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公开(公告)号：US07652113B2
公开(公告)日：2010-01-26
申请号：US10465194
申请日：2003-06-19
IPC分类号： C08F210/00 , C08F10/14
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6494 , C08F4/6493 , C08F2/40 , C08F2/005 , C08F210/14 , C08F2500/12
摘要： A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provide is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.
摘要翻译： 提供了一种用于烯烃聚合的新方法。 该方法包括在指定化合物存在下使至少一种烯烃与齐格勒 - 纳塔型催化剂接触，导致产生具有较窄分子量分布的聚合产物。 还提供了使聚烯烃的分子量分布变窄的方法，其包括使烯烃，齐格勒 - 纳塔催化剂和本文指定的化合物接触。 还提供了新型聚乙烯，以及由其制备的薄膜和制品。
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公开(公告)号：US06534613B2
公开(公告)日：2003-03-18
申请号：US09912063
申请日：2001-07-24
申请人： Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人： Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号： C08F1002
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12
摘要： A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst, at least one halogenated hydrocarbon, at least one compound of the formula XnER3-n as a co-catalyst and at least one compound containing at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)n—R3 as an external electron donor. Also provided are films and articles produced therefrom.
摘要翻译： 一种用于生产乙烯均聚物和共聚物的新方法，其涉及使聚乙烯和/或乙烯与至少一种或多种其它烯烃在齐格勒 - 纳塔型催化剂，至少一种卤代烃，至少一种化合物 的式XnER 3-n作为助催化剂和至少一种含有至少一个式R 1 -O（-R 2 -O）n -R 3的碳 - 碳 - 碳键（COC）的化合物作为外电子给体。 还提供了由其制备的薄膜和制品。
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公开(公告)号：US06417298B1
公开(公告)日：2002-07-09
申请号：US09387363
申请日：1999-08-31
IPC分类号： C08F204
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/6592 , C08F210/14 , C08F210/16 , Y10S526/943 , C08F4/65908 , C08F2/002 , C08F210/06 , C08F210/08
摘要： There is described a process utilizing metallocene catalyst for producing ethylene/olefin interpolymers which, for a given melt index and density, have a reduced melting peak temperature (Tm). The process involves contacting ethylene and at least one other olefin under polymerization conditions with a metallocene catalyst and at least one modifier comprising at least one element from Group 15 and/or Group 16 in amounts sufficient to reduce the melting peak temperature of the ethylene/olefin interpolymer. Also described herein are novel ethylene/olefin interpolymers resulting from the process.
摘要翻译： 描述了一种利用茂金属催化剂生产乙烯/烯烃互聚物的方法，对于给定的熔体指数和密度，熔融指数和密度具有降低的熔融峰温度（Tm）。 该方法包括在聚合条件下使乙烯和至少一种其它烯烃与金属茂催化剂和至少一种包含至少一种来自第15族和/或第16族的元素的改性剂以足以降低乙烯/烯烃的熔融峰温度的量 互聚物 本文还描述了由该方法得到的新型乙烯/烯烃互聚物。
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公开(公告)号：US06300432B1
公开(公告)日：2001-10-09
申请号：US09387667
申请日：1999-08-31
申请人： Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
发明人： Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
IPC分类号： C08F462
CPC分类号： C08F10/00 , C08F210/16 , Y10S526/901 , C08F4/6293 , C08F2/002 , C08F4/6294 , C08F210/14 , C08F2500/12
摘要： A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with at least one Ziegler-Natta catalyst comprising a component comprising at least one transition metal and a co-catalyst comprising at least one organometallic compound and at least one compound comprising at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)m—R3 in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.
摘要翻译： 一种用于生产烯烃均聚物和互聚物的新方法，其包括在聚合条件下使烯烃和/或烯烃和至少一种或多种其它烯烃与至少一种齐格勒 - 纳塔催化剂接触，所述齐格勒 - 纳塔催化剂包含至少一个转化 金属和助催化剂，其包含至少一种有机金属化合物和至少一种包含至少一种式R 1 -O（-R 2 -O）m -R 3的碳 - 碳 - 碳键（COC）的化合物，其量足以减少 聚合介质中的静电荷。 还公开了一种减少烯烃聚合介质中的静电荷的方法。
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公开(公告)号：US06291613B1
公开(公告)日：2001-09-18
申请号：US09387601
申请日：1999-08-31
IPC分类号： C08F460
CPC分类号： C08F210/16 , C08F10/00 , Y10S526/901 , C08F4/6493 , C08F2/005 , C08F2/40 , C08F210/14 , C08F2500/12
摘要： A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta catalyst in the presence of dinitrogen monoxide in the production of polymeric products having a narrower molecular weight distribution. A process for narrowing molecular weight distribution of polyolefins utilizing dinitrogen monoxide is also provided.
摘要翻译： 提供了一种用于烯烃聚合的新方法。 该方法包括在一氧化二氮存在下使至少一种烯烃与齐格勒 - 纳塔催化剂接触，生产具有较窄分子量分布的聚合产物。 还提供了使用一氧化二氮来缩小聚烯烃的分子量分布的方法。
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公开(公告)号：US06288181B1
公开(公告)日：2001-09-11
申请号：US09387600
申请日：1999-08-31
申请人： Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
发明人： Randal Ray Ford , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Roxanna Lea Whitfield , Alan George Wonders
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F210/16 , Y10S526/901 , Y10S526/943 , C08F2/002 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F210/06 , C08F210/08
摘要： A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with a metallocene catalyst and at least one ether comprising at least one carbon-oxygen-carbon linkage (C—O—C) of the formula R1—O(—R2—O)m—R3 in amounts sufficient to reduce the electrostatic charge in the polymerization medium. Also disclosed is a process for reducing electrostatic charge in an olefin polymerization medium.
