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公开(公告)号：US4407736A
公开(公告)日：1983-10-04
申请号：US258372
申请日：1981-04-28
IPC分类号： B01J23/656 , B01J37/02 , C10G35/09 , B01J21/12 , B01J23/64
CPC分类号： B01J37/024 , B01J23/6567 , C10G35/09
摘要： A hydrocarbon conversion catalyst comprising at least one platinum-group metal deposited on a composite comprising (I) alumina and (II) rhenium deposited on silica. The catalyst eliminates the need for presulfiding treatment required by conventional rhenium-promoted catalyst in reforming service, without comparative loss in reforming performance.
摘要翻译： 一种烃转化催化剂，其包含沉积在包含沉积在二氧化硅上的（I）氧化铝和（II）铼）的复合材料上的至少一种铂族金属。 该催化剂不需要在重整操作中常规的铼促进催化剂所需的预硫化处理，而在重整性能上没有相应的损失。
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公开(公告)号：US4319984A
公开(公告)日：1982-03-16
申请号：US237721
申请日：1981-02-24
IPC分类号： B01J23/656 , B01J37/04 , C10G35/09 , C10G35/06
CPC分类号： B01J23/6567 , B01J37/04 , C10G35/09
摘要： There is disclosed a catalyst, which catalyst comprises a physical particle-form mixture of a Component A and a Component B, said Component A comprising at least one Group VIII noble metal deposed on a solid catalyst support material providing acidic catalytic sites and said Component B comprising rhenium or a compound of rhenium deposed on a solid catalyst support material, said catalyst having been prepared by thoroughly blending finely-divided particles of Component A and Component B to provide a thoroughly-blended composite, said finely-divided particles having a particle diameter that is less than 100 mesh (150 microns), and forming said composite into particles having a size that is greater than 100 mesh (150 microns) and being suitable for use in a hydrocarbon conversion reaction zone.The catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reaction zone under reforming conditions and in the presence of hydrogen with said catalyst.
摘要翻译： 公开了一种催化剂，该催化剂包含组分A和组分B的物理颗粒形式的混合物，所述组分A包含至少一种第八族贵金属，其位于提供酸性催化位点的固体催化剂载体材料上，所述组分B 所述催化剂是通过将组分A和组分B的细碎颗粒充分混合而制备的，以提供充分混合的复合材料，所述细碎颗粒具有颗粒直径 小于100目（150微米），并将所述复合物形成为尺寸大于100目（150微米）的颗粒，并且适用于烃转化反应区。 该催化剂可用于烃流重整的方法中，该方法包括在重整条件下和氢气存在下，将所述物流在反应区中与所述催化剂接触。
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公开(公告)号：US4302358A
公开(公告)日：1981-11-24
申请号：US86707
申请日：1979-10-22
CPC分类号： C10G35/09 , B01J23/6567 , B01J37/04
摘要： There is disclosed a catalyst, which catalyst comprises a physical particle-form mixture of a Component A and a Component B, said Component A comprising at least one Group VIII noble metal deposed on a solid catalyst support material providing acidic catalytic sites and said Component B comprising rhenium or a compound of rhenium deposed on a solid catalyst support material, said catalyst having been prepared by thoroughly blending finely-divided particles of Component A and Component B to provide a thoroughly-blended composite, said finely-divided particles having a particle diameter that is less than 100 mesh (150 microns), and forming said composite into particles having a size that is greater than 100 mesh (150 microns) and being suitable for use in a hydrocarbon conversion reaction zone.The catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reaction zone under reforming conditions and in the presence of hydrogen with said catalyst.
摘要翻译： 公开了一种催化剂，该催化剂包含组分A和组分B的物理颗粒形式的混合物，所述组分A包含至少一种第八族贵金属，其位于提供酸性催化位点的固体催化剂载体材料上，所述组分B 所述催化剂是通过将组分A和组分B的细碎颗粒充分混合而制备的，以提供充分混合的复合材料，所述细碎颗粒具有颗粒直径 小于100目（150微米），并将所述复合物形成为尺寸大于100目（150微米）的颗粒，并且适用于烃转化反应区。 该催化剂可用于烃流重整的方法中，该方法包括在重整条件下和氢气存在下，将所述物流在反应区中与所述催化剂接触。
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4.发明授权Reforming catalyst containing a group VIII noble metal, a group VIII non-noble metal, and gallium on separate support particles 失效含有VIII族贵金属，VIII族非贵金属和镓的单独载体颗粒上的重整催化剂
公开(公告)号：US4469812A
公开(公告)日：1984-09-04
申请号：US533145
申请日：1983-09-16
CPC分类号： B01J23/896 , B01J37/04 , C10G35/09
摘要： The catalyst comprises a physical particle-form mixture of a Component A, a Component B, and a Component C, said Component A comprising at least one Group VIII noble metal, preferably platinum, deposed on a solid catalyst support material providing acidic catalytic sites, said Component B comprising a small amount of a non-noble metal of Group VIII selected from cobalt, nickel, and mixtures thereof, preferably cobalt, on a solid catalyst support material providing acidic catalytic sites, said Component C comprising a small amount of gallium deposed on a solid catalyst support material providing acidic catalytic sites, and said catalyst having been prepared by thoroughly and intimately blending finely-divided particles of said Components A, B, and C to provide a thoroughly-blended composite.The catalyst can be employed suitably in a hydrocarbon conversion process. In particular, the catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reforming zone under reforming conditions and in the presence of hydrogen with said catalyst. The process can be used advantageously to reform a hydrocarbon stream that contains up to 80 ppm sulfur.
