流出物分离 由至少50％线性正链烷烃组成的碳氢化合物流出物，以及从阶段b）获得的液体烃流出物的至少一部分的蒸汽裂解。
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4.发明申请TWO-STEP HYDROTREATMENT OF A FEED DERIVED FROM A RENEWABLE SOURCE USING A FIRST, METALLIC, CATALYST AND A SECOND, SULPHURIZED, CATALYST 失效使用第一，金属，催化剂和第二种硫化催化剂从可再生来源获得的进料的两步骤加氢公开(公告)号：US20100292518A1
公开(公告)日：2010-11-18
申请号：US12664136
申请日：2008-06-03
IPC分类号： C07C5/373
CPC分类号： C10G3/42 , C07C1/2078 , C10G3/46 , C10G3/47 , C10G3/48 , C10G3/50 , C10G45/08 , C10G51/02 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , C11C3/123 , Y02P30/20
摘要： The invention describes a two-step process for hydrotreatment of a feed derived from a renewable source, comprising: a) a first step, termed a mild pre-hydrogenation step, operating in the presence of a first, metallic, catalyst comprising an active hydrodehydrogenating phase constituted by at least one metal from group VIII and/or at least one metal from group VIB and an amorphous mineral support; and b) a second step, termed the second treatment step, operating in the presence of a second, sulphurized, catalyst comprising an active hydrodehydrogenating phase constituted by at least one non-noble metal from group VIII and/or at least one metal from group VIB and an amorphous mineral support.
摘要翻译： 本发明描述了用于加氢处理源自可再生源的进料的两步法，该方法包括：a）第一步骤，称为温和预氢化步骤，在第一金属催化剂存在下操作，其包含活性氢化氢 由至少一种来自第VIII族的金属和/或至少一种来自VIB族的金属和无定形矿物载体构成; 和b）称为第二处理步骤的第二步骤，在第二种硫化催化剂存在下操作，该催化剂包含由至少一种来自第VIII族的非贵金属和/或至少一种来自基团的金属构成的活性氢化氢化相 VIB和无定形矿物支持。
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公开(公告)号：US20060289338A1
公开(公告)日：2006-12-28
申请号：US11449867
申请日：2006-06-09
摘要： The invention relates to a process for FCC pretreatment by mild hydrocracking of a hydrocarbon feedstock that comprises a vacuum distillate fraction or a deasphalted oil or else a mixture of these two fractions, said primary feedstock, to produce gas oil and an effluent having an initial boiling point of more than 320° C., said effluent (FCC feedstock) then being subjected to a catalytic cracking, process in which at least 85% by weight of said primary feedstock ends above 375° C. and at least 95% by weight of said primary feedstock ends below 650° C., whereby the mild hydrocracking is performed under an absolute pressure of 2 to 12 MPa and at a temperature of between 300 and 500° C., characterized in that the hydrocarbon feedstock also comprises a lighter hydrocarbon fraction, a so-called secondary feedstock, of which at least 50% by weight ends below 375° C. and at least 80% ends above 200° C.
摘要翻译： 本发明涉及通过烃原料的轻度加氢裂化来进行FCC预处理的方法，所述烃原料包括真空蒸馏馏分或脱沥青油，或者所述主要原料的这两个馏分的混合物，以产生瓦斯油和具有初始沸点的流出物 所述流出物（FCC原料）然后进行催化裂化，其中至少85重量％的所述主要原料在375℃以上终止，并且至少95重量％ 所述主要原料终止于650℃以下，由此在2至12MPa的绝对压力和300至500℃的温度下进行轻度加氢裂化，其特征在于，烃原料还包含较轻的烃馏分 ，所谓的二次原料，其中至少50重量％终止于375℃以下且至少80％在200℃以上结束。
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公开(公告)号：US07718050B2
公开(公告)日：2010-05-18
申请号：US11449867
申请日：2006-06-09
摘要： The invention relates to a process for FCC pretreatment by mild hydrocracking of a hydrocarbon feedstock that comprises a vacuum distillate fraction or a deasphalted oil or else a mixture of these two fractions, said primary feedstock, to produce gas oil and an effluent having an initial boiling point of more than 320° C., said effluent (FCC feedstock) then being subjected to a catalytic cracking, process in which at least 85% by weight of said primary feedstock ends above 375° C. and at least 95% by weight of said primary feedstock ends below 650° C., whereby the mild hydrocracking is performed under an absolute pressure of 2 to 12 MPa and at a temperature of between 300 and 500° C., characterized in that the hydrocarbon feedstock also comprises a lighter hydrocarbon fraction, a so-called secondary feedstock, of which at least 50% by weight ends below 375° C. and at least 80% ends above 200° C.
摘要翻译： 本发明涉及通过烃原料的轻度加氢裂化来进行FCC预处理的方法，所述烃原料包括真空蒸馏馏分或脱沥青油，或者所述主要原料的这两个馏分的混合物，以产生瓦斯油和具有初始沸点的流出物 所述流出物（FCC原料）然后进行催化裂化，其中至少85重量％的所述主要原料在375℃以上终止，并且至少95重量％ 所述主要原料终止于650℃以下，由此在2至12MPa的绝对压力和300至500℃的温度下进行轻度加氢裂化，其特征在于，烃原料还包含较轻的烃馏分 ，所谓的二次原料，其中至少50重量％终止于375℃以下且至少80％在200℃以上结束。
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