公开(公告)号：US20180022882A1

公开(公告)日：2018-01-25

申请号：US15552338

申请日：2016-03-14

Applicant: RIMTEC CORPORATION

Inventor： Nobuto Kamei

IPC: C08J7/04 ,  C08J5/00

CPC classification number: C08J7/04 ,  B29K2023/38 ,  B32B27/00 ,  B32B27/34 ,  C08J5/00 ,  C08J7/047 ,  C08J2365/00 ,  C08J2479/08

Abstract: A resin molded article wherein a surface of a norbornene-based crosslinked polymer comprising at least one member selected from the group consisting of dicyclopentadiene-based monomer units, tetracyclododecene-based monomer units, and tricyclopentadiene-based monomer units in an amount of 50% by mass or more is coated with a polyamide-imide layer, and a method for producing the same. Since the resin molded article of the present invention has highly excellent heat resistance and durability, the resin molded article can be suitably used in applications that require heat resistance such as engine cover applications for automobiles and the like, and electric insulation applications.

公开(公告)号：US20160244540A1

公开(公告)日：2016-08-25

申请号：US15025113

申请日：2014-09-19

Applicant: RIMTEC CORPORATION

Inventor： Nobuto Kamei

IPC: C08F132/08

CPC classification number: C08F132/08 ,  C08G61/08 ,  C08G2261/135 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/592 ,  C08G2261/65 ,  C08G2261/76 ,  H01L23/293

Abstract: The present invention relates to a norbornene-based crosslinked polymer containing at least one member selected from the group consisting of dicyclopentadiene-based monomer units, tetracyclododecene-based monomer units, and tricyclopentadiene-based monomer units in an amount of 50% by mass or more, wherein the norbornene-based crosslinked polymer has a glass transition temperature of 240° C. or higher. Further, the present invention relates to a method for producing a norbornene-based crosslinked polymer as defined above, including step (1): heating a blend containing at least one member of the above monomer components, and a metathesis polymerization catalyst to a temperature lower than a deactivation temperature of the metathesis polymerization catalyst to carry out a primary curing; and step (2): heating a cured product obtained in the step (1) to a temperature equal to or higher than the deactivation temperature of the above metathesis polymerization catalyst to carry out a secondary curing.

Abstract translation: 本发明涉及含有50质量％以上的选自二环戊二烯类单体单元，四环十二碳烯类单体单元和三环戊二烯系单体单元中的至少一种的降冰片烯系交联聚合物 其中，所述降冰片烯系交联聚合物的玻璃化转变温度为240℃以上。 此外，本发明涉及如上所述的降冰片烯系交联聚合物的制造方法，其包括步骤（1）：将含有至少一种上述单体成分的共混物和易位聚合催化剂加热至低于 比易位聚合催化剂的去活化温度进行初级固化; 和步骤（2）：将步骤（1）中获得的固化产物加热至等于或高于上述易位聚合催化剂的失活温度的温度，进行二次固化。

公开(公告)号：US20190169329A1

公开(公告)日：2019-06-06

申请号：US16266378

申请日：2019-02-04

Applicant: RIMTEC CORPORATION

Inventor： Nobuto Kamei

IPC: C08F132/08 ,  C08G61/08 ,  H01L23/29

Abstract: The present invention relates to a norbornene-based crosslinked polymer containing at least one member selected from the group consisting of dicyclopentadiene-based monomer units, tetracyclododecene-based monomer units, and tricyclopentadiene-based monomer units in an amount of 50% by mass or more, wherein the norbornene-based crosslinked polymer has a glass transition temperature of 240° C. or higher. Further, the present invention relates to a method for producing a norbomene-based crosslinked polymer as defined above, including step (1): heating a blend containing at least one member of the above monomer components, and a metathesis polymerization catalyst to a temperature lower than a deactivation temperature of the metathesis polymerization catalyst to carry out a primary curing; and step (2): heating a cured product obtained in the step (1) to a temperature equal to or higher than the deactivation temperature of the above metathesis polymerization catalyst to carry out a secondary curing.

公开(公告)号：US20180319912A1

公开(公告)日：2018-11-08

申请号：US16030444

申请日：2018-07-09

Applicant: RIMTEC CORPORATION

Inventor： Nobuto Kamei

IPC: C08F132/08 ,  C08G61/08 ,  H01L23/29

CPC classification number: C08F132/08 ,  C08G61/08 ,  C08G2261/135 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/592 ,  C08G2261/65 ,  C08G2261/76 ,  H01L23/293

Abstract: The present invention relates to a norbornene-based crosslinked polymer containing at least one member selected from the group consisting of dicyclopentadiene-based monomer units, tetracyclododecene-based monomer units, and tricyclopentadiene-based monomer units in an amount of 50% by mass or more, wherein the norbornene-based crosslinked polymer has a glass transition temperature of 240° C. or higher. Further, the present invention relates to a method for producing a norbornene-based crosslinked polymer as defined above, including step (1): heating a blend containing at least one member of the above monomer components, and a metathesis polymerization catalyst to a temperature lower than a deactivation temperature of the metathesis polymerization catalyst to carry out a primary curing; and step (2): heating a cured product obtained in the step (1) to a temperature equal to or higher than the deactivation temperature of the above metathesis polymerization catalyst to carry out a secondary curing.

公开(公告)号：US09777086B2

公开(公告)日：2017-10-03

申请号：US14431150

申请日：2013-09-25

Applicant: RIMTEC CORPORATION

Inventor： Naoki Nishioka ,  Nobuto Kamei

IPC: C08G61/08 ,  C08F132/08 ,  C09D165/00 ,  C08L65/00

CPC classification number: C08F132/08 ,  C08G61/08 ,  C08G2261/3324 ,  C08G2261/418 ,  C08G2261/59 ,  C08L65/00 ,  C09D165/00

Abstract: A polymerizable composition comprised of a mixture of a norbornene-based monomer and a metathesis polymerization catalyst which is solidified by cooling is provided. Preferably, the norbornene-based monomer has a freezing point of 20° C. or more, more preferably the metathesis polymerization catalyst is a ruthenium-carbene complex. According to the present invention, it is possible to provide a polymerizable composition which is excellent in storage stability and which enables industrial production of small resin shaped articles which are excellent in stability of quality.

公开(公告)号：US20150240007A1

公开(公告)日：2015-08-27

申请号：US14431150

申请日：2013-09-25

Applicant: RIMTEC CORPORATION

Inventor： Naoki Nishioka ,  Nobuto Kamei

IPC: C08F132/08

CPC classification number: C08F132/08 ,  C08G61/08 ,  C08G2261/3324 ,  C08G2261/418 ,  C08G2261/59 ,  C08L65/00 ,  C09D165/00

Abstract: A polymerizable composition comprised of a mixture of a norbornene-based monomer and a metathesis polymerization catalyst which is solidified by cooling is provided. Preferably, the norbornene-based monomer has a freezing point of 20° C. or more, more preferably the metathesis polymerization catalyst is a ruthenium-carbene complex. According to the present invention, it is possible to provide a polymerizable composition which is excellent in storage stability and which enables industrial production of small resin shaped articles which are excellent in stability of quality.

Abstract translation: 提供由降冰片烯系单体和通过冷却固化的易位聚合催化剂的混合物组成的聚合性组合物。 优选地，所述降冰片烯系单体的凝固点为20℃以上，更优选所述易位聚合催化剂为钌 - 卡宾络合物。 根据本发明，可以提供一种储存稳定性优异的聚合性组合物，能够实现质量稳定性优异的小型树脂成形体的工业化生产。