公开(公告)号：US20140066536A1

公开(公告)日：2014-03-06

申请号：US13598832

申请日：2012-08-30

Applicant: Rick L. Adkins ,  Shriniwas S. Chauk ,  James R. Charron

Inventor： Rick L. Adkins ,  Shriniwas S. Chauk ,  James R. Charron

IPC: C08G65/26 ,  C08G18/50 ,  C08J9/04

CPC classification number: C08J9/04 ,  C08F283/06 ,  C08G18/632 ,  C08G18/636 ,  C08J2375/08 ,  C08F212/08 ,  C08F220/44

Abstract: This invention relates to polymer polyols comprising one or more base polyols; one or more ethylenically unsaturated monomers in which at least one of the monomers is styrene which contains less than or equal to 1000 ppm of impurities; with one or more preformed stabilizers; in the presence of at least one free radical polymerization initiator; and optionally, one or more chain transfer agents.

Abstract translation: 本发明涉及包含一种或多种碱性多元醇的聚合物多元醇; 一种或多种烯键式不饱和单体，其中至少一种单体是含有小于或等于1000ppm杂质的苯乙烯; 与一个或多个预制稳定剂; 在至少一种自由基聚合引发剂的存在下; 和任选的一种或多种链转移剂。

公开(公告)号：US08383733B2

公开(公告)日：2013-02-26

申请号：US13285057

申请日：2011-10-31

Applicant: Rick L. Adkins ,  Shriniwas S. Chauk

Inventor： Rick L. Adkins ,  Shriniwas S. Chauk

IPC: C08F4/00 ,  C08F2/00 ,  C08F4/32 ,  C08J9/00

CPC classification number: C08F283/06 ,  C08F290/06 ,  C08F290/14

Abstract: The present invention relates to novel polymer polyols which have low viscosities and high hydroxyl numbers, and to a process for the preparation of these novel polymer polyols. These polymer polyols have hydroxyl numbers of ≧20, solids contents of about 30 to about 65% by weight and a viscosity that is less than or equal to: be[2.7c]. These comprise the reaction product of a base polyol, a preformed stabilizer and at least one ethylenically unsaturated monomer, in the presence of a free-radical polymerization initiator and at least one polymer control agent. The base polyol has a hydroxyl number of 60 to 1900, a functionality of 1 to 10, and an equivalent weight of 30 to 900.

Abstract translation: 本发明涉及具有低粘度和高羟值的新型聚合物多元醇，以及制备这些新型聚合物多元醇的方法。 这些聚合物多元醇的羟值为≥20，固体含量为约30至约65重量％，粘度小于或等于：[2.7c]。 这些包括在自由基聚合引发剂和至少一种聚合物控制剂的存在下的基础多元醇，预制的稳定剂和至少一种烯属不饱和单体的反应产物。 基础多元醇的羟值为60〜1900，官能度为1〜10，当量为30〜900。

公开(公告)号：US20120041144A1

公开(公告)日：2012-02-16

申请号：US13285057

申请日：2011-10-31

Applicant: RICK L. ADKINS ,  Shriniwas S. Chauk

Inventor： RICK L. ADKINS ,  Shriniwas S. Chauk

IPC: C08K5/06 ,  C08L25/12

CPC classification number: C08F283/06 ,  C08F290/06 ,  C08F290/14

Abstract: The present invention relates to novel polymer polyols which have low viscosities and high hydroxyl numbers, and to a process for the preparation of these novel polymer polyols. These polymer polyols have hydroxyl numbers of 20, solids contents of about 30 to about 65% by weight and a viscosity that is less than or equal to: be[12.7c]. These comprise the reaction product of a base polyol, a preformed stabilizer and at least one ethylenically unsaturated monomer, in the presence of a free-radical polymerization initiator and at least one polymer control agent. The base polyol has a hydroxyl number of 60 to 1900, a functionality of 1 to 10, and an equivalent weight of 30 to 900.

Abstract translation: 本发明涉及具有低粘度和高羟值的新型聚合物多元醇，以及制备这些新型聚合物多元醇的方法。 这些聚合物多元醇的羟值为20，固体含量为约30至约65重量％，粘度小于或等于：[12.7c]。 这些包括在自由基聚合引发剂和至少一种聚合物控制剂的存在下的基础多元醇，预制的稳定剂和至少一种烯属不饱和单体的反应产物。 基础多元醇的羟值为60〜1900，官能度为1〜10，当量为30〜900。

