公开(公告)号：US20180229299A1

公开(公告)日：2018-08-16

申请号：US15896595

申请日：2018-02-14

Applicant: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ARKANSAS

Inventor： Cameron Crane ,  Jingyi Chen ,  Feng Wang

IPC: B22F1/02 ,  B01J23/72 ,  B01J21/08 ,  B01J35/00 ,  B01J37/02 ,  C10M125/04 ,  C10M125/26 ,  A61K41/00 ,  A61K49/00 ,  A01N25/28 ,  A01N59/20 ,  G01N21/552 ,  G01N21/65 ,  B22F1/00

CPC classification number: B22F1/02 ,  A01N25/28 ,  A01N59/20 ,  A61K41/0052 ,  A61K49/0002 ,  B01J21/08 ,  B01J23/72 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J37/0211 ,  B01J37/0221 ,  B22F1/0018 ,  B22F1/0025 ,  B22F1/0062 ,  B22F2001/0037 ,  B22F2301/10 ,  B22F2302/256 ,  B22F2304/054 ,  B82Y5/00 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C10M125/04 ,  C10M125/26 ,  C10M2201/05 ,  C10M2201/105 ,  C10N2210/01 ,  C10N2220/082 ,  G01N21/554 ,  G01N21/658 ,  Y10S977/773 ,  Y10S977/81 ,  Y10S977/892 ,  Y10S977/915 ,  Y10S977/927 ,  Y10S977/954

Abstract: In one aspect, compositions comprising copper-silica (Cu—SiO2) core-shell nanoparticles are described herein. The core-shell nanoparticles comprise copper (Cu) core components and silica (SiO2) shell components encapsulating the core components. In some embodiments, the nanoparticle compositions comprise a continuous aqueous phase and a population of copper-silica (Cu—SiO2) core-shell nanoparticles dispersed in the aqueous phase.

公开(公告)号：US20180207620A1

公开(公告)日：2018-07-26

申请号：US15933903

申请日：2018-03-23

Applicant: Umicore AG & Co. KG

Inventor： Maximilian Biberger ,  Bryant Kearl ,  Qinghua Yin ,  Xiwang Qi ,  David Leamon

IPC: B01J23/63 ,  B01J37/02 ,  B01J37/34 ,  B01D53/94 ,  B01J37/00 ,  B01J37/08 ,  B01J35/00

CPC classification number: B01J23/63 ,  B01D53/9422 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2042 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/908 ,  B01D2255/9202 ,  B01J35/0013 ,  B01J37/0018 ,  B01J37/0211 ,  B01J37/0215 ,  B01J37/0234 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/08 ,  B01J37/349 ,  B01J2523/00 ,  B01J2523/25 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/822 ,  B01J2523/31

Abstract: The present disclosure relates to micron-sized particle used for catalyzing and storing NOx gases, such as those found in vehicle exhaust emissions, washcoats employing micron-sized particle used for catalyzing and storing NOx gases, washcoat coated substrates, lean NOx trap (LNT) systems, and vehicles using such systems. Also provided are methods of preparing micron-sized particle used for catalyzing and storing NOx gases, as well as preparation of washcoats and coated substrates. More specifically, the present disclosure relates to a lean NOx trapping materials, wherein the materials include a NOx catalytic component attached to a micron-sized carrier particle and a NOx storage component, as well as washcoats and coated substrates useful in the treatment of exhaust gases. In some embodiments, a portion of the NOx storage component is attached to the micron-sized carrier particle.

公开(公告)号：US09808791B2

公开(公告)日：2017-11-07

申请号：US14404561

申请日：2013-05-29

Applicant: TOTO LTD.

