公开(公告)号：US20130105727A1

公开(公告)日：2013-05-02

申请号：US13666389

申请日：2012-11-01

申请人： Ralph Rieger ,  Tina Schroeder-Grimonpont ,  Evgueni Klimov ,  Gregor Herth

发明人： Ralph Rieger ,  Tina Schroeder-Grimonpont ,  Evgueni Klimov ,  Gregor Herth

IPC分类号： C09K5/00

CPC分类号： C09K5/063

摘要： The present invention relates to heat storage compositions comprising 70 to 99% by weight of calcium chloride hexahydrate 1 to 10% by weight of one or more cationic polyelectrolytes and 0 to 20% by weight of one or more further salts, based in each case on the heat storage composition, to a process for production thereof, to the use thereof as a latent heat storage material and use of the latter in heat-storing building materials and as a heat storage element for vehicles, walls of transport vessels or other heat storage vessels.

摘要翻译： 本发明涉及储热组合物，其包含70-99重量％的氯化钙六水合物1-10重量％的一种或多种阳离子聚电解质和0-20重量％的一种或多种其它盐， 蓄热组合物，其制造方法，其作为潜热蓄热材料的用途，其用于蓄热建筑材料和作为车辆的蓄热元件，运送容器的壁或其他蓄热材料 船只。

公开(公告)号：US08741169B2

公开(公告)日：2014-06-03

申请号：US13614131

申请日：2012-09-13

申请人： Ralph Rieger ,  Jens Charles ,  Tina Schroeder-Grimonpont ,  Francisco Javier Lopez Villanueva ,  Juergen Mertes ,  Evgueni Klimov ,  Gregor Herth

发明人： Ralph Rieger ,  Jens Charles ,  Tina Schroeder-Grimonpont ,  Francisco Javier Lopez Villanueva ,  Juergen Mertes ,  Evgueni Klimov ,  Gregor Herth

IPC分类号： E04B1/74

CPC分类号： C09K5/063

摘要： The present invention relates to a heat storage composition comprising 60-98% by weight of sodium sulfate decahydrate and 1-10% by weight of one or more superabsorbents 1-10% by weight of one or more nucleators and 0-20% by weight of one or more water-soluble salts, based in each case on the heat storage composition, said superabsorbent comprising, in polymerized form, a) at least 50 mol %, based on the superabsorbent, of one or more monoethylenically unsaturated monomers comprising acid groups, the degree of neutralization of the monoethylenically unsaturated monomers comprising acid groups being 15 to 85 mol %, and b) 0.015 to 0.1 mol %, based on the total amount of monomers, of at least one crosslinker, to a process for production thereof and to the use thereof as a heat-storing building material and as a heat storage element for motor vehicles, walls of transport vessels or other heat storage vessels.

摘要翻译： 本发明涉及一种储热组合物，其包含60-98重量％的十水硫酸钠和1-10重量％的一种或多种超吸收剂，1-10重量％的一种或多种成核剂和0-20重量％ 一种或多种水溶性盐，基于每种情况下在储热组合物上，所述超吸收剂以聚合形式包含a）至少50mol％的基于超吸收剂的一种或多种包含酸基团的单烯属不饱和单体 包含酸基团的单烯属不饱和单体的中和度为15〜85摩尔％，b为0.015〜0.1摩尔％，基于单体的总量，至少一种交联剂，其制备方法和 作为储热建筑材料的使用以及用作机动车辆的储存元件，运输容器的壁或其它蓄热容器。

公开(公告)号：US20130157863A1

公开(公告)日：2013-06-20

申请号：US13716827

申请日：2012-12-17

申请人： Peter HAHN ,  Markus Brym ,  Harald Keller ,  Christian Nitschke ,  Hans Willax ,  Britta Katz ,  Jutta Brust ,  Tina Schroeder-Grimonpont ,  Ralph Rieger ,  Regina Klein

发明人： Peter HAHN ,  Markus Brym ,  Harald Keller ,  Christian Nitschke ,  Hans Willax ,  Britta Katz ,  Jutta Brust ,  Tina Schroeder-Grimonpont ,  Ralph Rieger ,  Regina Klein

