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公开(公告)号：US5147837A
公开(公告)日：1992-09-15
申请号：US600889
申请日：1990-10-22
申请人： Ralph M. Dessau , Ying-Yen P. Tsao
发明人： Ralph M. Dessau , Ying-Yen P. Tsao
IPC分类号： B01J21/06 , B01J29/068 , B01J29/44 , B01J29/72 , C07C5/333
CPC分类号： B01J21/063 , B01J29/068 , B01J29/44 , C07C5/3332
摘要： The aging properties of Group VIII metal modified non-acidic microporous crystalline materials which in catalysis exhibit high selectivity for dehydrogenation and dehydrocyclization are improved by the incorporation therein of titanium and/or titania.
摘要翻译： 通过掺入钛和/或二氧化钛，可以改善在催化中表现出高脱氢和脱氢环化选择性的第VIII族金属改性非酸性微孔结晶材料的老化性能。
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公开(公告)号：US06984606B2
公开(公告)日：2006-01-10
申请号：US10782172
申请日：2004-02-19
申请人： Ralph M. Dessau
发明人： Ralph M. Dessau
IPC分类号： B01J21/16 , C07D301/06 , C07D301/10
摘要： Noble metal-containing titanium zeolite catalysts are prepared by reacting a titanium compound, a silicon source, a templating agent, and a noble metal source at a temperature and for a time sufficient to form a molecular sieve. The catalyst is useful in olefin epoxidation with oxygen and hydrogen.
摘要翻译： 通过在足以形成分子筛的温度和时间下使钛化合物，硅源，模板剂和贵金属源反应来制备含贵金属的钛沸石催化剂。 该催化剂可用于与氧气和氢气进行烯烃环氧化反应。
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公开(公告)号：US5292980A
公开(公告)日：1994-03-08
申请号：US686957
申请日：1991-04-18
申请人： Ralph M. Dessau
发明人： Ralph M. Dessau
CPC分类号： C07C45/74 , C07C45/66 , C07C5/2518 , C07C5/367 , Y02P20/582
摘要： Basic intermediate or large pore zeolites having a Constraint Index less than 12 are useful as catalysts in the dehydrogenation-aromatization of cyclic dienes, in the isomerization of olefins and in the aldol condensation, and particularly in the cyclization of acetonylacetone to 3-methyl-2-cyclopenten-1-one.
摘要翻译： 具有小于12的约束指数的基本中间或大孔沸石可用作环状二烯的脱氢芳构化，烯烃异构化和醛醇缩合中的催化剂，特别是在丙酮基丙酮环化为3-甲基-2 环戊烯-1-酮。
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公开(公告)号：US4884531A
公开(公告)日：1989-12-05
申请号：US213855
申请日：1988-06-30
摘要： A method is provided of operating an internal combustion engine comprising subjecting a hydrocarbon fuel of relatively low octane number to in situ reforming at elevated temperatures by passing it through a reaction zone containing a substantially non-acid catalyst comprising a Group VIII hydrogenation/dehydrogenation metallic element, e.g., platinum, and an intermediate pore zeolite, e.g., having an X-ray diffraction pattern similar to that of an acidic zeolite which has a Constraint Index in the approximate range of about 1 to 12, such that the fuel leaving said reaction zone has an increased octane number, and passing the fuel to the combustion chamber of said engine.
摘要翻译： 提供了一种操作内燃机的方法，该内燃机包括使相对低辛烷值的烃燃料在升高的温度下进行原位重整，使其通过含有基本上非酸性催化剂的反应区，该催化剂包含第VIII族氢化/脱氢金属元素 例如铂和中间孔沸石，例如具有类似于具有大约1至12约的约束指数的酸性沸石的X射线衍射图，使得离开所述反应区的燃料 具有增加的辛烷值，并将燃料通过所述发动机的燃烧室。
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公开(公告)号：US4822942A
公开(公告)日：1989-04-18
申请号：US214781
申请日：1988-07-01
IPC分类号： B01J29/44 , C07C5/41 , C07C15/46 , C10G35/095 , C07C2/52
CPC分类号： C10G35/095 , B01J29/44 , C07C5/417
摘要： An indium containing crystalline microporous material also containing a dehydrogenation component exhibits high selectivity for the aromatization of a normal paraffin to styrene, under dehydrocyclization conditions.Group VIII metal-containing non-acidic crystalline microporous indium containing materials are highly selective catalysts for styrene production from n-octane.
