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公开(公告)号:US20150218196A1
公开(公告)日:2015-08-06
申请号:US14409604
申请日:2013-06-20
发明人: Adriaan Jacobus Minnaard , Manuel Jäger , Aditya Lakshmi Narasimha Raju Gottumukkala , Johannes Gerardus de Vries , Andreas Alexander Bastian , Andreas Herrmann
CPC分类号: C07H15/222 , C07H1/00 , C07H3/02 , C07H3/04 , C07H3/06 , C07H5/06 , C07H15/04 , C07H15/18 , C07H15/22 , C07H15/224 , C07H15/226 , C07H15/228 , C07H15/23 , C07H15/232 , C07H15/234 , C07H17/04 , C07H23/00
摘要: The invention relates to the field of carbohydrate chemistry. Provided is a process for the regioselective oxidation of a single secondary hydroxy function of a carbohydrate substrate comprising two or more secondary hydroxy functions, comprising contacting the carbohydrate substrate in a solvent in the presence of a transition metal catalyst complex with an oxidizing agent to yield a mono-oxidized carbohydrate.
摘要翻译: 本发明涉及碳水化合物化学领域。 提供了一种用于区域选择性氧化包含两个或更多个次级羟基官能团的碳水化合物底物的单次级羟基官能团的方法,包括在过渡金属催化剂配合物与氧化剂存在下使碳水化合物底物在溶剂中接触,得到 单氧化碳水化合物。
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公开(公告)号:US09751906B2
公开(公告)日:2017-09-05
申请号:US14409604
申请日:2013-06-20
发明人: Adriaan Jacobus Minnaard , Manuel Jäger , Aditya Lakshmi Narasimha Raju Gottumukkala , Johannes Gerardus de Vries , Andreas Alexander Bastian , Andreas Herrmann
IPC分类号: C07H15/222 , C07H15/226 , C07H15/224 , C07H15/22 , C07H15/232 , C07H15/228 , C07H15/234 , C07H15/23 , C07H1/00 , C07H3/04 , C07H3/06 , C07H15/04 , C07H15/18 , C07H23/00 , C07H3/02 , C07H5/06 , C07H17/04
CPC分类号: C07H15/222 , C07H1/00 , C07H3/02 , C07H3/04 , C07H3/06 , C07H5/06 , C07H15/04 , C07H15/18 , C07H15/22 , C07H15/224 , C07H15/226 , C07H15/228 , C07H15/23 , C07H15/232 , C07H15/234 , C07H17/04 , C07H23/00
摘要: The invention relates to the field of carbohydrate chemistry. Provided is a process for the regioselective oxidation of a single secondary hydroxy function of a carbohydrate substrate comprising two or more secondary hydroxy functions, comprising contacting the carbohydrate substrate in a solvent in the presence of a transition metal catalyst complex with an oxidizing agent to yield a mono-oxidized carbohydrate.
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