Inventor： Hiromasa Tokudome ,  Sayuri Okunaka

IPC: B01J23/58 ,  C01B3/04 ,  C01B3/06 ,  C01G23/00 ,  B82Y30/00 ,  B01J37/03 ,  B01J21/06 ,  B01J23/46 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  B01J19/12

CPC classification number: B01J23/58 ,  B01J19/127 ,  B01J21/063 ,  B01J23/464 ,  B01J35/004 ,  B01J35/023 ,  B01J37/0211 ,  B01J37/033 ,  B01J37/036 ,  B82Y30/00 ,  C01B3/04 ,  C01B3/042 ,  C01B3/06 ,  C01G23/006 ,  C01P2002/50 ,  C01P2002/54 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/64 ,  Y02E60/364 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/47 ,  B01J2523/822

Abstract: Disclosed is a visible light responsive photocatalyst that simultaneously realizes high crystallinity and refinement of primary particles. Also disclosed is a photocatalyst composed of secondary particles that have a high porosity and are aggregates of fine primary particles. Rhodium-doped strontium titanate that is a visible light responsive photocatalyst of the present invention has a primary particle diameter of not more than 70 nm and has a absorbance at a wavelength of 570 nm of not less than 0.6 and a absorbance at a wavelength of 1800 nm of not more than 0.7, each absorbance determining by measuring a diffuse reflection spectrum, the rhodium-doped strontium titanate having a high water-splitting activity as a photocatalyst.

公开(公告)号：US09744523B2

公开(公告)日：2017-08-29

申请号：US14502724

申请日：2014-09-30

Applicant: SABIC Global Technologies B.V.

Inventor： Hicham Idriss ,  Ahmed Khaja Wahab ,  Maher Al-Oufi ,  Geoff Waterhouse

IPC: B01J21/06 ,  B01J23/52 ,  C01B3/04 ,  B01J37/16 ,  B01J23/38 ,  B01J35/00 ,  C25B1/00 ,  B01J37/02 ,  B01J35/10 ,  C01B13/02 ,  B01J23/66 ,  B01J23/40

CPC classification number: B01J23/52 ,  B01J21/063 ,  B01J23/38 ,  B01J23/40 ,  B01J23/66 ,  B01J35/0013 ,  B01J35/004 ,  B01J35/006 ,  B01J35/1014 ,  B01J37/0211 ,  B01J37/0242 ,  B01J37/16 ,  C01B3/042 ,  C01B13/0207 ,  C25B1/003 ,  Y02E60/364 ,  Y02E60/368 ,  Y10T428/2991

Abstract: Disclosed is a photocatalyst, and methods for its use, that includes a photoactive material comprising a photonic band gap and an electronic band gap, wherein the photonic band gap at least partially overlaps with the electronic band gap, and an electrically conductive material deposited on the photoactive material.

公开(公告)号：US20170120222A1

公开(公告)日：2017-05-04

申请号：US15339082

申请日：2016-10-31

Applicant: SK INNOVATION CO., LTD. ,  KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Tae Jin KIM ,  Chang Q LEE ,  Young Eun CHEON ,  Ju Hwan IM ,  Min Kee CHOI

IPC: B01J23/63 ,  B01J21/04 ,  C07C5/333 ,  B01J37/04 ,  B01J37/02 ,  B01J37/08 ,  B01J23/62 ,  B01J35/00

CPC classification number: B01J23/63 ,  B01J21/04 ,  B01J23/002 ,  B01J23/62 ,  B01J23/96 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0211 ,  B01J37/036 ,  B01J37/04 ,  B01J37/08 ,  B01J38/12 ,  B01J2523/00 ,  C07C5/48 ,  C07C2521/04 ,  C07C2523/08 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2523/63 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06 ,  C07C11/09 ,  B01J2523/32 ,  B01J2523/3712 ,  B01J2523/828

Abstract: Disclosed are a complex oxide catalyst for dehydrogenation, a method of preparing the same, and use thereof, wherein the catalyst includes a first transition metal selected from the group consisting of gallium, vanadium, chromium, manganese, molybdenum, and zinc, a hydrogen-activating metal including at least one selected from the group consisting of Groups 8, 9, 10, and 11 elements in a periodic table, and alumina, the amount of the first transition metal being 0.1 wt % to 20 wt %, the amount of the hydrogen-activating metal being 0.01 wt % to 2 wt %, based on the amount of the alumina, the first transition metal being loaded on the alumina, and the hydrogen-activating metal being surrounded by the alumina.

