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1.发明授权Fluorinated polymer and amine resin compositions and products formed therefrom 有权氟化聚合物和胺树脂组合物及由其形成的产品公开(公告)号：US07320829B2
公开(公告)日：2008-01-22
申请号：US10774187
申请日：2004-02-05
申请人： Joe A. Wright , Daniel D. Woodland , Raymond J. Weinert, Jr. , James E. Robbins , Robert E. Medsker , Edward N. Kresge , Daniel C. Gottschalk , Guillermina C. Garcia , Martin J. Fay
发明人： Joe A. Wright , Daniel D. Woodland , Raymond J. Weinert, Jr. , James E. Robbins , Robert E. Medsker , Edward N. Kresge , Daniel C. Gottschalk , Guillermina C. Garcia , Martin J. Fay
CPC分类号： C08G18/10 , C08G18/5015 , C08G63/682 , C08G63/6824 , C08G65/18 , C08G65/226 , C08J3/244 , C08J7/047 , C08J2367/00 , C08J2467/00 , C08L61/20 , C08L67/00 , C09D167/00 , Y10T428/3154 , Y10T428/31551 , Y10T428/31681 , Y10T428/31786 , Y10T428/3179 , Y10T428/31794 , Y10T428/31797 , C08G18/46 , C08L2666/14 , C08L2666/16
摘要： A reactive fluorinated polymer having polyester and polyether segments is mixed with a reactive melamine resin to form a coating composition. The polyether segment can include monomeric units from an oxetane monomer having pendant fluorine groups that are linked to the oxetane via an ether group. The melamine resin can be a lower alkyl etherified melamine-formaldehyde. The composition can be disposed on a substrate and treated to form a laminate.
摘要翻译： 将具有聚酯和聚醚链段的反应性氟化聚合物与反应性三聚氰胺树脂混合以形成涂料组合物。 聚醚链段可包括具有通过醚基与氧杂环丁烷连接的具有侧基氟基的氧杂环丁烷单体的单体单元。 三聚氰胺树脂可以是低级烷基醚化三聚氰胺 - 甲醛。 组合物可以设置在基底上并进行处理以形成层压体。
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公开(公告)号：US06383651B1
公开(公告)日：2002-05-07
申请号：US09384464
申请日：1999-08-27
IPC分类号： B32B2706
CPC分类号： C08G65/226 , C08G18/10 , C08G18/5015 , C08G63/6824 , C08G65/18 , C09D167/00 , Y10T428/31786 , Y10T428/31794 , C08G18/46 , C08L2666/14
摘要： A polyester polymer including at least one polyoxetane block of repeating units derived from polymerizing at least one oxetane monomer having at least one pendant —CH2—O—(CH2)n— Rf group wherein said Rf group is partially or fully fluorinated is described. A preferred process for forming said polymer by reacting the hydroxyl terminated polymer with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants.
摘要翻译： 描述了聚酯聚合物，其包含至少一个衍生自聚合至少一种具有至少一个侧基-CH 2 -O-（CH 2）n-Rf基团的氧杂环丁烷单体的重复单元的聚氧杂环丁烷嵌段，其中所述Rf基团部分或完全氟化。 通过在适当的条件下使羟基封端的聚合物与多元羧酸反应形成所述聚合物以形成酯键，然后将该产物与形成聚酯的反应物相加并反应的优选方法。
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公开(公告)号：US06579966B1
公开(公告)日：2003-06-17
申请号：US10294942
申请日：2002-11-14
申请人： Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Edward N. Kresge , Daniel C. Gottschalk , Joe A. Wright
发明人： Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Edward N. Kresge , Daniel C. Gottschalk , Joe A. Wright
IPC分类号： C08G7324
CPC分类号： C08G18/10 , C08G18/5015 , C08G63/682 , C08G63/6824 , C08G65/18 , C08G65/226 , C08J7/047 , C08J2467/00 , C08L61/20 , C08L67/00 , C09D167/00 , Y10T428/31681 , Y10T428/31794 , Y10T428/31797 , C08G18/46 , C08L2666/14 , C08L2666/16
摘要： A polyester polymer includes at least one hydroxyl terminated polyoxetane block containing repeat units derived from polymerizing at least one oxetane monomer having a pendant —CH2—O—(CH2)n—Rf group wherein said Rf group is partially or fully fluorinated. A preferred process for forming said polymer is by reacting a hydroxyl terminated polyoxetane with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants. The polyester polymer containing at least one polyoxetane block therein when reacted with an amino resin curative can be used as a coating on a substrate wherein the coating has dry erase properties. The coated substrate can be used as prepared or applied to yet other substrates.
