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公开(公告)号:US06191239B1
公开(公告)日:2001-02-20
申请号:US09251811
申请日:1999-02-17
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F416
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F4/6492 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more olefin comonomer(s) under polymerization conditions with a Ziegler-Natta type catalyst, trimethylaluminum and tetrahydrofuran. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种烯烃共聚单体与齐格勒 - 纳塔型催化剂,三甲基铝和四氢呋喃接触。 还提供了由其制备的薄膜和制品。
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公开(公告)号:US06271321B1
公开(公告)日:2001-08-07
申请号:US09251969
申请日:1999-02-17
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F416
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst containing at least one or more internal electron donors, trimethylaluminum and at least one or more external electron donors containing at least one carbon-oxygen-carbon linkage (C—O—C) selected from the group consisting of Formula 1, R1—CH2—O—CH2—R2, Formula 2, Formula 3, R5—O—R6, and Formula 4, R7—O(—R8—O)n—R9. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种其它烯烃与含有至少一种或多种内部电子给体的齐格勒 - 纳塔型催化剂接触,三甲基铝 和至少一种或多种含有选自由式1,式2,式3和式4组成的组中的至少一个碳 - 碳 - 碳键(COC)的外部电子给体。还提供了由其制备的薄膜和制品。
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公开(公告)号:US06228957B1
公开(公告)日:2001-05-08
申请号:US09251356
申请日:1999-02-17
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F410
CPC分类号: C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/903 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more olefin comonomer(s) under polymerization conditions with a Ziegler-Natta type catalyst substantially free of internal electron donor, trimethylaluminum and at least one compound containing at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)n—R3 where n ranges from 0 to 30, and R1, R2 and R3 independently contain from 1 to 30 carbon atoms and from 0 to 30 heteroatoms of an element, or mixtures thereof, selected from Groups 13, 14, 15, 16 and 17 of the Periodic Table of Elements, and further wherein R1, R2 and/or R3 can be linked and form part of a cyclic or polycyclic structure. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种烯烃共聚单体与基本上不含内电子供体的齐格勒 - 纳塔型催化剂接触,并且至少 一种含有至少一个式R 1 -O(-R 2 -O)n -R 3的碳 - 碳 - 碳键(COC)的化合物,其中n为0至30,R 1,R 2和R 3独立地为1至30 碳原子和0至30个选自元素周期表第13,14,15,16和17族的元素或其混合物的杂原子,并且其中R 1,R 2和/或R 3可以连接并形成 部分环状或多环结构。 还提供了由其制备的薄膜和制品。
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公开(公告)号:US06534613B2
公开(公告)日:2003-03-18
申请号:US09912063
申请日:2001-07-24
申请人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人: Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号: C08F1002
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12
摘要: A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst, at least one halogenated hydrocarbon, at least one compound of the formula XnER3-n as a co-catalyst and at least one compound containing at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)n—R3 as an external electron donor. Also provided are films and articles produced therefrom.
摘要翻译: 一种用于生产乙烯均聚物和共聚物的新方法,其涉及使聚乙烯和/或乙烯与至少一种或多种其它烯烃在齐格勒 - 纳塔型催化剂,至少一种卤代烃,至少一种化合物 的式XnER 3-n作为助催化剂和至少一种含有至少一个式R 1 -O(-R 2 -O)n -R 3的碳 - 碳 - 碳键(COC)的化合物作为外电子给体。 还提供了由其制备的薄膜和制品。
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公开(公告)号:US06417296B2
公开(公告)日:2002-07-09
申请号:US09818327
申请日:2001-03-27
申请人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
发明人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
IPC分类号: C08F234
CPC分类号: C08F10/00 , C08F210/16 , Y10S526/901 , C08F2/002 , C08F4/6294 , C08F4/6293 , C08F210/08 , C08F2500/12 , C08F210/06 , C08F210/14
摘要: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta catalyst comprising at least one transition metal compound and at least one organometallic co-catalyst compound and tetrahydrofuran in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.
摘要翻译: 一种制备烯烃的均聚物和共聚体的新方法,其包括在聚合条件下使烯烃和/或烯烃与至少一种或多种其它烯烃与包含至少一种过渡金属化合物的齐格勒 - 纳塔催化剂和至少 一种有机金属助催化剂化合物和四氢呋喃,其量足以减少聚合介质中的静电电荷。 还公开了一种减少烯烃聚合介质中的静电荷的方法。
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公开(公告)号:US06313236B1
公开(公告)日:2001-11-06
申请号:US09387599
申请日:1999-08-31
申请人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
发明人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
IPC分类号: C08F200
CPC分类号: C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F210/16 , C08F2410/02 , Y10S526/901 , C08F2/40 , C08F4/52 , C08F4/6493 , C08F4/6494 , C08F2/002 , C08F4/65925 , C08F210/14 , C08F2500/12 , C08F4/6492
摘要: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with an olefin polymerization catalyst and at least one ether comprising at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)m—R3 in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.
