CELL FOR ELECTROCHEMICALLY DETERMINING ACTIVE SPECIES CONCENTRATIONS IN REDOX FLOW BATTERIES

    公开(公告)号:US20230131299A1

    公开(公告)日:2023-04-27

    申请号:US18088440

    申请日:2022-12-23

    Abstract: A redox flow battery system with a redox flow battery includes a redox flow cell, and a supply/storage system external of the redox flow cell. The supply/storage system includes first and second electrolytes for circulation through the redox flow cell. At least the first electrolyte is a liquid electrolyte that has electrochemically active species with multiple, reversible oxidation states. A secondary cell is fluidly connected with the first electrolyte and is operable to monitor concentration of one or more of the electrochemically active species. The secondary cell includes a counter electrode, a working microelectrode, and an ionically conductive path formed by the first electrolyte between the counter electrode and the working microelectrode.

    Condensation-based redox flow battery rebalancing

    公开(公告)号:US11923583B2

    公开(公告)日:2024-03-05

    申请号:US17521238

    申请日:2021-11-08

    CPC classification number: H01M8/188 H01M8/04186 H01M8/04164

    Abstract: In a redox flow battery (RFB), the base solvent of the electrolytes tends to migrate across the barrier layer from one electrode toward the other. This can result in a volume and concentration imbalance between the electrolytes that is detrimental to battery efficiency and capacity. Compatible electrolytes can be mixed to rebalance the system, but for incompatible electrolytes mixing is not a viable option. To this end, the RFB herein includes a separator that recovers base solvent from the vapor phase of one of the electrolytes and returns the recovered base solvent to the other electrolyte to thereby reverse the imbalance.

    CONDENSATION-BASED REDOX FLOW BATTERY REBALANCING

    公开(公告)号:US20230144710A1

    公开(公告)日:2023-05-11

    申请号:US17521238

    申请日:2021-11-08

    CPC classification number: H01M8/188 H01M8/04186 H01M8/04164

    Abstract: In a redox flow battery (RFB), the base solvent of the electrolytes tends to migrate across the barrier layer from one electrode toward the other. This can result in a volume and concentration imbalance between the electrolytes that is detrimental to battery efficiency and capacity. Compatible electrolytes can be mixed to rebalance the system, but for incompatible electrolytes mixing is not a viable option. To this end, the RFB herein includes a separator that recovers base solvent from the vapor phase of one of the electrolytes and returns the recovered base solvent to the other electrolyte to thereby reverse the imbalance.

    REDOX FLOW BATTERY WITH IMPROVED EFFICIENCY

    公开(公告)号:US20220190364A1

    公开(公告)日:2022-06-16

    申请号:US17119408

    申请日:2020-12-11

    Abstract: A method for maintaining a redox flow includes draining a first battery electrolyte solution from a redox flow battery cell, the cell including a separator layer arranged between a first electrode and a second electrode, a first circulation loop configured to provide the first battery electrolyte solution to the first electrode and a second circulation loop configured to provide a second battery electrolyte solution to the second electrode; and flowing a non-battery electrolyte solution through the first electrode. The non-battery electrolyte removes at least a portion of the solid precipitates from at least one of the first electrode and the separator layer. The method also includes draining the non-battery electrolyte solution from the cell and returning the first battery electrolyte solution to the cell. A method for a redox flow battery and a redox flow battery are also disclosed.

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