摘要翻译： 聚酯聚合物包括至少一个羟基封端的聚氧杂环丁烷嵌段，其含有聚合至少一种具有侧基-CH 2 -O-（CH 2）n -R f基团的氧杂环丁烷单体的重复单元，其中所述Rf基部分或完全氟化。 形成所述聚合物的优选方法是在合适的条件下使羟基封端的聚氧杂环丁烷与多元羧酸反应以形成酯键，然后将该产物与形成聚酯的反应物加成并反应。 当与氨基树脂固化剂反应时，其中含有至少一个聚氧杂环丁烷嵌段的聚酯聚合物可以用作基材上的涂层，其中涂层具有干擦除性质。 涂覆的基底可以用作制备的或应用于其它基底。
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公开(公告)号：US07846507B2
公开(公告)日：2010-12-07
申请号：US10966528
申请日：2004-10-15
申请人： Marten S. Callicott , David L. Hyde , Charles M. Kausch , Anthony Verrocchi , Joe A. Wright , Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Daniel C. Gottschalk , Edward N. Kresge
发明人： Marten S. Callicott , David L. Hyde , Charles M. Kausch , Anthony Verrocchi , Joe A. Wright , Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Daniel C. Gottschalk , Edward N. Kresge
CPC分类号： C09D167/00 , C08G18/10 , C08G18/5015 , C08G65/18 , C08G65/226 , Y10T428/31786 , Y10T428/31797 , C08L2666/14 , C08G18/46
摘要： A method for preparing a substrate having an adherent, durable, flexible, and stain resistant layer. The layer is formed by applying a composition that includes (i) the reaction product of a polyester and a polyoxetane having at least one carboxylic acid end group and at least one pendant —CH2—O—(CH2)n—Rf group and (ii) an amino resin curative. The substrate may be printed or embossed or both. The coated substrate has both stain resistant properties and dry erase properties.
摘要翻译： 一种制备具有粘附性，耐久性，柔韧性和耐污染层的基材的方法。 通过施加包括（i）具有至少一个羧酸端基和至少一个侧链-CH 2 -O-（CH 2）n -RF基团的聚酯和聚氧杂丙烷的反应产物和（ii） ）氨基树脂治疗剂。 基底可以印刷或压花或两者。 涂覆的基材具有耐污性和干擦性能。
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公开(公告)号：US06686051B1
公开(公告)日：2004-02-03
申请号：US09698554
申请日：2000-10-27
申请人： Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Edward N. Kresge , Daniel C. Gottschalk , Joe A. Wright
发明人： Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Edward N. Kresge , Daniel C. Gottschalk , Joe A. Wright
IPC分类号： B32B1508
CPC分类号： C08G18/10 , C08G18/5015 , C08G63/682 , C08G63/6824 , C08G65/18 , C08G65/226 , C08J7/047 , C08J2467/00 , C08L61/20 , C08L67/00 , C09D167/00 , Y10T428/31681 , Y10T428/31794 , Y10T428/31797 , C08G18/46 , C08L2666/14 , C08L2666/16
摘要： A polyester polymer includes at least one hydroxyl terminated polyoxetane block containing repeat units derived from polymerizing at least one oxetane monomer having a pendant —CH2—O—(CH2)n—Rf group wherein said Rf group is partially or fully fluorinated. A preferred process for forming said polymer is by reacting a hydroxyl terminated polyoxetane with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants. The polyester polymer containing at least one polyoxetane block therein when reacted with an amino resin curative can be used as a coating on a substrate wherein the coating has dry erase properties. The coated substrate can be used as prepared or applied to yet other substrates.
