公开(公告)号：US20130142726A1

公开(公告)日：2013-06-06

申请号：US13750722

申请日：2013-01-25

申请人： Rajesh Bhaskar Biniwale ,  Jayshri Vijay Pande ,  Anshu Ajit Shukla

发明人： Rajesh Bhaskar Biniwale ,  Jayshri Vijay Pande ,  Anshu Ajit Shukla

IPC分类号： C01B3/32

CPC分类号： C01B3/326 ,  B01J21/18 ,  B01J23/42 ,  B01J23/464 ,  B01J23/50 ,  B01J23/63 ,  B01J23/6482 ,  B01J23/66 ,  B01J35/06 ,  B01J37/0211 ,  C01B3/26 ,  C07C5/325 ,  H01M8/065 ,  Y02E60/50 ,  Y02P20/133 ,  Y02P20/582

摘要： Hydrogenated liquid organic compounds are used for storage and supply of hydrogen at near ambient conditions. The hydrogen is released from the hydrogenated liquid organic compounds through a catalytic dehydrogenation reaction using a M/support or M-M′/support catalyst. The M/support catalyst comprises a metal M selected from Pt, Pd, Rh, Ru, Ir, Os, or combination thereof, and a support selected from Y2O3 or V2O5 or combinations thereof. The M-M′/support catalyst comprises a first metal M selected from Cu, Ag, Au, or combination thereof, a second metal M′ selected from Pt, Pd, Rh, Ru, Ir, Os, Fe, Ni, Re, Mo, W, V, Cr, Co or combinations thereof, and a support selected from activated carbon, alumina, alumite, zirconia, silica or combination thereof. Synergistic effects are created by using the combination of the M and M′ in the catalyst, which result in shifting of the equilibrium of the reaction favorably to dehydrogenation.

摘要翻译： 氢化液体有机化合物用于在接近环境条件下储存和供应氢气。 通过使用M /载体或M-M'/载体催化剂的催化脱氢反应，氢从氢化液体有机化合物中释放出来。 M /载体催化剂包括选自Pt，Pd，Rh，Ru，Ir，Os或其组合的金属M，以及选自Y 2 O 3或V 2 O 5的载体或其组合。 M-M'/载体催化剂包括选自Cu，Ag，Au或其组合的第一金属M，选自Pt，Pd，Rh，Ru，Ir，Os，Fe，Ni，Re， Mo，W，V，Cr，Co或其组合，以及选自活性炭，氧化铝，耐酸铝，氧化锆，二氧化硅或其组合的载体。 通过在催化剂中使用M和M'的组合产生协同效应，这导致反应平衡有利地转化为脱氢。

公开(公告)号：US09005571B2

公开(公告)日：2015-04-14

申请号：US13750722

申请日：2013-01-25

申请人： Rajesh Bhaskar Biniwale ,  Jayshri Vijay Pande ,  Anshu Ajit Shukla

发明人： Rajesh Bhaskar Biniwale ,  Jayshri Vijay Pande ,  Anshu Ajit Shukla

IPC分类号： C01B3/26 ,  C01B3/32 ,  B01J23/42 ,  B01J23/46 ,  B01J23/50 ,  B01J23/63 ,  B01J23/648 ,  B01J23/66 ,  B01J35/06 ,  B01J37/02 ,  C07C5/32 ,  H01M8/06 ,  B01J21/18

CPC分类号： C01B3/326 ,  B01J21/18 ,  B01J23/42 ,  B01J23/464 ,  B01J23/50 ,  B01J23/63 ,  B01J23/6482 ,  B01J23/66 ,  B01J35/06 ,  B01J37/0211 ,  C01B3/26 ,  C07C5/325 ,  H01M8/065 ,  Y02E60/50 ,  Y02P20/133 ,  Y02P20/582

摘要： Hydrogenated liquid organic compounds are used for storage and supply of hydrogen at near ambient conditions. The hydrogen is released from the hydrogenated liquid organic compounds through a catalytic dehydrogenation reaction using a M/support or M-M′/support catalyst. The M/support catalyst comprises a metal M selected from Pt, Pd, Rh, Ru, Ir, Os, or combination thereof, and a support selected from Y2O3 or V2O5 or combinations thereof. The M-M′/support catalyst comprises a first metal M selected from Cu, Ag, Au, or combination thereof, a second metal M′ selected from Pt, Pd, Rh, Ru, Ir, Os, Fe, Ni, Re, Mo, W, V, Cr, Co or combinations thereof, and a support selected from activated carbon, alumina, alumite, zirconia, silica or combination thereof. Synergistic effects are created by using the combination of the M and M′ in the catalyst, which result in shifting of the equilibrium of the reaction favorably to dehydrogenation.

摘要翻译： 氢化液体有机化合物用于在接近环境条件下储存和供应氢气。 通过使用M /载体或M-M'/载体催化剂的催化脱氢反应，氢从氢化液体有机化合物中释放出来。 M /载体催化剂包括选自Pt，Pd，Rh，Ru，Ir，Os或其组合的金属M，以及选自Y 2 O 3或V 2 O 5的载体或其组合。 MM'/载体催化剂包括选自Cu，Ag，Au或其组合的第一金属M，选自Pt，Pd，Rh，Ru，Ir，Os，Fe，Ni，Re，Mo， W，V，Cr，Co或其组合，以及选自活性炭，氧化铝，耐酸铝，氧化锆，二氧化硅或其组合的载体。 通过在催化剂中使用M和M'的组合产生协同效应，这导致反应平衡有利地转化为脱氢。