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1.发明授权Process for the preparation of a molecular sieve adsorbent for the adsorptive dehydration of alcohols 有权用于制备用于醇的吸附脱水的分子筛吸附剂的方法公开(公告)号：US07407906B2
公开(公告)日：2008-08-05
申请号：US11297523
申请日：2005-12-08
CPC分类号： B01J20/186
摘要： This invention relates to the use of pore mouth control of microporous solids for developing novel molecular sieve adsorbents and their potential in the drying of alcohols. More specifically, the invention relates to the manufacture and use of a molecular sieve adsorbent, which selectively adsorbs water from azeotropic alcohol-water mixtures by pore mouth control of microporous solids with liquid phase metal alkoxide deposition on the external surface at ambient conditions of temperature and pressure. The prepared adsorbent is therefore useful for the commercial drying of alcohols.
摘要翻译： 本发明涉及微孔固体的孔口控制用于开发新的分子筛吸附剂及其在醇的干燥中的潜力。 更具体地，本发明涉及分子筛吸附剂的制造和使用，其通过在环境温度条件下在外表面上的液相金属醇盐沉积孔微孔固体的孔口控制来选择性地吸附共沸醇 - 水混合物中的水，以及 压力。 因此，制备的吸附剂可用于醇的商业干燥。
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2.发明申请Catalytic epoxidation of styrene with molecular oxygen using metal ion exchanged zeolites 有权使用金属离子交换的沸石用分子氧催化苯乙烯的环氧化公开(公告)号：US20070149791A1
公开(公告)日：2007-06-28
申请号：US11375697
申请日：2006-03-14
申请人： Raksh Vir Jasra , Jince Sebastian
发明人： Raksh Vir Jasra , Jince Sebastian
IPC分类号： C07D301/06
CPC分类号： B01J29/072 , B01J29/143 , C07D301/06
摘要： This invention provides a catalytic epoxidation of styrene to styrene oxide with molecular oxygen using cobalt containing zeolite. Catalytic epoxidation of styrene-to-styrene epoxide was carried out using molecular oxygen in presence of Co2+ exchanged zeolites. Molecular oxygen from air is also useful for the epoxidation reaction at atmospheric pressure. The presence of adsorbed water molecules in the catalyst also increases the styrene conversion without affecting the styrene oxide selectivity. Various alkali and alkaline earth cationic promoters were introduced into the zeolite catalyst to increase the styrene oxide selectivity. The present invention explore the effect of adsorbed water molecules and alkali and alkaline earth metal cationic promoters in the cobalt exchanged zeolite catalyst, on the styrene conversion and styrene oxide selectivity for the catalytic epoxidation of styrene to styrene oxide with molecular oxygen.
摘要翻译： 本发明提供使用含钴沸石的苯乙烯与分子氧的氧化苯乙烯的催化环氧化。 苯乙烯 - 苯乙烯环氧化物的催化环氧化是在分子氧存在下进行的。 来自空气的分子氧也可用于在大气压下的环氧化反应。 催化剂中吸附水分子的存在也增加了苯乙烯转化率，而不影响氧化苯乙烯的选择性。 将各种碱金属和碱土金属阳离子促进剂引入到沸石催化剂中以增加氧化苯乙烯的选择性。 本发明探讨了吸附水分子和碱金属和碱土金属阳离子助催化剂在钴交换沸石催化剂中对苯乙烯转化率和苯乙烯氧化物选择性对苯乙烯与分子氧催化氧化苯乙烯氧化物的影响。
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3.发明授权Process for the preparation of a molecular sieve adsorbent for the size/shape selective separation of air 有权制备分子筛吸附剂的方法，用于选择性分离空气的尺寸/形状公开(公告)号：US06878657B2
公开(公告)日：2005-04-12
申请号：US10403475
申请日：2003-03-31
CPC分类号： B01J20/28097 , B01D53/02 , B01J20/186
摘要： This invention relates to the use of pore mouth control of zeolite NaA for developing a novel molecular sieve adsorbents and their potential in the separation and purification of gaseous mixtures by the size/shape selective adsorption. More specifically,the invention relates to the manufacture and use of a molecular sieve adsorbent, which is selective towards oxygen from its gaseous mixture with nitrogen and argon by pore mouth control of zeolite NaA with liquid phase alkoxide deposition on the external surface at ambient conditions of temperature and pressure. Thus prepared adsorbent is useful for the separation and purification of nitrogen and argon from its mixture with oxygen.