摘要翻译： 聚酯聚合物包括至少一个羟基封端的聚氧杂环丁烷嵌段，其含有聚合至少一种具有侧基-CH 2 -O-（CH 2）n -R f基团的氧杂环丁烷单体的重复单元，其中所述Rf基部分或完全氟化。 形成所述聚合物的优选方法是在合适的条件下使羟基封端的聚氧杂环丁烷与多元羧酸反应以形成酯键，然后将该产物与形成聚酯的反应物加成并反应。 当与氨基树脂固化剂反应时，其中含有至少一个聚氧杂环丁烷嵌段的聚酯聚合物可以用作基材上的涂层，其中涂层具有干擦除性质。 涂覆的基底可以用作制备的或应用于其它基底。
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公开(公告)号：US06423418B1
公开(公告)日：2002-07-23
申请号：US09244711
申请日：1999-02-04
申请人： Marten S. Callicott , David L. Hyde , Charles M. Kausch , Anthony Verrocchi , Joe A. Wright , Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Daniel C. Gottschalk
发明人： Marten S. Callicott , David L. Hyde , Charles M. Kausch , Anthony Verrocchi , Joe A. Wright , Raymond J. Weinert , Robert E. Medsker , Daniel D. Woodland , Daniel C. Gottschalk
IPC分类号： B32B1508
CPC分类号： C08G18/10 , C08G18/5015 , C08G65/18 , C08G65/226 , C09D167/00 , Y10T428/31681 , Y10T428/31794 , Y10T428/31797 , C08G18/46 , C08L2666/14
摘要： A substrate having an adherent and stain resistant layer having durability and flexibility, said layer comprising the reaction product of a reactive polyester having free carboxylic acid and/or hydroxyl groups, a hydroxyl terminated polymer including repeat units from an oxetane having pendant —CH2—O—(CH2)n—Rf groups (said Rf groups generally being a fluorinated alkyl group) and an amino resin curative. The substrate may be printed or embossed or both. The coated substrate has both stain resistant properties and dry erase properties with dry erase markers. The coated substrate can be used as prepared or applied to other substrates.
摘要翻译： 具有耐久性和柔韧性的粘附防污层的基材，所述层包含具有游离羧酸和/或羟基的反应性聚酯的反应产物，羟基封端的聚合物，包括具有侧链-CH2-O的氧杂环丁烷的重复单元 - （CH 2）n -R f基团（所述Rf基团通常为氟化烷基）和氨基树脂固化剂。 基底可以印刷或压花或两者。 涂布的基材具有抗干燥性和干擦拭性能，具有干擦痕标记。 涂覆的基材可以制备或应用于其它基材使用。
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7.发明授权公开(公告)号：US07087710B2
公开(公告)日：2006-08-08
申请号：US10882738
申请日：2004-06-30
申请人： Robert E. Medsker , Richard R. Thomas , Charles M. Kausch , Daniel D. Woodland , Raymond J. Weinert , Jane E. Leising , Yongsin Kim
发明人： Robert E. Medsker , Richard R. Thomas , Charles M. Kausch , Daniel D. Woodland , Raymond J. Weinert , Jane E. Leising , Yongsin Kim
IPC分类号： C08G65/22
CPC分类号： C08G65/226 , C08G65/18 , C08L71/02 , C08L2205/05 , C08L71/00
摘要： A fluorine containing polymer which acts as a wetting, flow or leveling agent, and has at least one polar group. The polymer has at least one pendant or ether side chain containing from about 1 to about 20 carbon atoms with at least 25% of the hydrogen atoms being replaced by fluorine atoms. The fluorinated polymers unexpectedly impart wetting, flow or leveling properties to a variety of coatings while producing little foam.