公开(公告)号：US20170028386A1

公开(公告)日：2017-02-02

申请号：US15291786

申请日：2016-10-12

Applicant: Rennovia Inc.

Inventor： Vincent J. Murphy ,  James Shoemaker ,  Guang Zhu ,  Raymond Archer ,  George Frederick Salem ,  Eric L. Dias

IPC: B01J23/52 ,  B01J21/06 ,  C07C51/235 ,  B01J35/00 ,  B01J37/02 ,  B01J37/18 ,  B01J21/08 ,  B01J29/06

CPC classification number: B01J23/52 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/42 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0248 ,  B01J37/18 ,  C07B2200/07 ,  C07C51/235 ,  C07C51/377 ,  C07C51/412 ,  C07C209/00 ,  C07C253/00 ,  C07D201/08 ,  C07D223/10 ,  C07D309/30 ,  C08G63/16 ,  C08G69/14 ,  C08G69/26 ,  C08G69/36 ,  Y02P20/582 ,  C07C59/285 ,  C07C55/14 ,  C07C211/12 ,  C07C255/04

Abstract: Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.

Abstract translation: 公开了由铂和金组成的催化剂。 催化剂通常可用于选择性氧化由伯醇基团和至少一个仲醇基团组成的组合物，其中至少伯醇基团转化为羧基。 更具体地说，催化剂是负载催化剂，包括包含金的颗粒和包含铂的颗粒，其中铂与金的摩尔比在约100:1至约1:4的范围内，铂基本上以Pt（0）的形式存在， 并且含铂颗粒的尺寸在约2至约50nm的范围内。 还公开了将碳水化合物转化为羧酸或其衍生物的氧化化学催化转化的方法。 此外，公开了使用包含铂和金的催化剂将葡萄糖选择性氧化成葡糖二酸或其衍生物的方法。 此外，公开了用于生产这种催化剂的方法。

公开(公告)号：US09555371B2

公开(公告)日：2017-01-31

申请号：US14576649

申请日：2014-12-19

Applicant: Johnson Matthey Public Limited Company

Inventor： Janet Mary Fisher ,  Raj Rao Rajaram ,  David Thompsett ,  Jillian Elaine Collier

IPC: B01D53/94 ,  B01J23/10 ,  F01N3/28 ,  B01J23/20 ,  B01J37/03 ,  B01J37/02 ,  B01J37/08 ,  B01J35/00 ,  B01J23/648 ,  B01J35/10

CPC classification number: B01D53/9413 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/2065 ,  B01D2255/207 ,  B01D2255/9155 ,  B01D2258/012 ,  B01J23/20 ,  B01J23/6484 ,  B01J23/6486 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0211 ,  B01J37/0236 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/03 ,  B01J37/033 ,  B01J37/08 ,  B01J2523/00 ,  Y02A50/2325 ,  B01J2523/3712 ,  B01J2523/56 ,  B01J2523/57

Abstract: Niobia- and tantala-doped ceria catalysts, their use in selective catalytic reduction (SCR) processes, and a compact after-treatment system for exhaust gases are disclosed. In some aspects, the catalyst comprises at least 91 wt. % of ceria and 0.1 to 9 wt. % of niobia or tantala doped on the ceria. While conventional SCR catalysts can deactivate at higher temperatures, the doped cerias, particularly ones having as little as 1 or 2 wt. % of Nb2O5 or Ta2O5, are activated toward NOx conversion by calcination. The doped cerias are also valuable for SCRF® catalyzed filter applications, including an after-treatment system that comprises a diesel particulate filter having inlets and outlets, and a dual-function catalyst coated on the inlets, outlets, or both. Compared with conventional SCR catalysts, the niobia or tantala-doped cerias enable a higher level of NO2 to be present.