公开(公告)号：US07456229B2

公开(公告)日：2008-11-25

申请号：US11443811

申请日：2006-05-31

Applicant: Stanley L. Hager ,  Rick L. Adkins ,  Shriniwas S. Chauk

Inventor： Stanley L. Hager ,  Rick L. Adkins ,  Shriniwas S. Chauk

IPC: C08G18/00

CPC classification number: C08G18/4072 ,  C08G18/632 ,  C08G2101/0016 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

Abstract: This invention relates to a process for the production of rigid and semi-rigid foams at low isocyanate levels, and to the foams produced by this process. The process comprises reacting a polyisocyanate component with an isocyanate-reactive component, in the presence of at least one blowing agent, at least one surfactant and at least one catalyst. Suitable isocyanate-reactive components are characterized as having a solids content of at least 40% by weight, and an overall hydroxyl number of the remaining liquid, non-solids portion of at least 160. In addition, the isocyanate-reactive component comprises at least 50% by weight of a polymer polyol having a solids content of at least 30% by weight and in which the base polyol has a hydroxyl number of at least 75.

Abstract translation: 本发明涉及用于生产低异氰酸酯水平的刚性和半刚性泡沫以及通过该方法生产的泡沫的方法。 该方法包括在至少一种发泡剂，至少一种表面活性剂和至少一种催化剂的存在下使多异氰酸酯组分与异氰酸酯反应性组分反应。 合适的异氰酸酯反应性组分的特征在于固体含量为至少40重量％，剩余液体，非固体部分的总羟基数至少为160.此外，异氰酸酯反应性组分至少包含 50重量％的固体含量为至少30重量％的聚合物多元醇，其中基础多元醇的羟值为至少75。

公开(公告)号：US20070282029A1

公开(公告)日：2007-12-06

申请号：US11443811

申请日：2006-05-31

Applicant: Stanley L. Hager ,  Rick L. Adkins ,  Shriniwas S. Chauk

Inventor： Stanley L. Hager ,  Rick L. Adkins ,  Shriniwas S. Chauk

IPC: C08G18/00

CPC classification number: C08G18/4072 ,  C08G18/632 ,  C08G2101/0016 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2101/0083

Abstract: This invention relates to a process for the production of rigid and semi-rigid foams at low isocyanate levels, and to the foams produced by this process. The process comprises reacting a polyisocyanate component with an isocyanate-reactive component, in the presence of at least one blowing agent, at least one surfactant and at least one catalyst. Suitable isocyanate-reactive components are characterized as having a solids content of at least 40% by weight, and an overall hydroxyl number of the remaining liquid, non-solids portion of at least 160. In addition, the isocyanate-reactive component comprises at least 50% by weight of a polymer polyol having a solids content of at least 30% by weight and in which the base polyol has a hydroxyl number of at least 75.

Abstract translation: 本发明涉及用于生产低异氰酸酯水平的刚性和半刚性泡沫以及通过该方法生产的泡沫的方法。 该方法包括在至少一种发泡剂，至少一种表面活性剂和至少一种催化剂的存在下使多异氰酸酯组分与异氰酸酯反应性组分反应。 合适的异氰酸酯反应性组分的特征在于固体含量为至少40重量％，剩余液体，非固体部分的总羟基数至少为160.此外，异氰酸酯反应性组分至少包含 50重量％的固体含量为至少30重量％的聚合物多元醇，其中基础多元醇的羟值为至少75。

公开(公告)号：US07759423B2

公开(公告)日：2010-07-20

申请号：US10909493

申请日：2004-08-02

Applicant: Shriniwas S. Chauk

Inventor： Shriniwas S. Chauk

IPC: C08G18/63

CPC classification number: C08G18/702 ,  C08F283/06 ,  C08F290/062 ,  C08G18/632 ,  C08G18/636 ,  C08G18/672 ,  C08G18/68 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  C08G18/48

Abstract: The present invention relates to ultra-high solids content polymer polyols which have good filterability while maintaining a reasonable viscosity, and to a process for the preparation of these ultra-high solids contents polymer polyols. These polymer polyols comprise the free-radical polymerization product of (A) a base polyol, (B) a pre-formed stabilizer, (C) at least one ethylenically unsaturated monomer, (D) at least one free-radical polymerization initiator, and (E) at least one chain transfer agent. The solids contents varies from 60% to about 85% by weight.

Abstract translation: 本发明涉及具有良好过滤性同时保持合理粘度的超高固含量聚合物多元醇，以及制备这些超高固含量聚合物多元醇的方法。 这些聚合物多元醇包含（A）基础多元醇，（B）预成形稳定剂，（C）至少一种烯属不饱和单体，（D）至少一种自由基聚合引发剂和 （E）至少一种链转移剂。 固体含量在60％至85％之间变化。