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公开(公告)号:US06228957B1
公开(公告)日:2001-05-08
申请号:US09251356
申请日:1999-02-17
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F410
CPC分类号: C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/903 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more olefin comonomer(s) under polymerization conditions with a Ziegler-Natta type catalyst substantially free of internal electron donor, trimethylaluminum and at least one compound containing at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)n—R3 where n ranges from 0 to 30, and R1, R2 and R3 independently contain from 1 to 30 carbon atoms and from 0 to 30 heteroatoms of an element, or mixtures thereof, selected from Groups 13, 14, 15, 16 and 17 of the Periodic Table of Elements, and further wherein R1, R2 and/or R3 can be linked and form part of a cyclic or polycyclic structure. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种烯烃共聚单体与基本上不含内电子供体的齐格勒 - 纳塔型催化剂接触,并且至少 一种含有至少一个式R 1 -O(-R 2 -O)n -R 3的碳 - 碳 - 碳键(COC)的化合物,其中n为0至30,R 1,R 2和R 3独立地为1至30 碳原子和0至30个选自元素周期表第13,14,15,16和17族的元素或其混合物的杂原子,并且其中R 1,R 2和/或R 3可以连接并形成 部分环状或多环结构。 还提供了由其制备的薄膜和制品。
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公开(公告)号:US06534613B2
公开(公告)日:2003-03-18
申请号:US09912063
申请日:2001-07-24
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F1002
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst, at least one halogenated hydrocarbon, at least one compound of the formula XnER3-n as a co-catalyst and at least one compound containing at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)n—R3 as an external electron donor. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其涉及使聚乙烯和/或乙烯与至少一种或多种其它烯烃在齐格勒 - 纳塔型催化剂,至少一种卤代烃,至少一种化合物 的式XnER 3-n作为助催化剂和至少一种含有至少一个式R 1 -O(-R 2 -O)n -R 3的碳 - 碳 - 碳键(COC)的化合物作为外电子给体。 还提供了由其制备的薄膜和制品。
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公开(公告)号:US06191239B1
公开(公告)日:2001-02-20
申请号:US09251811
申请日:1999-02-17
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F416
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F4/6492 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more olefin comonomer(s) under polymerization conditions with a Ziegler-Natta type catalyst, trimethylaluminum and tetrahydrofuran. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种烯烃共聚单体与齐格勒 - 纳塔型催化剂,三甲基铝和四氢呋喃接触。 还提供了由其制备的薄膜和制品。
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公开(公告)号:US06271321B1
公开(公告)日:2001-08-07
申请号:US09251969
申请日:1999-02-17
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F416
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst containing at least one or more internal electron donors, trimethylaluminum and at least one or more external electron donors containing at least one carbon-oxygen-carbon linkage (C—O—C) selected from the group consisting of Formula 1, R1—CH2—O—CH2—R2, Formula 2, Formula 3, R5—O—R6, and Formula 4, R7—O(—R8—O)n—R9. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种其它烯烃与含有至少一种或多种内部电子给体的齐格勒 - 纳塔型催化剂接触,三甲基铝 和至少一种或多种含有选自由式1,式2,式3和式4组成的组中的至少一个碳 - 碳 - 碳键(COC)的外部电子给体。还提供了由其制备的薄膜和制品。
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