Abstract translation: 公知了氧化铌和钽铝氧化物催化剂，它们在选择性催化还原（SCR）工艺中的应用，以及用于废气的紧凑的后处理系统。 在一些方面，催化剂包含至少91wt。 ％的二氧化铈和0.1〜9wt。 在氧化铈上掺杂的氧化铌或钽的百分比。 虽然常规SCR催化剂可以在较高温度下失活，但是掺杂的二氧化铈，特别是具有少至1或2wt。 Nb 2 O 5或Ta 2 O 5的％通过煅烧而被NOx活化。 掺杂的二氧化铈对于SCRF®催化过滤器应用也是有价值的，其包括后处理系统，其包括具有入口和出口的柴油微粒过滤器，以及涂覆在入口或出口上的双功能催化剂。 与传统的SCR催化剂相比，氧化铌或氧化钽掺杂的铈氧化物可以提供更高水平的NO2。

公开(公告)号：US20170014812A1

公开(公告)日：2017-01-19

申请号：US14801085

申请日：2015-07-16

Applicant: INEOS EUROPE AG

Inventor： Muin S. Haddad ,  James F. Brazdil ,  Robert A. Gustaferro

IPC: B01J27/198 ,  B01J37/02 ,  B01J27/199

CPC classification number: B01J27/198 ,  B01J23/22 ,  B01J27/199 ,  B01J35/0013 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0211 ,  B01J37/0236

Abstract: A promoted VPO catalyst for the oxidation of n-butane to maleic anhydride wherein the catalyst comprises the mixed oxides of vanadium and phosphorus, niobium and at least one of antimony and bismuth, wherein the catalyst may be produced in a process comprising impregnating a VPO catalyst with a metal source compound of niobium and a metal source compound of at least one of antimony and bismuth, to form a metal impregnated VPO catalyst, and then drying the metal impregnated VPO catalyst to form the promoted VPO catalyst.

Abstract translation: 用于将正丁烷氧化成马来酸酐的促进的VPO催化剂，其中催化剂包括钒和磷，铌和锑和铋中的至少一种的混合氧化物，其中催化剂可以以包括浸渍VPO催化剂 用铌的金属源化合物和锑和铋中的至少一种的金属源化合物形成金属浸渍的VPO催化剂，然后干燥金属浸渍的VPO催化剂以形成促进的VPO催化剂。

公开(公告)号：US09499402B2

公开(公告)日：2016-11-22

申请号：US14118301

申请日：2012-05-15

Applicant: Debasish Chakraborty

Inventor： Debasish Chakraborty

IPC: C01B3/08 ,  H01M8/06 ,  B01J21/04 ,  B01J23/46 ,  B01J23/58 ,  B01J23/63 ,  B01J23/644 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  C01B3/04

CPC classification number: C01B3/08 ,  B01J21/04 ,  B01J23/46 ,  B01J23/462 ,  B01J23/58 ,  B01J23/63 ,  B01J23/644 ,  B01J23/6447 ,  B01J35/00 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/02 ,  B01J37/0203 ,  B01J37/0211 ,  B01J37/0221 ,  B01J37/08 ,  C01B3/047 ,  H01M8/0606 ,  Y02E60/324 ,  Y02E60/364 ,  Y02E60/50

Abstract: In a method of preparing a ruthenium-containing catalyst on a non-conductive metal oxide support comprises dissolving one or more ruthenium precursor compounds in an liquid organic polyol, combining the thus obtained solution with (a) nano-powder(s) of one or more metal oxides in a ratio of moles metal oxide(s) to moles ruthenium atoms in the one or more ruthenium precursor compounds of about 0:1 to about 6:1, the metal oxide nano-powder(s) having a surface area of from about 5 to about 300 m2/g and a point of zero charge (PZC) of pH 5.5 or higher, agitating the thus obtained mixture, adding pre-shaped alumina support pellets to the agitated mixture, which is than heated at a temperature of about 50° C. to the boiling point of the organic polyol, until the reaction is finished, cooling the mixture and combining it with an aqueous solution of NaNO3 and/or KNO3, agitating the resultant mixture, separating the solvent and the solids, and drying the thus obtained solid pellets of alumina, or alumina and the metal oxide(s) of the nano-powder(s) coated with ruthenium and an additional amount Na and/or K ions. Also disclosed is the supported ruthenium-containing catalyst obtainable by the method and the use thereof in decomposing ammonia into nitrogen and oxygen.

