公开(公告)号：US20240218261A1

公开(公告)日：2024-07-04

申请号：US18149087

申请日：2022-12-31

申请人： Chevron U.S.A. Inc.

发明人： Sven Ivar Hommeltoft

IPC分类号： C10G3/00 ,  B01J8/02

CPC分类号： C10G3/50 ,  B01J8/025 ,  C10G3/48 ,  C10G2300/1014 ,  C10G2400/04

摘要： A reactor system includes a fixed bed reactor that treats a lipid feedstock using a metal oxide catalyst to produce a treated stream comprising a bio-oil. The reactor system includes a ketopyrolyis zone in which the metal oxide catalyst reacts with the lipid feedstock to produce the treated stream. The reactor system can operate in a reaction mode, during which the reactor treats the lipid feedstock, and a regeneration mode, during which coke is burned from the metal oxide catalyst.

公开(公告)号：US20180361368A1

公开(公告)日：2018-12-20

申请号：US16101257

申请日：2018-08-10

申请人： UOP LLC

发明人： Gregory J. Lewis ,  Christopher P. Nicholas ,  Lisa M. Knight ,  Jaime G. Moscoso ,  Seungwan Seo ,  Suk Bong Hong ,  Junghwan Lee

IPC分类号： B01J29/84 ,  C01B39/54 ,  B01J37/04 ,  B01J37/00

CPC分类号： B01J29/84 ,  B01J29/061 ,  B01J31/02 ,  B01J37/0018 ,  B01J37/04 ,  C01B37/08 ,  C01B39/54 ,  C10G3/48 ,  C10G11/04 ,  C10G29/205 ,  C10G35/065 ,  C10G45/04 ,  C10G45/60 ,  C10G47/12 ,  C10G50/00 ,  Y02P30/20

摘要： A family of highly charged crystalline microporous metallophosphate molecular sieves designated PST-17 has been synthesized. These metallophosphates are represented by the empirical formula of: Rp+rAm+MxEyPOz where A is an alkali metal such as potassium, R is a quaternary ammonium cation such as ethyltrimethylammonium, M is a divalent metal such as zinc and E is a trivalent framework element such as aluminum or gallium. The PST-17 family of molecular sieves are stabilized by combinations of alkali and organoammonium cations, enabling unique metalloalumino(gallo)phosphate compositions and exhibit the BPH topology. The PST-17 family of molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

公开(公告)号：US20180134968A1

公开(公告)日：2018-05-17

申请号：US15817168

申请日：2017-11-18

申请人： Nankai University ,  Tianjin Nankai University Castor Engineering Science and Technology Co., Ltd. ,  TIANJIN BINENG SCIENCE AND TECHNOLOGY CO.,LTD.

发明人： Wei LI ,  SiYang LIU ,  Qingxin GUAN ,  Bohan CHAI ,  Liangnian HE ,  Feng YE ,  Xiaoying CUI

IPC分类号： C10G3/00 ,  C10L1/04

CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G3/48 ,  C10G3/49 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/043 ,  C10L2270/04 ,  Y02P30/20

摘要： A hydrodeoxygenation catalyst takes self-made porous large-specific surface nano-alumina as a carrier, takes NixMoW, NixCoW or NixCoMo as an active component, and takes Mn as an assistant. Hydrothermal stability of the catalyst and dispersion of active components may be increased by enlarging a pore channel and a specific surface area of the carrier, thereby prolonging the life of the hydrodeoxygenation catalyst. A hydroisomerization catalyst takes multi-walled carbon nanotube composite hierarchical-pore-channel NiAPO-11 or NiSAPO-11 as a carrier and takes NixMoLa, NixCoLa or NixWLa as an active component. Due to the adding of the carbon nanotubes, the pore channel of the carrier is enriched, and connection between the active components and the carrier is effectively enhanced, thereby prolonging the life of the catalyst on a basis of increasing selectivity of aviation kerosene component. Moreover, the biological aviation kerosene satisfying usage conditions is prepared by virtue of mild reaction conditions.

公开(公告)号：US09790439B2

公开(公告)日：2017-10-17

申请号：US13699328

申请日：2011-05-23

申请人： Jaakko Nousiainen ,  Pekka Knuuttila ,  Arto Rissanen

发明人： Jaakko Nousiainen ,  Pekka Knuuttila ,  Arto Rissanen

IPC分类号： C10L1/02 ,  B01J8/00 ,  C10G45/60 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  C10G3/00

CPC分类号： C10G45/60 ,  C10G3/46 ,  C10G3/48 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2300/802 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

摘要： The present invention relates to a process for producing mixture of fuel components, which process comprises providing a feed of biological origin; subjecting said feed of biological origin and a hydrogen gas feed to a single step of hydroprocessing in the presence of a catalyst system comprising dewaxing catalyst to form a mixture of fuel components. The present invention relates also to an apparatus for producing a mixture of fuel components from a feed of biological origin. The invention relates also to the use of the fuel components.