摘要翻译： 催化剂包含组分A，组分B和组分C的物理颗粒形式的混合物，所述组分A包含至少一种第八族贵金属，优选铂，其沉积在提供酸性催化位点的固体催化剂载体材料上， 所述组分B包含少量选自钴，镍及其混合物，优选钴的非贵金属的第Ⅷ族，在提供酸性催化位点的固体催化剂载体材料上，所述组分C包含少量镓， 在提供酸性催化位点的固体催化剂载体材料上，并且所述催化剂通过将所述组分A，B和C的细碎颗粒彻底和紧密地混合以提供充分混合的复合材料制备。 催化剂可以在烃转化方法中适当地使用。 特别地，催化剂可以用于烃流重整的方法中，该方法包括在重整条件下和氢气存在下将所述物流在重整区中与所述催化剂接触。 该方法可有利地用于重整含有高达80ppm硫的烃流。
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5.发明授权Reforming with a catalyst containing a Group VIII noble metal, a Group VIII non-noble metal, and gallium on separate support particles 失效使用含有VIII族贵金属，VIII族非贵金属和镓的催化剂在分开的载体颗粒上重整
公开(公告)号：US4482449A
公开(公告)日：1984-11-13
申请号：US595278
申请日：1984-03-30
IPC分类号： B01J23/89 , B01J37/04 , C10G35/09 , C10G35/085
CPC分类号： C10G35/09 , B01J23/896 , B01J37/04
摘要： The catalyst comprises a physical particle-form mixture of a Componet A, a Component B, and a Component C, said Component A comprising at least one Group VIII noble metal, preferably platinum, deposed on a solid catalyst support material providing acidic catalytic sites, said Component B comprising a small amount of a non-noble metal of Group VIII selected from cobalt, nickel, and mixtures thereof, preferably cobalt, on a solid catalyst support material providing acidic catalytic sites, said Component C comprising a small amount of gallium deposed on a solid catalyst support material providing acidic catalytic sites, and said catalyst having been prepared by thoroughly and intimately blending finely-divided particles of said Component A, B, and C to provide a thoroughly-blended composite.The catalyst can be employed suitably in a hydrocarbon conversion process. In particular, the catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reforming zone under reforming conditions and in the presence of hydrogen with said catalyst. The process can be used advantageously to reform a hydrocarbon stream that contains up to 80 ppm sulfur.
摘要翻译： 所述催化剂包括组分A，组分B和组分C的物理颗粒形式的混合物，所述组分A包含至少一种第八族贵金属，优选铂，其沉积在提供酸性催化位点的固体催化剂载体材料上， 所述组分B包含少量选自钴，镍及其混合物，优选钴的非贵金属的第Ⅷ族，在提供酸性催化位点的固体催化剂载体材料上，所述组分C包含少量镓， 在提供酸性催化位点的固体催化剂载体材料上，并且所述催化剂通过将所述组分A，B和C的细碎颗粒彻底和紧密地混合以提供充分混合的复合材料制备。 催化剂可以在烃转化方法中适当地使用。 特别地，催化剂可以用于烃流重整的方法中，该方法包括在重整条件下和氢气存在下将所述物流在重整区中与所述催化剂接触。 该方法可有利地用于重整含有高达80ppm硫的烃流。
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公开(公告)号：US4401558A
公开(公告)日：1983-08-30
申请号：US318554
申请日：1981-11-05
IPC分类号： B01J37/04 , C10G35/09 , C10G35/085
摘要： There is disclosed a catalyst, which catalyst comprises a physical particle-form mixture of a Component A and a Component B, said Component A comprising one or more Group VIII noble metals and a combined halogen deposed on a refractory inorganic oxide and said Component B comprising a metal from Group IVB or Group VB of the Periodic Table of Elements and a combined halogen deposed on a refractory inorganic oxide. Such catalyst is suitable for use in a hydrocarbon conversion reaction zone.The catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reaction zone under reforming conditions and in the presence of hydrogen with said catalyst. The catalyst is not presulfided. A preferred process comprises contacting a hydrocarbon stream that contains a substantial amount of sulfur.