摘要翻译： 还含有脱氢组分的含铟结晶微孔材料在脱氢环化条件下对正链烷烃对苯乙烯的芳构化具有高选择性。 含Ⅷ族金属的非酸性结晶微孔含铟材料是用于正辛烷生产苯乙烯的高选择性催化剂。
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公开(公告)号：US4650917A
公开(公告)日：1987-03-17
申请号：US766996
申请日：1985-08-19
申请人： Ralph M. Dessau , David H. Olson
发明人： Ralph M. Dessau , David H. Olson
CPC分类号： C10G69/126 , C10G2400/10
摘要： The viscosity index of synthetic lubricant stocks such as those produced by olefin oligomerization is increased by contacting such stocks with a solid acidic isomerization catalyst such as boron trifluoride at elevated temperatures, say above about 200.degree. C. The high viscosity index fractions of the resulting product may be sorbed by a shape-selective zeolite such as ZSM-5 and recovered to produce a high VI lubricant.
摘要翻译： 通过在高于约200℃的升高的温度下使这些原料与固体酸性异构化催化剂如三氟化硼接触来提高合成润滑剂原料如粘度低聚产生的粘度指数。所得产物的高粘度指数级分 可以被诸如ZSM-5的形状选择性沸石吸收并回收以产生高VI润滑剂。
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公开(公告)号：US4444986A
公开(公告)日：1984-04-24
申请号：US307048
申请日：1981-09-30
申请人： Ralph M. Dessau
发明人： Ralph M. Dessau
CPC分类号： C07C37/82 , C07C17/389 , C07C29/76 , C07C7/13 , C10G25/03 , C07C2101/14
摘要： An improved hydrocarbon separation process by the selective sorption properties of certain members of a novel class of zeolites is provided. The novel class of zeolites is characterized by a silica to alumina mole ratio greater than 12 and a Constraint Index within the approximate range of greater than about 2 to about 12. The process of this invention involves selective separation of higher molecular weight hydrocarbon compounds in admixture with lower molecular weight hydrocarbon compounds within a homolgous series by contacting the respective mixture with a zeolite having a SiO.sub.2 /Al.sub.2 O.sub.3 mole ratio of at least about 12 and a Constraint Index with the approximate range of greater than 2 to about 12, to effect the selective sorption of said higher molecular weight hydrocarbon compounds by said zeolite.
摘要翻译： 提供了通过新型沸石的某些成员的选择吸附性能改进的烃分离方法。 新型沸石的特征在于二氧化硅与氧化铝的摩尔比大于12，约束指数在大约2至大约12的范围内。本发明的方法涉及高分子量烃化合物的混合物的选择性分离 通过使相应的混合物与SiO 2 / Al 2 O 3摩尔比为至少约12的沸石和大约2至大约12的约束指数的约束指数接触，使均相系列中的低分子量烃化合物进行选择性 通过所述沸石吸附所述较高分子量的烃化合物。
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公开(公告)号：US4309281A
公开(公告)日：1982-01-05
申请号：US105190
申请日：1979-12-19
申请人： Ralph M. Dessau
发明人： Ralph M. Dessau
IPC分类号： C07C1/00 , C07C7/13 , C07C9/00 , C07C17/389 , C07C27/00 , C07C29/76 , C07C31/12 , C07C37/82 , C07C67/00 , C10G25/03
摘要： Improved hydrocarbon separation processes by the selective sorption properties of a novel class of zeolites are provided. The novel class of zeolites is characterized by a silica to alumina mole ratio greater than 12 and a constraint index within the approximate range of greater than about 2 to about 12. The separations encompassed by this invention include paraffins from aromatics, olefins from aromatics, olefins from paraffins, linear paraffins from branched paraffins, linear olefins from branched olefins, methyl branched hydrocarbons from more highly branched hydrocarbons, higher molecular weight components from lower molecular weight components within an homologous series, n-paraffins or methylparaffins from cycloparaffins, n-alkyl or methyl alkyl substituted aromatics from more highly branched isomers, mixed paraffins from aromatics (dewaxing), and non-aromatic methyl-branched hydrocarbons from aromatics. Also mono-substituted or para-disubstituted aromatics can be separated from ortho- and/or meta-disubstituted or more highly substituted aromatics. By reducing the diffusional rate characteristics of the aforesaid zeolites, improved separation of p-xylene from its isomers is also attained.