摘要翻译： 本发明涉及沸石NaA用于开发新型分子筛吸附剂的孔口控制及其通过尺寸/形状选择性吸附分离和纯化气态混合物的潜力的用途。 更具体地说，本发明涉及分子筛吸附剂的制造和使用，该分子筛吸附剂通过在氮气和氩气的气体混合物中对氧气进行选择性，通过在室温条件下的外部表面上的沸点NaA与液相醇盐沉积 温度和压力。 如此制备的吸附剂可用于从其与氧气的混合物中分离和纯化氮气和氩气。
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4.发明授权Catalytic epoxidation of styrene with molecular oxygen using metal ion exchanged zeolites 有权使用金属离子交换的沸石用分子氧催化苯乙烯的环氧化公开(公告)号：US07345182B2
公开(公告)日：2008-03-18
申请号：US11375697
申请日：2006-03-14
申请人： Raksh Vir Jasra , Jince Sebastian
发明人： Raksh Vir Jasra , Jince Sebastian
IPC分类号： C07D301/03
CPC分类号： B01J29/072 , B01J29/143 , C07D301/06
摘要： This invention provides a catalytic epoxidation of styrene to styrene oxide with molecular oxygen using cobalt containing zeolite. Catalytic epoxidation of styrene-to-styrene epoxide was carried out using molecular oxygen in presence of Co2+ exchanged zeolites. Molecular oxygen from air is also useful for the epoxidation reaction at atmospheric pressure. The presence of adsorbed water molecules in the catalyst also increases the styrene conversion without affecting the styrene oxide selectivity. Various alkali and alkaline earth cationic promoters were introduced into the zeolite catalyst to increase the styrene oxide selectivity. The present invention explore the effect of adsorbed water molecules and alkali and alkaline earth metal cationic promoters in the cobalt exchanged zeolite catalyst, on the styrene conversion and styrene oxide selectivity for the catalytic epoxidation of styrene to styrene oxide with molecular oxygen.
摘要翻译： 本发明提供使用含钴沸石的苯乙烯与分子氧的氧化苯乙烯的催化环氧化。 苯乙烯 - 苯乙烯环氧化物的催化环氧化是在分子氧存在下进行的。 来自空气的分子氧也可用于在大气压下的环氧化反应。 催化剂中吸附水分子的存在也增加了苯乙烯转化率，而不影响氧化苯乙烯的选择性。 将各种碱金属和碱土金属阳离子促进剂引入到沸石催化剂中以增加氧化苯乙烯的选择性。 本发明探讨了吸附水分子和碱金属和碱土金属阳离子助催化剂在钴交换沸石催化剂中对苯乙烯转化率和苯乙烯氧化物选择性对苯乙烯与分子氧催化氧化苯乙烯氧化物的影响。
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5.发明授权Process for the preparation of molecular sieve adsorbent for selective adsorption of nitrogen and argon 有权用于选择性吸附氮和氩的分子筛吸附剂的制备方法公开(公告)号：US06572838B1
公开(公告)日：2003-06-03
申请号：US10105876
申请日：2002-03-25
申请人： Jince Sebastian , Raksh Vir Jasra
发明人： Jince Sebastian , Raksh Vir Jasra
IPC分类号： C01B3914
CPC分类号： B01D53/02 , B01D2253/10 , B01D2253/108 , B01D2257/102 , B01D2257/11 , B01J20/186 , C01B13/027 , C01B21/0466 , C01B23/0068 , C01B2210/0034 , C01B2210/0046 , C01B2210/0082 , Y10S95/902 , Y10S423/24
摘要： The present invention relates to the manufacture of novel molecular sieve adsorbents for the separation of a gaseous mixture of oxygen, nitrogen and argon. The adsorbent is useful for the separation of oxygen and/or nitrogen from air. More specifically, the invention relates to the manufacture of a molecular sieve adsorbent, which is selective towards nitrogen from its gaseous mixture with oxygen and/or argon and argon from its gaseous mixture with oxygen.
摘要翻译： 本发明涉及用于分离氧气，氮气和氩气的气体混合物的新型分子筛吸附剂的制造。 吸附剂可用于从空气中分离氧和/或氮。 更具体地说，本发明涉及一种分子筛吸附剂的制造，该分子筛吸附剂从其与氧和/或氩气和氩气的气态混合物的氮气与其与氧的气体混合物选择性。
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6.发明申请Process for the preparation of a molecular sieve adsorbent for the adsorptive dehydration of alcohols 有权用于制备用于醇的吸附脱水的分子筛吸附剂的方法公开(公告)号：US20060287189A1
公开(公告)日：2006-12-21
申请号：US11297523
申请日：2005-12-08
IPC分类号： B01J29/04
CPC分类号： B01J20/186
摘要： This invention relates to the use of pore mouth control of microporous solids for developing novel molecular sieve adsorbents and their potential in the drying of alcohols. More specifically, the invention relates to the manufacture and use of a molecular sieve adsorbent, which selectively adsorbs water from azeotropic alcohol-water mixtures by pore mouth control of microporous solids with liquid phase metal alkoxide deposition on the external surface at ambient conditions of temperature and pressure. The prepared adsorbent is therefore useful for the commercial drying of alcohols.
摘要翻译： 本发明涉及微孔固体的孔口控制用于开发新的分子筛吸附剂及其在醇的干燥中的潜力。 更具体地，本发明涉及分子筛吸附剂的制造和使用，其通过在环境温度条件下在外表面上的液相金属醇盐沉积孔微孔固体的孔口控制来选择性地吸附共沸醇 - 水混合物中的水，以及 压力。 因此，制备的吸附剂可用于醇的商业干燥。
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