Abstract translation: 在非导电性金属氧化物载体上制备含钌催化剂的方法包括将一种或多种钌前体化合物溶解在液体有机多元醇中，将由此获得的溶液与（a）一种或多种纳米粉末组合， 一种或多种钌前体化合物中的金属氧化物与一种或多种钌前体化合物中钌原子摩尔数的摩尔比为大约0:1至大约6:1的金属氧化物，所述金属氧化物纳米粉末的表面积为 约5至约300m 2 / g和pH 5.5或更高的零电荷点（PZC），搅拌由此获得的混合物，将预形状的氧化铝载体颗粒加入到搅拌的混合物中，该混合物在温度为 约50℃至有机多元醇的沸点，直到反应完成，冷却混合物并将其与NaNO 3和/或KNO 3的水溶液混合，搅拌所得混合物，分离溶剂和固体，和 干燥由此获得的氧化铝固体颗粒， 或氧化铝和涂覆有钌的纳米粉末和额外量的Na和/或K离子的金属氧化物。 还公开了通过该方法获得的负载的含钌催化剂及其在将氨分解成氮和氧的用途。

公开(公告)号：US09498771B2

公开(公告)日：2016-11-22

申请号：US14421061

申请日：2013-09-06

Applicant: Rui Imoto ,  Daichi Sato ,  Satoshi Nagao ,  Masaya Ibe

Inventor： Rui Imoto ,  Daichi Sato ,  Satoshi Nagao ,  Masaya Ibe

IPC: B01J23/42 ,  B01J27/18 ,  B01J37/00 ,  B01D53/56 ,  B01D53/94 ,  B01J27/16 ,  B01J23/40 ,  B01J23/44 ,  B01J29/83 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  B01J37/08 ,  B01J23/46 ,  B01J27/185

CPC classification number: B01J27/16 ,  B01D53/94 ,  B01D53/945 ,  B01D2255/1023 ,  B01D2255/2092 ,  B01D2255/9202 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J27/1856 ,  B01J29/83 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/023 ,  B01J37/0063 ,  B01J37/0201 ,  B01J37/0211 ,  B01J37/08 ,  Y02T10/22

Abstract: To provide an exhaust gas catalyst using a fired aluminum phosphate body with more excellent performance, and a method for producing it. (1) An exhaust gas purification catalyst including at least one platinum-group metal selected from the group consisting of Pt, Rh and Pd having a mean particle diameter of between 0.50 nm and 2.0 nm, supported on a tridymite-type fired aluminum phosphate body. (2) A method for producing an exhaust gas purification catalyst, including the steps of: firing aluminum phosphate obtained from an aqueous solution prepared to a pH of 3.5 to 4.5, at a temperature of between 1000° C. and 1200° C. for 2 hours or longer, to obtain a fired aluminum phosphate body, and supporting at least one type of platinum-group metal selected from the group consisting of Pt, Rh and Pd on the fired aluminum phosphate body.

Abstract translation: 为了提供使用具有更优异性能的烧制磷酸铝体的废气催化剂及其制造方法。 （1）一种废气净化催化剂，其包含平均粒径为0.50nm〜2.0nm的选自Pt，Rh和Pd中的至少一种铂族金属，负载在鳞石英型烧制磷酸铝体上 。 （2）一种废气净化催化剂的制造方法，其特征在于，包括以下步骤：在1000〜1200℃的温度下，将由pH 3.5〜4.5的水溶液得到的磷酸铝进行烧成， 2小时以上，得到烧成的磷酸铝体，在烧成的磷酸铝体上负载至少一种选自Pt，Rh，Pd的铂族金属。