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8.发明授权Fluorinated short carbon atom side chain and polar group containing polymer, and flow, or leveling, or wetting agents thereof 有权氟化短碳原子侧链和含极性基团的聚合物，以及流动或流平或其润湿剂公开(公告)号：US06660828B2
公开(公告)日：2003-12-09
申请号：US09855053
申请日：2001-05-14
申请人： Richard R. Thomas , Robert E. Medsker , Charles M. Kausch , Daniel D. Woodland , Gary L. Jialanella , Raymond J. Weinert , Jane E. Leising , James E. Robbins , Brian T. Cartwright
发明人： Richard R. Thomas , Robert E. Medsker , Charles M. Kausch , Daniel D. Woodland , Gary L. Jialanella , Raymond J. Weinert , Jane E. Leising , James E. Robbins , Brian T. Cartwright
IPC分类号： C08G6522
CPC分类号： C08G65/226 , C08G65/18 , C08L71/02 , C08L2205/05 , Y10S525/934 , C08L71/00
摘要： The polymer of the present invention is derived from cyclic ether monomers, dioxane, dioxalane or trioxane and contains both pendant Rf fluoro groups as well as polar groups. These polymers have good wetting, or flow, or leveling properties. They can be reacted with other monomers, such as in the preparation of polyesters, and can be used in waxes, polishes and coatings.
摘要翻译： 本发明的聚合物衍生自环醚单体，二恶烷，二氧杂环戊烷或三恶烷，并且含有Rf侧氟基团以及极性基团。 这些聚合物具有良好的润湿性，流动性或流平性。 它们可以与其他单体反应，例如在聚酯的制备中，并且可以用于蜡，抛光剂和涂料中。
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9.发明授权Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer 有权一元多氟氧杂环丁烷聚合物和含有单官能多氟氧杂环丁烷聚合物的可辐射固化涂层公开(公告)号：US06727344B2
公开(公告)日：2004-04-27
申请号：US10108318
申请日：2002-03-28
IPC分类号： C08G6522
CPC分类号： C09D175/16 , C08G18/5015 , C08G18/672 , C08G65/226 , Y10T428/31794 , C08G18/50
摘要： Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.
摘要翻译： 单官能聚氟乙烯低聚物和聚合物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 氟氧杂环丁烷低聚物或聚合物可以与通常的环醚共聚。 或者，具有单个羟基端基的多氟氧杂环丁烷低聚物或聚合物可以用各种化合物进行官能化，以产生官能化低聚物如丙烯酸酯，甲基丙烯酸酯，烯丙基胺，胺等官能端基 或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化，以提供以前由迁移的化学品如蜡和油提供的润湿和表面性能的改进。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。
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10.发明授权Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer 失效一元多氟氧杂环丁烷聚合物和含有单官能多氟氧杂环丁烷聚合物的可辐射固化涂层公开(公告)号：US06972317B2
公开(公告)日：2005-12-06
申请号：US10108916
申请日：2002-03-28
IPC分类号： C08G18/50 , C08G18/67 , C08G65/22 , C09D175/16
CPC分类号： C09D175/16 , C08G18/5015 , C08G18/672 , C08G65/226 , Y10T428/31794 , C08G18/50
摘要： Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.
摘要翻译： 单官能聚氟乙烯低聚物和聚合物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 氟氧杂环丁烷低聚物或聚合物可以与通常的环醚共聚。 或者，具有单个羟基端基的多氟氧杂环丁烷低聚物或聚合物可以用各种化合物进行官能化，以产生官能化低聚物等丙烯酸酯，甲基丙烯酸酯，烯丙基胺，胺等功能性端基 或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化，以提供以前由迁移的化学品如蜡和油提供的润湿和表面性能的改进。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。
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