IPC分类号： C08L39/00 ,  C08L33/14 ,  C08L33/26

CPC分类号： C08L39/00 ,  C08L33/14 ,  C08L33/26 ,  C09J133/066

摘要： The present invention relates to microcapsule dispersions comprising microcapsules comprising a hydrophilic capsule core and a capsule wall polymer which is obtainable by polymerization of a monomer composition comprising 25 to 95% by weight of one or more C1-C24-alkyl and/or glycidyl esters of acrylic acid and/or methacrylic acid 5 to 75% by weight of one or more hydrophilic monomers selected from acrylic acid esters and/or methacrylic acid esters which carry hydroxy and/or carboxy groups, and allylgluconamide 0 to 40% by weight of one or more compounds having two or more ethylenically unsaturated radicals, where the microcapsules are dispersed in a hydrophobic diluents, to the microcapsules, and to a method for producing them and to their use for the delayed release of active ingredients for construction, cosmetics or crop protection applications.

摘要翻译： 本发明涉及包含包含亲水胶囊核心和胶囊壁聚合物的微胶囊的微胶囊分散体，其通过聚合包含25-95重量％的一种或多种C 1 -C 24烷基和/或缩水甘油酯的单体组合物 丙烯酸和/或甲基丙烯酸5至75重量％的一种或多种选自携带羟基和/或羧基的丙烯酸酯和/或甲基丙烯酸酯的亲水性单体和烯丙基甲酰胺，0至40重量％的一个或多个 更多具有两个或更多个烯键式不饱和基团的化合物，其中微胶囊分散在疏水性稀释剂中）到微胶囊中，以及其制备方法和用于延迟释放用于建筑，化妆品或作物保护应用的活性成分的用途 。

公开(公告)号：US08389670B2

公开(公告)日：2013-03-05

申请号：US13511890

申请日：2010-11-29

申请人： Marcel Kastler ,  Silke Annika Koehler ,  Klaus Muellen ,  Ralph Rieger

发明人： Marcel Kastler ,  Silke Annika Koehler ,  Klaus Muellen ,  Ralph Rieger

IPC分类号： C08G75/00

CPC分类号： H01L51/0043 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/92 ,  H01L51/0036 ,  H01L51/0558 ,  Y02E10/549

摘要： Dithienobenzo-thieno[3,2-b]thiophene-copolymers of the formula (I) wherein: pi is a monocyclic or polycyclic moiety optionally substituted with 1-4 Ra groups, wherein Ra, at each occurrence, is independently hydrogen or a) a halogen, b) —(CN, c) —NO2, d) oxo, e) —OH, f) ═C(Rb)2; g) a C1-20 alkyl group, h) a C2-20 alkenyl group, i) a C2-20 alkynyl group, j) a C1-20 alkoxy group, k) a C1-20 alkylthio group, l) a C1-20 haloalkyl group, m) a —Y—C3-10 cycloalkyl group, n) a —Y—C6-14 aryl group, o) a —Y-3-12 membered cycloheteroalkyl group, or p) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl or haloaryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 Rb groups; Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and R1, R2, R3, at each occurrence, are independently H, a halogen, CN, a C1-30 alkyl group, a C2-30 alkenyl group, a C1-30 haloalkyl group, a C2-30 alkynyl group, a C1-30 alkoxy group, a C(O)—C1-20 alkyl group, a C(O)—OC1-20 alkyl group, a Y—C3-10 cycloalkyl group, a —Y-3-12 membered cycloheteroalkyl group, each optionally substituted with 1-5 substituents selected from a halogen, —CN, a C1-6 alkyl group, a C1-6 alkoxy group, and a C1-6 haloalkyl group, -L-Ar1, -L-Ar1—Ar1, -L-Ar1—R4, or -L-Ar1—Ar1—R4 and Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; n=0, 1, 2; and o=1-1000.

公开(公告)号：US20110168264A1

公开(公告)日：2011-07-14

申请号：US13002392

申请日：2009-06-25

申请人： Marcel Kastler ,  Silke Koehler ,  Klaus Muellen ,  Miaoyin Liu ,  Dirk Beckmann ,  Ralph Rieger

发明人： Marcel Kastler ,  Silke Koehler ,  Klaus Muellen ,  Miaoyin Liu ,  Dirk Beckmann ,  Ralph Rieger

IPC分类号： H01L51/46 ,  H01L51/30 ,  H01L51/54 ,  C08G75/06 ,  C08L81/02

CPC分类号： H01L51/0036 ,  C07D495/04 ,  C08G61/126 ,  H01B1/127 ,  H01L51/0043 ,  H01L51/0074 ,  H01L51/0541 ,  H01L51/0545 ,  Y02E10/549