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公开(公告)号：US4353814A
公开(公告)日：1982-10-12
申请号：US108177
申请日：1979-12-28
摘要： There is disclosed a catalyst, which catalyst comprises a physical particle-form mixture of a Component A and a Component B, said Component A comprising one or more Group VIII noble metals and a combined halogen deposed on a refractory inorganic oxide and said Component B comprising a metal from Group IVB or Group VB of the Periodic Table of Elements and a combined halogen deposed on a refractory inorganic oxide. Such catalyst is suitable for use in a hydrocarbon conversion reaction zone.The catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reaction zone under reforming conditions and in the presence of hydrogen with said catalyst. The catalyst is not presulfided. A preferred process comprises contacting a hydrocarbon stream that contains a substantial amount of sulfur.
摘要翻译： 公开了一种催化剂，该催化剂包含组分A和组分B的物理颗粒形式的混合物，所述组分A包含一种或多种第VIII族贵金属和被置于耐火无机氧化物上的组合卤素，所述组分B包含 元素周期表第IVB族或第VB族的金属，以及沉积在耐火无机氧化物上的组合卤素。 这种催化剂适用于烃转化反应区。 该催化剂可用于烃流重整的方法中，该方法包括在重整条件下和氢气存在下，将所述物流在反应区中与所述催化剂接触。 催化剂未预硫化。 优选的方法包括使含有大量硫的烃流接触。
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公开(公告)号：US4298461A
公开(公告)日：1981-11-03
申请号：US92569
申请日：1979-11-08
IPC分类号： B01J23/656 , B01J37/02 , C10G35/09 , C10G35/06
CPC分类号： B01J23/6567 , B01J37/024 , C10G35/09
摘要： A hydrocarbon conversion catalyst comprising at least one platinum-group metal deposited on a composite comprising (I) alumina and (II) rhenium deposited on silica. The catalyst eliminates the need for presulfiding treatment required by conventional rhenium-promoted catalyst in reforming service, without comparative loss in reforming performance.
摘要翻译： 一种烃转化催化剂，其包含沉积在包含沉积在二氧化硅上的（I）氧化铝和（II）铼）的复合材料上的至少一种铂族金属。 该催化剂不需要在重整操作中常规的铼促进催化剂所需的预硫化处理，而在重整性能上没有相应的损失。
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公开(公告)号：US4261811A
公开(公告)日：1981-04-14
申请号：US27909
申请日：1979-04-06
IPC分类号： C10G35/085 , B01J23/656 , C10G35/09 , C10G35/08
CPC分类号： C10G35/09 , B01J23/6567
摘要： An improved process for the reforming of a hydrocarbon stream, which process comprises contacting said hydrocarbon stream under reforming conditions and in the presence of hydrogen with a catalyst which comprises platinum, rhenium, a small amount of palladium, and combined halogen on a refractory inorganic oxide, such as an alumina, and which has not been presulfided. The improvement comprises a rhenium-containing catalyst which has not been presulfided and which contains a small amount of palladium, i.e., about 0.05 wt. % to about 1 wt. % palladium. The feedstock being reformed can contain up to about 50 ppm sulfur.
摘要翻译： 一种用于烃流重整的改进方法，该方法包括在重整条件下和氢存在下使所述烃流与包含铂，铼，少量钯和在耐火无机氧化物上的组合卤素的催化剂接触 ，例如氧化铝，并且尚未预硫化。 该改进包括未被预硫化并含有少量钯的含铼催化剂，即约0.05wt。 ％至约1wt。 ％钯。 重整的原料可以含有高达约50ppm的硫。
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公开(公告)号：US4497902A
公开(公告)日：1985-02-05
申请号：US536246
申请日：1983-09-27
CPC分类号： B01J21/10 , B01D53/508 , B01J23/10 , C10G11/18
摘要： An absorbent for sulfur oxides comprising an inorganic oxide composition in association with at least one free or combined rare earth metal selected from the group consisting of lanthanum, cerium, praseodymium, samarium and dysprosium, wherein said inorganic oxide composition is selected from the group consisting of MgAl.sub.2 O.sub.4, mixtures of alumina with magnesium oxide and mixtures of magnesium oxide with MgAl.sub.2 O.sub.4. The absorbent can be circulated through a fluidized catalytic cracking process together with hydrocarbon cracking catalyst to reduce sulfur oxide emissions from the regeneration zone.
摘要翻译： 一种用于硫氧化物的吸收剂，其包含与至少一种选自镧，铈，镨，钐和镝的游离或组合的稀土金属相关的无机氧化物组合物，其中所述无机氧化物组合物选自 MgAl2O4，氧化铝与氧化镁的混合物以及氧化镁与MgAl2O4的混合物。 吸收剂可与烃裂化催化剂一起通过流化催化裂化过程循环，以减少再生区的硫氧化物排放。
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