摘要翻译: 一种用于生产烯烃的均聚物和共聚体的新方法,其包括在聚合条件下使烯烃和/或烯烃与至少一种或多种其它烯烃与烯烃聚合催化剂和至少一种包含至少一种碳 - 式-R 1 -O(-R 2 -O)m -R 3的氧 - 碳键(COC),其量足以减少聚合介质中的静电电荷。 还公开了一种减少烯烃聚合介质中的静电荷的方法。
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公开(公告)号:US06300432B1
公开(公告)日:2001-10-09
申请号:US09387667
申请日:1999-08-31
申请人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
发明人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
IPC分类号: C08F462
CPC分类号: C08F10/00 , C08F210/16 , Y10S526/901 , C08F4/6293 , C08F2/002 , C08F4/6294 , C08F210/14 , C08F2500/12
摘要: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with at least one Ziegler-Natta catalyst comprising a component comprising at least one transition metal and a co-catalyst comprising at least one organometallic compound and at least one compound comprising at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)m—R3 in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.
摘要翻译: 一种用于生产烯烃均聚物和互聚物的新方法,其包括在聚合条件下使烯烃和/或烯烃和至少一种或多种其它烯烃与至少一种齐格勒 - 纳塔催化剂接触,所述齐格勒 - 纳塔催化剂包含至少一个转化 金属和助催化剂,其包含至少一种有机金属化合物和至少一种包含至少一种式R 1 -O(-R 2 -O)m -R 3的碳 - 碳 - 碳键(COC)的化合物,其量足以减少 聚合介质中的静电荷。 还公开了一种减少烯烃聚合介质中的静电荷的方法。
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公开(公告)号:US06288181B1
公开(公告)日:2001-09-11
申请号:US09387600
申请日:1999-08-31
申请人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
发明人: Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
IPC分类号: C08F442
CPC分类号: C08F10/00 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F210/16 , Y10S526/901 , Y10S526/943 , C08F2/002 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F210/06 , C08F210/08
摘要: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with a metallocene catalyst and at least one ether comprising at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)m—R3 in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.
摘要翻译: 一种用于生产烯烃均聚物和互聚物的新方法,其包括在聚合条件下使烯烃和/或烯烃与至少一种或多种其它烯烃与金属茂催化剂和至少一种包含至少一种碳 - 氧的醚接触 - 碳键(COC),其量为足以减少聚合介质中的静电电荷的式R 1 -O(-R 2 -O)m -R 3。 还公开了一种减少烯烃聚合介质中的静电荷的方法。
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公开(公告)号:US06187879B1
公开(公告)日:2001-02-13
申请号:US09387366
申请日:1999-08-31
IPC分类号: C08F1002
CPC分类号: C08F10/00 , C08F4/65908 , C08F4/6592 , C08F4/65925 , C08F210/16 , Y10S526/901 , C08F4/65912 , C08F4/65916 , C08F2/005 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要: A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with an olefin polymerization catalyst and dinitrogen monoxide in an amount sufficient to reduce the electrostatic charge in the polymerization medium. Also provided is a process for reducing electrostatic charge in the polymerization of an olefin by adding dinitrogen monoxide.
摘要翻译: 一种制备烯烃均聚物和互聚物的新方法,其包括在聚合条件下使烯烃和/或烯烃与至少一种或多种其它烯烃与烯烃聚合催化剂和一氧化二氮反应,其量足以降低静电 在聚合介质中充电。 还提供了通过添加一氧化二氮来减少烯烃聚合中的静电荷的方法。
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公开(公告)号:US06417299B1
公开(公告)日:2002-07-09
申请号:US09387364
申请日:1999-08-31
IPC分类号: C08F200
CPC分类号: C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65925 , C08F210/16 , Y10S526/943 , C08F4/6495 , C08F4/6465 , C08F4/6496 , C08F4/6494 , C08F4/65916 , C08F210/06 , C08F2500/12 , C08F2500/08 , C08F2500/26 , C08F210/14
摘要: There is described a process for producing ethylene/olefin interpolymers which, for a given melt index and density, have a reduced melting peak temperature (Tm). The process involves contacting ethylene and at least one other olefin under polymerization conditions with an olefin polymerization catalyst and at least one modifier comprising at least one element from Group 15 and/or Group 16 in amounts sufficient to reduce the melting peak temperature of the ethylene/olefin interpolymer. Also described herein are novel ethylene/olefin interpolymers resulting from the process.
摘要翻译: 描述了一种用于生产乙烯/烯烃互聚物的方法,其对于给定的熔体指数和密度具有降低的熔融峰温度(Tm)。 该方法包括在聚合条件下使乙烯和至少一种其它烯烃与烯烃聚合催化剂和至少一种包含至少一种来自第15族和/或第16族的元素的改性剂以足以降低乙烯/ 烯烃互聚物。 本文还描述了由该方法得到的新型乙烯/烯烃互聚物。
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