摘要翻译： 一种用于生产烯烃均聚物和互聚物的新方法，其包括在聚合条件下使烯烃和/或烯烃与至少一种或多种其它烯烃与金属茂催化剂和至少一种包含至少一种碳 - 氧的醚接触 - 碳键（COC），其量为足以减少聚合介质中的静电电荷的式R 1 -O（-R 2 -O）m -R 3。 还公开了一种减少烯烃聚合介质中的静电荷的方法。
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公开(公告)号：US6111036A
公开(公告)日：2000-08-29
申请号：US951597
申请日：1997-10-16
申请人： Alan George Wonders , Mark Alan Edmund , Anthony Dominick Messina , Steven Paul Bellner , Randal Ray Ford
发明人： Alan George Wonders , Mark Alan Edmund , Anthony Dominick Messina , Steven Paul Bellner , Randal Ray Ford
CPC分类号： B01J8/24 , B01J8/1836 , C08F10/00 , B01J2208/00274
摘要： Disclosed herein is a fluid bed polymerization process including an improved method for cooling the fluid bed. The recycled fluid stream is cooled by a method comprisinga) cooling said gas sufficiently to condense a portion of said gas to a liquid,b) thereafter separating said liquid from said cooled gas,c) compressing said cooled gas,d) thereafter recooling said cooled gas sufficiently to condense a portion thereof to a liquid,e) reintroducing said liquid portions and said recooled gas into said reactor sufficiently to maintain reactive conditions.
摘要翻译： 本文公开了一种流化床聚合方法，其包括用于冷却流化床的改进方法。 通过以下方法冷却回收的流体流：a）充分冷却所述气体以将一部分所述气体冷凝成液体，b）此后将所述液体与所述冷却气体分离，c）压缩所述冷却气体，d）然后将所述气体再冷却 足以将其一部分冷凝成液体，e）将所述液体部分和所述再冷却气体重新引入所述反应器中以充分维持反应条件。
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8.发明申请PROCESS FOR THE POLYMERIZATION OF OLEFINS; NOVEL POLYETHYLENES, AND FILMS AND ARTICLES PRODUCED THEREFROM 有权烯烃聚合方法; 新型聚乙烯，以及生产的薄膜和文章公开(公告)号：US20080146760A1
公开(公告)日：2008-06-19
申请号：US11841666
申请日：2007-08-20
IPC分类号： C08F210/14
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6494 , C08F4/6493 , C08F2/40 , C08F2/005 , C08F210/14 , C08F2500/12
摘要： A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provide is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.
摘要翻译： 提供了一种用于烯烃聚合的新方法。 该方法包括在指定化合物存在下使至少一种烯烃与齐格勒 - 纳塔型催化剂接触，导致产生具有较窄分子量分布的聚合产物。 还提供了使聚烯烃的分子量分布变窄的方法，其包括使烯烃，齐格勒 - 纳塔催化剂和本文指定的化合物接触。 还提供了新型聚乙烯，以及由其制备的薄膜和制品。
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公开(公告)号：US06271321B1
公开(公告)日：2001-08-07
申请号：US09251969
申请日：1999-02-17
申请人： Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
发明人： Randal Ray Ford , William Albert Ames , Kenneth Alan Dooley , Jeffrey James Vanderbilt , Alan George Wonders
IPC分类号： C08F416
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6493 , C08F4/6494 , C08F210/14 , C08F2500/12
摘要： A novel process for producing homopolymers and copolymers of ethylene which involves contacting ethylene and/or ethylene and at least one or more other olefin(s) under polymerization conditions with a Ziegler-Natta type catalyst containing at least one or more internal electron donors, trimethylaluminum and at least one or more external electron donors containing at least one carbon-oxygen-carbon linkage (C—O—C) selected from the group consisting of Formula 1, R1—CH2—O—CH2—R2, Formula 2, Formula 3, R5—O—R6, and Formula 4, R7—O(—R8—O)n—R9. Also provided are films and articles produced therefrom.
摘要翻译： 一种用于生产乙烯均聚物和共聚物的新方法，其包括在聚合条件下使乙烯和/或乙烯与至少一种或多种其它烯烃与含有至少一种或多种内部电子给体的齐格勒 - 纳塔型催化剂接触，三甲基铝 和至少一种或多种含有选自由式1，式2，式3和式4组成的组中的至少一个碳 - 碳 - 碳键（COC）的外部电子给体。还提供了由其制备的薄膜和制品。
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公开(公告)号：US06187879B1
公开(公告)日：2001-02-13
申请号：US09387366
申请日：1999-08-31
IPC分类号： C08F1002
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/6592 , C08F4/65925 , C08F210/16 , Y10S526/901 , C08F4/65912 , C08F4/65916 , C08F2/005 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要： A novel process for producing homopolymers and interpolymers of olefins which involves contacting an olefin and/or an olefin and at least one or more other olefin(s) under polymerization conditions with an olefin polymerization catalyst and dinitrogen monoxide in an amount sufficient to reduce the electrostatic charge in the polymerization medium. Also provided is a process for reducing electrostatic charge in the polymerization of an olefin by adding dinitrogen monoxide.
摘要翻译： 一种制备烯烃均聚物和互聚物的新方法，其包括在聚合条件下使烯烃和/或烯烃与至少一种或多种其它烯烃与烯烃聚合催化剂和一氧化二氮反应，其量足以降低静电 在聚合介质中充电。 还提供了通过添加一氧化二氮来减少烯烃聚合中的静电荷的方法。
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