公开(公告)号：US20170130134A1

公开(公告)日：2017-05-11

申请号：US15319194

申请日：2015-06-29

申请人： SHELL OIL COMPANY

发明人： Vikrant Nanasaheb URADE ,  Laxmi Narasimhan CHILKOOR SOUNDARARAJAN ,  Madhusudhan Rao PANCHAGNULA ,  Alan Anthony DEL PAGGIO

IPC分类号： C10G1/00 ,  C10K3/04 ,  C10G3/00 ,  C10G1/06 ,  C10G1/10

CPC分类号： C10G1/002 ,  C10G1/06 ,  C10G1/086 ,  C10G1/10 ,  C10G3/42 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/202 ,  C10K1/004 ,  C10K3/04 ,  Y02P30/20

摘要： The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein the one or more active metals are present in an oxidic state; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600° C. and a pressure in the range of from 0.50 to 7.50 MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), to produce a vapour phase product 25 comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1-C3 gases.

公开(公告)号：US09617479B2

公开(公告)日：2017-04-11

申请号：US14573081

申请日：2014-12-17

申请人： Bradley R. Fingland ,  Joseph Emmanuel Gatt

发明人： Bradley R. Fingland ,  Joseph Emmanuel Gatt

IPC分类号： C07C1/00 ,  C10G1/00 ,  C10G73/02 ,  C10G53/00 ,  C10G3/00 ,  C10G45/12 ,  C10G45/10 ,  C10G45/06 ,  C10G69/02 ,  C10L1/08 ,  C10L10/14 ,  C07C7/04 ,  B01J23/85

CPC分类号： C10G3/50 ,  B01J23/85 ,  C07C7/04 ,  C10G3/44 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G69/02 ,  C10G2300/1014 ,  C10L1/08 ,  C10L10/14 ,  C10L2200/0469 ,  C10L2270/026 ,  Y02E50/13 ,  Y02P20/52 ,  Y02P30/20 ,  C07C11/06

摘要： Feeds containing triglycerides are processed to produce a diesel fuel product and propylene. The diesel product and propylene are generated by deoxygenating the triglyceride-containing feed using processing conditions that enhance preservation of olefins that are present in the triglycerides. The triglyceride-containing feed is processed in the presence of a catalyst containing a Group VI metal and a Group VIII non-noble metal and in the presence of CO.

公开(公告)号：US20160332941A1

公开(公告)日：2016-11-17

申请号：US15217715

申请日：2016-07-22

申请人： Virent, Inc.

发明人： Taylor Beck ,  Brian Blank ,  Casey Jones ,  Elizabeth Woods ,  Randy Cortright

IPC分类号： C07C29/60 ,  C07C45/00 ,  C10G3/00 ,  C07C51/377 ,  B01J23/835 ,  B01J23/652

CPC分类号： C07B35/06 ,  B01J21/066 ,  B01J23/14 ,  B01J23/6527 ,  B01J23/755 ,  B01J23/835 ,  B01J23/888 ,  B01J29/46 ,  B01J29/90 ,  B01J37/0201 ,  B01J37/0213 ,  B01J38/02 ,  B01J38/12 ,  C07C1/2072 ,  C07C1/24 ,  C07C29/60 ,  C07C45/002 ,  C07C51/377 ,  C07D301/02 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G3/50 ,  C10G2300/1014 ,  C10G2400/30 ,  Y02P20/584 ,  Y02P20/588 ,  Y02P30/20

摘要： Methods, catalysts, and reactor systems for producing in high yield aromatic chemicals and liquid fuels from a mixture of oxygenates comprising di- and polyoxygenates are disclosed. Also disclosed are methods, catalysts, and reactor systems for producing aromatic chemicals and liquid fuels from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like; and methods, catalysts, and reactor systems for producing the mixture of oxygenates from oxygenated hydrocarbons such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like. The disclosed catalysts for preparing the mixture of oxygenates comprise a NinSnm alloy and a crystalline alumina support.

摘要翻译： 公开了用于从含有二氧化物和聚氧化物的含氧化合物的混合物中生产高产率芳族化学品和液体燃料的方法，催化剂和反应器系统。 还公开了用于从碳氢化合物如碳水化合物，糖，糖醇，糖分解产物等产生芳族化合物和液体燃料的方法，催化剂和反应器系统; 以及用于从氧化烃如碳水化合物，糖，糖醇，糖降解产物等产生含氧化合物的混合物的方法，催化剂和反应器系统。 所公开的用于制备含氧化合物混合物的催化剂包括NinSnm合金和结晶氧化铝载体。

公开(公告)号：US09433936B2

公开(公告)日：2016-09-06

申请号：US14196019

申请日：2014-03-04

申请人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partidge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia

发明人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partidge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia

IPC分类号： B01J29/06 ,  B01J29/76 ,  B01J29/12 ,  B01J29/74 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/78 ,  C10G45/64 ,  C10G45/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G3/00 ,  B01J37/00

CPC分类号： B01J29/7661 ,  B01J29/12 ,  B01J29/126 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/7861 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/44 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G45/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P30/20

摘要： Provided are catalysts including: a zeolite component selected from zeolites having 10-member ring pores, zeolites having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component selected from tantalum oxide, tungsten oxide, molybdenum oxide, vanadium oxide, magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, niobium oxide, tungstated zirconia, cobalt molybdenum oxide, cobalt molybdenum sulfide, nickel molybdenum oxide, nickel molybdenum sulfide, nickel tungsten oxide, nickel tungsten sulfide, cobalt tungsten oxide, cobalt tungsten sulfide, nickel molybdenum tungsten oxide and nickel molybdenum tungsten sulfide, cobalt molybdenum tungsten oxide and cobalt molybdenum tungsten sulfide, wherein the weight ratio of the zeolite to the hydrothermally stable binder is 85:15 to 25:75.