摘要： Poly(5,5′-bis(thiophen-2-yl)-benzo[2,1-b;3,4-b′]dithiophene) comprising as repeating units the group of the formula (I) wherein R is independently selected from a) a C1-2O alkyl group, b) a C2-20 alkenyl group, c) a C2-20 alkynyl group, d) a C1-20 alkoxy group, e) a —Y—C3-10 cycloalkyl group, f) a —Y—C6-14 aryl group, g) a —Y-3-12 membered cycloheteroalkyl group, or h) a —Y-5-14 membered het-eroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 R1 groups, R1 is independently selected from a) a S(O)m—C1-20 alkyl group, b) a S(O)m—OC1-20 alkyl group, c) a S(O)m—OC6-14 aryl group, d) a C(O)—OC1-20 alkyl group, e) a C(O)—OC6-14 aryl group, f) a C1-20 alkyl group, g) a C2-20 alkenyl group, h) a C2-20 alkynyl group, i) a C1-20 alkoxy group, j) a C3-10 cycloalkyl group, k) a C6-14 aryl group, I) a 3-12 membered cycloheteroalkyl group, or m) a 5-14 membered heteroaryl group, Y is independently selected from a divalent C1-6 alkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2, and having a number average molecular weight Mn in the range of from 5,000 to 200,000 g/mol.

摘要翻译： 包括作为重复单元的式（I）基团，其中R独立地被选择的聚（5,5'-双（噻吩-2-基） - 苯并[2,1-b; 3,4-b']二噻吩） 从a）C1-2O烷基，b）C2-20烯基，c）C2-20炔基，d）C1-20烷氧基，e）-Y-C3-10环烷基，f ）a -Y-C 6-14芳基，g）-Y-3-12元环杂烷基，或h）-Y-5-14元环芳基，其中每个C 1-20烷基， C2-20烯基，C2-20炔基，C3-10环烷基，C6-14芳基，3-12元环杂烷基和5-14元杂芳基任选被1- 4个R 1基团，R 1独立地选自a）S（O）m -C 1-20烷基，b）S（O）m OC 1-7-20烷基，c）S（O）m OC 1-6 - 14芳基，d）C（O）-OC1-20烷基，e）C（O）-OC6-14芳基，f）C1-20烷基，g）C2-20烯基， h）C 20-20炔基，i）C 1-20烷氧基，j）C 3-10环烷基 烷叉基，k）C 6-14芳基，I）3-12元环杂烷基或m）5-14元杂芳基，Y独立地选自二价C 1-6烷基或共价键 ; m独立地选自0,1或2，数均分子量Mn在5,000至200,000g / mol的范围内。

公开(公告)号：US08598304B2

公开(公告)日：2013-12-03

申请号：US13002392

申请日：2009-06-25

申请人： Marcel Kastler ,  Silke Koehler ,  Klaus Muellen ,  Miaoyin Liu ,  Dirk Beckmann ,  Ralph Rieger

发明人： Marcel Kastler ,  Silke Koehler ,  Klaus Muellen ,  Miaoyin Liu ,  Dirk Beckmann ,  Ralph Rieger

IPC分类号： C08G75/00

CPC分类号： H01L51/0036 ,  C07D495/04 ,  C08G61/126 ,  H01B1/127 ,  H01L51/0043 ,  H01L51/0074 ,  H01L51/0541 ,  H01L51/0545 ,  Y02E10/549

摘要： Poly(5,5′-bis(thiophen-2-yl)-benzo[2,1-b;3,4-b′]dithiophene) comprising as repeating units the group of the formula (I) wherein R is independently selected from a) a C1-20 alkyl group, b) a C2-20 alkenyl group, c) a C2-20 alkynyl group, d) a C1-20 alkoxy group, e) a —Y—C3-10 cycloalkyl group, f) a —Y—C6-14 aryl group, g) a —Y-3-12 membered cycloheteroalkyl group, or h) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 R1 groups, R1 is independently selected from a) a S(O)m—C1-20 alkyl group, b) a S(O)m—OC1-20 alkyl group, c) a S(O)m—OC6-14 aryl group, d) a C(O)—OC1-20 alkyl group, e) a C(O)—OC6-14 aryl group, f) a C1-20 alkyl group, g) a C2-20 alkenyl group, h) a C2-20 alkynyl group, i) a C1-20 alkoxy group, j) a C3-10 cycloalkyl group, k) a C6-14 aryl group, l) a 3-12 membered cycloheteroalkyl group, or m) a 5-14 membered heteroaryl group, Y is independently selected from a divalent C1-6 alkyl group, or a covalent bond; and m is independently selected from 0, 1, or 2, and having a number average molecular weight Mn in the range of from 5,000 to 200,000 g/mol.