摘要翻译： 提供了通过新型沸石的选择吸附性能改进的烃分离方法。 新型沸石的特征在于二氧化硅与氧化铝的摩尔比大于12，约束指数在大约2至大约12的范围内。本发明包括的分离物包括来自芳族化合物的链烷烃，芳族化合物的烯烃，烯烃 来自链烷烃的链烷烃，来自支链烯烃的直链烯烃，来自支链烯烃的直链烯烃，来自更高支化烃的甲基支链烃，来自同系物系中的较低分子量组分的较高分子量组分，来自环烷烃的正链烷烃或甲基烷烃，正烷基或 来自更高支化异构体的甲基烷基取代的芳族化合物，来自芳族化合物的混合石蜡（脱蜡））和来自芳族化合物的非芳族甲基支链烃。 也可以将单取代或对位取代的芳族化合物与邻位和/或间二取代或更高取代的芳族化合物分离。 通过降低上述沸石的扩散速率特性，也可获得对二甲苯与其异构体的改进分离。
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公开(公告)号：US4119646A
公开(公告)日：1978-10-10
申请号：US737942
申请日：1976-11-02
IPC分类号： C07C45/51 , C07C45/54 , C07D307/28 , C07D307/79 , C07D307/86
CPC分类号： C07D307/28 , C07C45/513 , C07C45/54 , C07C45/68
摘要： An olefin is reacted with a source of X free radical in the presence of an ion of manganese, vanadium, or cerium having a valence higher than the lowest valence above the zero valent form of the metal to form derivatives of the olefin that contain one or more functional groups. The free radical X is one that is resistant to substantial oxidation by the ion or the metal and is obtained from ketones, aldehydes, esters, nitriles, nitroparaffins, sulfoxides, thiosulfonic acid esters, alkanesulfonic acids, alkensulfinic acids, and thiols. Hexahydrobenzofuranone compounds are prepared by this reaction.
摘要翻译： 烯烃与X自由基源在锰，钒或铈的离子存在下反应，其价态高于零价形式的金属上的最低价，其形成含有一个或多个碳原子的烯烃的衍生物， 更多功能组。 自由基X是能够通过离子或金属抵抗实质氧化的自由基X，其由酮，醛，酯，腈，硝基花青，亚砜，硫代磺酸酯，链烷磺酸，亚磺酸和硫醇得到。 通过该反应制备六氢苯并呋喃酮化合物。
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公开(公告)号：US4081456A
公开(公告)日：1978-03-28
申请号：US659803
申请日：1976-02-20
IPC分类号： C07D207/26 , C07D207/27 , C07D315/00 , C07D403/06 , C07D403/12
CPC分类号： C07D207/27 , C07D315/00
摘要： Gamma-alkyl-gamma-butyrolactones having an alkyl substituent of at least 16 carbon atoms in length, preferably at least 25 carbon atoms, are formed by reacting a monoolefin with a carboxylic acid in the presence of a reducible metal ion of higher-valent form, such as the manganic ion, Mn.sup.+3. The resulting lactones are useful as antiwear agents and for improving the adherence of wax coatings of paper and, upon reaction with amines, polyalkylenepolyamines, for providing novel lactams and bislactams useful as multifunctional agents in lubricants, fuels, coolants and other organic fluids. Thus, the compounds of this invention are of the general structure ##STR1## the alkyl group being as defined above, X being oxygen, imino, alkylimino, polyalkylenepolyamino or lactam(polyalkylenepolyamino) and the dangling valences being hydrogen or lower alkyl (that is, no greater than 6 carbon atoms).
摘要翻译： 具有长度为至少16个碳原子的烷基取代基，优选至少25个碳原子的γ-烷基-γ-丁内酯是通过使单烯烃与羧酸在可还原的高价金属离子存在下反应形成的 ，如锰离子，Mn + 3。 所得内酯可用作抗磨剂，并且用于改善纸的蜡涂层的粘附性，并且与胺反应，聚亚烷基多胺，用于提供用作润滑剂，燃料，冷却剂和其它有机流体中的多官能试剂的新型内酰胺和双内酰胺。 因此，本发明的化合物具有如上定义的烷基的一般结构，X为氧，亚氨基，烷基亚氨基，聚亚烷基聚氨基或内酰胺（聚亚烷基聚氨基），悬浮体为氢或低级烷基（即， 不大于6个碳原子）。
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