摘要翻译： 提供的催化剂包括：选自具有10元环孔的沸石的沸石组分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co的氢化组分 ，Mo，W，Rh，Re，Ru，Ir及其混合物，以及选自氧化钽，氧化钨，氧化钼，氧化钒，氧化镁，氧化钙，氧化钇，氧化镧，铈的水热稳定的粘合剂成分 氧化物，氧化铌，钨酸氧化锆，钴钼氧化物，钴硫化钼，镍钼氧化物，镍钼硫化物，镍钨氧化物，镍硫化钨，钴钨氧化物，硫化钴硫化物，镍钼钨氧化物和镍钼硫化钨， 钴钼氧化钨和钴钼硫化钨，其中沸石与水热稳定粘合剂的重量比为85:15至25:75。

公开(公告)号：US20160096996A1

公开(公告)日：2016-04-07

申请号：US14968344

申请日：2015-12-14

申请人： Virent, Inc.

发明人： Ming Qiao ,  Elizabeth Woods ,  Paul Myren ,  Randy Cortright ,  John Kania

IPC分类号： C10G1/06 ,  C07C1/24 ,  C10G3/00

CPC分类号： C10G1/065 ,  C07C1/24 ,  C10G3/42 ,  C10G3/44 ,  C10G3/48 ,  C10G3/49 ,  C10G3/52 ,  C10G3/62 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/305 ,  C10G2300/308 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/30 ,  C10L1/04 ,  C10L1/06 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

摘要： The present invention provides methods, reactor systems, and catalysts for converting in a continuous process biomass to fuels and chemicals. The invention includes methods of converting the water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C2+O1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C2+O1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

公开(公告)号：US09278346B2

公开(公告)日：2016-03-08

申请号：US13557475

申请日：2012-07-25

申请人： Wenqin Shen ,  Alguo Liu ,  Wayne Turbeville

发明人： Wenqin Shen ,  Alguo Liu ,  Wayne Turbeville

IPC分类号： B01J23/44 ,  B01J23/42 ,  B01J35/00 ,  B01J37/02 ,  B01J23/847 ,  B01J23/889 ,  B01J21/06 ,  B01J23/14 ,  B01J23/28 ,  B01J23/36 ,  B01J23/46 ,  B01J23/63 ,  B01J23/648 ,  B01J23/652 ,  B01J23/656 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J37/00 ,  C10L1/04 ,  C10G3/00

CPC分类号： B01J35/002 ,  B01J21/066 ,  B01J23/14 ,  B01J23/28 ,  B01J23/36 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/466 ,  B01J23/468 ,  B01J23/63 ,  B01J23/6482 ,  B01J23/6484 ,  B01J23/6486 ,  B01J23/6525 ,  B01J23/6527 ,  B01J23/6562 ,  B01J23/6567 ,  B01J23/72 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8472 ,  B01J23/8474 ,  B01J23/8476 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8892 ,  B01J23/8896 ,  B01J37/0009 ,  B01J37/0207 ,  B01J37/0242 ,  C10G3/47 ,  C10G3/48 ,  C10G3/52 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10L1/04 ,  Y02P30/20

摘要： A hydrodeoxygenation catalyst comprises a metal catalyst, an acid promoter, and a support. The metal catalyst is selected from platinum, palladium, ruthenium, rhenium rhodium, osmium, iridium, nickel, cobalt, molybdenum, copper, tin, or mixtures thereof. The support is a promoted-zirconium material including texture promoters and acid promoters. The hydrodeoxygenation catalyst may be used for hydrodeoxygenation (HDO) of sugar or sugar alcohol in an aqueous solution. In one embodiment the HDO catalyst may be used for HDO of fatty acids such as fatty acid methyl esters (FAME), triglycerols (in plant oil and animal fat), pyrolysis oil, or lignin. The hydrodeoxygenation catalyst for fatty acid process does not require the use of an acid promoter, it is optional.

摘要翻译： 加氢脱氧催化剂包括金属催化剂，酸促进剂和载体。 金属催化剂选自铂，钯，钌，铑铑，锇，铱，镍，钴，钼，铜，锡或其混合物。 载体是促进锆材料，包括纹理启动子和酸促进剂。 加氢脱氧催化剂可用于水溶液中糖或糖醇的加氢脱氧（HDO）。 在一个实施方案中，HDO催化剂可用于脂肪酸的HDO，例如脂肪酸甲酯（FAME），甘油三酯（植物油和动物脂肪），热解油或木质素。 用于脂肪酸方法的加氢脱氧催化剂不需要使用酸促进剂，它是任选的。