摘要翻译： 包括作为重复单元的式（I）基团，其中R独立地被选择的聚（5,5'-双（噻吩-2-基） - 苯并[2,1-b; 3,4-b']二噻吩） 从a）C 1-20烷基，b）C 2-20烯基，c）C 2-20炔基，d）C 1-20烷氧基，e）-Y-C 3-10环烷基，f ）-Y-C 6-14芳基，g）a -Y-3-12元环杂烷基，或h）-Y-5-14元杂芳基，其中C 1-20烷基，C 2 -20链烯基，C2-20炔基，C3-10环烷基，C6-14芳基，3-12元环杂烷基和5-14元杂芳基任选被1-4个R1 基团，R 1独立地选自a）S（O）m -C 1-20烷基，b）S（O）m OC 1-7-20烷基，c）S（O）m -C 0-6-14芳基 基团，d）C（O）-OC 1-20烷基，e）C（O）-OC 6-14芳基，f）C 1-20烷基，g）C 2-20烯基，h） C 20-20炔基，i）C 1-20烷氧基，j）C 3-10环烷基，k）C 6-14 芳基，l）3-12元环杂烷基，或m）5-14元杂芳基，Y独立地选自二价C 1-6烷基或共价键; m独立地选自0,1或2，数均分子量Mn在5,000至200,000g / mol的范围内。

公开(公告)号：US20120289672A1

公开(公告)日：2012-11-15

申请号：US13511890

申请日：2010-11-29

申请人： Marcel Kastler ,  Silke Annika Koehler ,  Klaus Muellen ,  Ralph Rieger

发明人： Marcel Kastler ,  Silke Annika Koehler ,  Klaus Muellen ,  Ralph Rieger

IPC分类号： C08G75/00 ,  H01L51/40 ,  H01B1/12

CPC分类号： H01L51/0043 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/92 ,  H01L51/0036 ,  H01L51/0558 ,  Y02E10/549

摘要： Dithienobenzo-thieno[3,2-b]thiophene-copolymers of the formula (I) wherein: pi is a monocyclic or polycyclic moiety optionally substituted with 1-4 Ra groups, wherein Ra, at each occurrence, is independently hydrogen or a) a halogen, b) —(CN, c) —NO2, d) oxo, e) —OH, f) ═C(Rb)2; g) a C1-20 alkyl group, h) a C2-20 alkenyl group, i) a C2-20 alkynyl group, j) a C1-20 alkoxy group, k) a C1-20 alkylthio group, l) a C1-20 haloalkyl group, m) a —Y—C3-10 cycloalkyl group, n) a —Y—C6-14 aryl group, o) a —Y-3-12 membered cycloheteroalkyl group, or p) a —Y-5-14 membered heteroaryl group, wherein each of the C1-20 alkyl group, the C2-20 alkenyl group, the C2-20 alkynyl group, the C3-10 cycloalkyl group, the C6-14 aryl or haloaryl group, the 3-12 membered cycloheteroalkyl group, and the 5-14 membered heteroaryl group is optionally substituted with 1-4 Rb groups; Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; and R1, R2, R3, at each occurrence, are independently H, a halogen, CN, a C1-30 alkyl group, a C2-30 alkenyl group, a C1-30 haloalkyl group, a C2-30 alkynyl group, a C1-30 alkoxy group, a C(O)—C1-20 alkyl group, a C(O)—OC1-20 alkyl group, a Y—C3-10 cycloalkyl group, a —Y-3-12 membered cycloheteroalkyl group, each optionally substituted with 1-5 substituents selected from a halogen, —CN, a C1-6 alkyl group, a C1-6 alkoxy group, and a C1-6 haloalkyl group, -L-Ar1, -L-Ar1-—Ar1, -L-Ar1—R4, or -L-Ar1—Ar1—R4 and Y, at each occurrence, is independently a divalent C1-6 alkyl group, a divalent C1-6 haloalkyl group, or a covalent bond; n=0, 1, 2; and o=1-1000.