公开(公告)号：US08796345B2

公开(公告)日：2014-08-05

申请号：US13517254

申请日：2010-12-08

申请人： Rene Alexander Klein ,  Christina Marinus ,  Chris Ian Lindsay ,  Hendrikus Abbenhuis ,  Jos Wilting ,  Gijsbert Gerritsen

发明人： Rene Alexander Klein ,  Christina Marinus ,  Chris Ian Lindsay ,  Hendrikus Abbenhuis ,  Jos Wilting ,  Gijsbert Gerritsen

IPC分类号： C08G18/22 ,  C08G18/32 ,  C08G18/38 ,  C08J9/04 ,  C08K5/54

CPC分类号： C08G18/222 ,  C08G18/3893

摘要： A method to form a urethane material, the method comprises blending and reacting at least one isocyanate, at least one isocyanate reactive compound and a metallized polyhedral oligomeric silsesquioxane to provide said urethane material, the metallized polyhedral oligomeric silsesquioxane is a dimeric structure with general formula wherein M represents a metal providing a 6-coordinated metal center, x and y being 1, R1O and R2O represent an alkoxide bridging the 6-coordinated metal centers, R3OH and R4OH represent an alcohol ligand and each of R5, to R18 is selected from the group consisting of alkyl-, polyether- and polyester ligands.

摘要翻译： 一种形成聚氨酯材料的方法，所述方法包括使至少一种异氰酸酯，至少一种异氰酸酯反应性化合物和金属化多面体低聚倍半硅氧烷共混并反应以提供所述聚氨酯材料，所述金属化多面体低聚倍半硅氧烷是具有通式的二聚结构，其中 M表示提供6配位金属中心的金属，x和y为1，R 1 O和R 20代表桥接6-配位金属中心的醇盐，R3OH和R4OH表示醇配体，R 5至R 18中的每一个选自 由烷基，聚醚和聚酯配体组成的组。

公开(公告)号：US20120264840A1

公开(公告)日：2012-10-18

申请号：US13517254

申请日：2010-12-08

申请人： Rene Alexander Klein ,  Christina Marinus ,  Chris Ian Lindsay ,  Hendrikus Abbenhuis ,  Jos Wilting ,  Gijsbert Gerritsen

发明人： Rene Alexander Klein ,  Christina Marinus ,  Chris Ian Lindsay ,  Hendrikus Abbenhuis ,  Jos Wilting ,  Gijsbert Gerritsen

IPC分类号： C08G18/76 ,  C07C269/02 ,  C08J9/06

CPC分类号： C08G18/222 ,  C08G18/3893

摘要： A method to form a urethane material, the method comprises blending and reacting at least one isocyanate, at least one isocyanate reactive compound and a metallized polyhedral oligomeric silsesquioxane to provide said urethane material, the metallized polyhedral oligomeric silsesquioxane is a dimeric structure with general formula wherein M represents a metal providing a 6-coordinated metal center, x and y being 1, R1O and R2O represent an alkoxide bridging the 6-coordinated metal centers, R3OH and R4OH represent an alcohol ligand and each of R5, to R18 is selected from the group consisting of alkyl-, polyether- and polyester ligands.

摘要翻译： 一种形成聚氨酯材料的方法，所述方法包括使至少一种异氰酸酯，至少一种异氰酸酯反应性化合物和金属化多面体低聚倍半硅氧烷共混并反应以提供所述聚氨酯材料，所述金属化多面体低聚倍半硅氧烷是具有通式的二聚结构，其中 M表示提供6配位金属中心的金属，x和y为1，R 1 O和R 20代表桥接6-配位金属中心的醇盐，R3OH和R4OH表示醇配体，R 5至R 18中的每一个选自 由烷基，聚醚和聚酯配体组成的组。

公开(公告)号：US09029483B2

公开(公告)日：2015-05-12

申请号：US13582010

申请日：2011-02-28

申请人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B. M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

发明人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B. M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

IPC分类号： C08G77/398 ,  C08G77/388 ,  C08G77/395 ,  C07F7/21

CPC分类号： C08G77/398 ,  C07F7/21 ,  C08G77/388 ,  C08G77/395

摘要： Polyhedral oligomeric silsesquioxanes (POSS) linked ligand of the general formula (I) L[(R1a)n-1(SiO1,5)nR2a]k[(R1b)n-1SiO1,5)nR2b]l[(R1c)n-1SiO1,5)nR2c]m  (I) in which (R1a,b,c)n-1(SiO1,5)n is a polyhedral oligomeric silsesquioxanes (POSS) with n=4, 6, 8, 10, 12, 14, 16 or 18 and R1a, R1b, R1c is each independently selected from the group consisting of same or different branched or linear C1-C20 alkyl chains, cyclo alkyl, C1-C20 alkoxy, aryl, aryloxy, heteroaryl and arylalkyl groups, k, l, m is 0 or 1 provided that k+l+m≧1, R2a, R2b, R2c is a spacer that binds the polyhedral oligomeric silsesquioxane (POSS) to the ligand L and ligand L is an uncharged electron donor.

摘要翻译： 通式（I）L [（R1a）n-1（SiO1,5）nR2a] k [（R1b）n-1SiO1,5）nR2b] l [（R1c）n-1（SiO1））的多面体低聚倍半硅氧烷（POSS） 1SiO1,5）nR2c] m（I）其中（R1a，b，c）n-1（SiO1,5）n是具有n = 4,6,8,10,12,14的多面体低聚倍半硅氧烷（POSS） ，16或18，并且R 1a，R 1b，R 1c各自独立地选自相同或不同的支链或直链C 1 -C 20烷基链，环烷基，C 1 -C 20烷氧基，芳基，芳氧基，杂芳基和芳基烷基，k， l，m为0或1，条件是k + 1 +m≥1，R2a，R2b，R2c是将多面体低聚倍半硅氧烷（POSS）与配体L结合的间隔物，配体L是不带电子的电子给体。

公开(公告)号：US20130131284A1

公开(公告)日：2013-05-23

申请号：US13582010

申请日：2011-02-28

申请人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B.M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

发明人： Cengiz Azap ,  Dorit Wolf ,  Hendrikus Cornelis Louis Abbenhuis ,  Gijsbert Gerritsen ,  Karol Grela ,  Jos B.M. Wilting ,  Kinga Leszczynska ,  Justyna Czaban ,  Anna Wojtasiewicz

IPC分类号： C08G77/398 ,  C08G77/388 ,  C08G77/395

CPC分类号： C08G77/398 ,  C07F7/21 ,  C08G77/388 ,  C08G77/395

摘要： Polyhedral oligomeric silsesquioxanes (POSS) linked ligand of the general formula (I) L[(R1a)n-1(SiO1,5)nR2a]k[(R1b)n-1SiO1,5)nR2b]l[(R1c)n-1SiO1,5)nR2c]m  (I) in which (R1a,b,c)n-1(SiO1,5)n is a polyhedral oligomeric silsesquioxanes (POSS) with n=4, 6, 8, 10, 12, 14, 16 or 18 and R1a, R1b, R1c is each independently selected from the group consisting of same or different branched or linear C1-C20 alkyl chains, cyclo alkyl, C1-C20 alkoxy, aryl, aryloxy, heteroaryl and arylalkyl groups, k, l, m is 0 or 1 provided that k+l+m≧1, R2a, R2b, R2c is a spacer that binds the polyhedral oligomeric silsesquioxane (POSS) to the ligand L and ligand L is an uncharged electron donor.

摘要翻译： 通式（I）L [（R1a）n-1（SiO1,5）nR2a] k [（R1b）n-1SiO1,5）nR2b] l [（R1c）n-1（SiO1））的多面体低聚倍半硅氧烷（POSS）连接的配体 1SiO1,5）nR2c] m（I）其中（R1a，b，c）n-1（SiO1,5）n是具有n = 4,6,8,10,12,14的多面体低聚倍半硅氧烷（POSS） ，16或18，并且R 1a，R 1b，R 1c各自独立地选自相同或不同的支链或直链C 1 -C 20烷基链，环烷基，C 1 -C 20烷氧基，芳基，芳氧基，杂芳基和芳基烷基，k， l，m为0或1，条件是k + 1 + m> = 1，R2a，R2b，R2c是将多面体低聚倍半硅氧烷（POSS）与配体L结合的间隔基，配体L是不带电子的电子给体。