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公开(公告)号：US07855236B2
公开(公告)日：2010-12-21
申请号：US12096412
申请日：2006-12-06
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： Method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which process comprises the steps of: (i) providing the synthesis gas; and (ii) catalytically converting the synthesis gas at an elevated temperature and a steady state total reactor pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons; the method comprising admixing the synthesis gas of step (i) with one or more inert gases to form an admixture stream prior to catalytically converting the synthesis gas in step (ii) at the steady state total reactor pressure and wherein as the activity of the catalyst converting the synthesis gas proceeds towards a steady state, the amount of inert gas(es) in the admixture stream is reduced.
摘要翻译： 开始用于从合成气中产生通常为气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）提供合成气; 和（ii）在升高的温度和稳态的总反应器压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃; 该方法包括将步骤（i）的合成气与一种或多种惰性气体混合以在稳定状态的总反应器压力下催化转化步骤（ii）中的合成气之前形成混合物流，并且其中作为催化剂的活性 合成气转化为稳定状态，混合物流中的惰性气体的量减少。
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2.发明申请公开(公告)号：US20080275144A1
公开(公告)日：2008-11-06
申请号：US12096412
申请日：2006-12-06
IPC分类号： C07C1/04
CPC分类号： C10G2/32 , C10G2300/1022 , C10G2300/4081
摘要： Method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which process comprises the steps of: (i) providing the synthesis gas; and (ii) catalytically converting the synthesis gas at an elevated temperature and a steady state total reactor pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons; the method comprising admixing the synthesis gas of step (i) with one or more inert gases to form an admixture stream prior to catalytically converting the synthesis gas in step (ii) at the steady state total reactor pressure and wherein as the activity of the catalyst converting the synthesis gas proceeds towards a steady state, the amount of inert gas(es) in the admixture stream is reduced.
摘要翻译： 开始用于从合成气中产生通常为气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）提供合成气; 和（ii）在升高的温度和稳态的总反应器压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃; 该方法包括将步骤（i）的合成气与一种或多种惰性气体混合以在稳定状态的总反应器压力下催化转化步骤（ii）中的合成气之前形成混合物流，并且其中作为催化剂的活性 合成气转化为稳定状态，混合物流中的惰性气体的量减少。
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公开(公告)号：US20080275142A1
公开(公告)日：2008-11-06
申请号：US12096409
申请日：2006-12-06
申请人： Arend Hoek , Lip Piang Kueh
发明人： Arend Hoek , Lip Piang Kueh
IPC分类号： C07C1/02
CPC分类号： C10G2/32 , C10G2/332 , C10G2300/1022 , C10G2300/301
摘要： The present invention provides a method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which method comprises the steps of: (i) providing an activated catalyst in tubes of a fixed bed reactor, preferably a multitubular fixed bed reactor, the catalyst being suitable to convert synthesis gas to normally gaseous, normally liquid and optionally normally solid hydrocarbons; (ii) contacting the activated catalyst with a liquid to obtain a wetted activated catalyst; (iii) contacting the wetted activated catalyst with synthesis gas and catalytically converting the synthesis gas at an elevated temperature and pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons.
摘要翻译： 本发明提供了一种从合成气中开始生产常态气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）在固定床反应器的管中提供活化催化剂， 优选为多管式固定床反应器，该催化剂适用于将合成气转化为通常为气态，通常为液态和任选通常为固体烃; （ii）使活化的催化剂与液体接触以获得润湿的活化催化剂; （iii）使润湿的活化催化剂与合成气接触并在升高的温度和压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃。
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公开(公告)号：US20150034528A1
公开(公告)日：2015-02-05
申请号：US14354944
申请日：2012-10-31
申请人： Arlène Marcellina Pouw , Pascal Edzo Armin Rots , Antonius Adrianus Maria Roovers , Lip Piang Kueh , Jelle Sietsma , Iris Teo Jin Li
发明人： Arlène Marcellina Pouw , Pascal Edzo Armin Rots , Antonius Adrianus Maria Roovers , Lip Piang Kueh , Jelle Sietsma , Iris Teo Jin Li
CPC分类号： C09K5/063 , C07C9/14 , C07C9/22 , C10G2/00 , C10G2300/302 , C10G2300/308 , F28D20/02
摘要： The present invention provides a Fischer-Tropsch derived paraffin wax comprising paraffins having from 9 to 24 carbon atoms. In another aspect the present invention provides a thermal energy storage material comprising a Fischer-Tropsch derived paraffin wax comprising paraffins having from 9 to 24 carbon atoms, which Fischer-Tropsch derived paraffin wax has a melting point in the range of 15 to 40° C.
摘要翻译： 本发明提供了一种费 - 托衍生的石蜡，其包含具有9-24个碳原子的链烷烃。 另一方面，本发明提供一种热能储存材料，其包含费 - 托衍生的石蜡，其包含具有9-24个碳原子的链烷烃，该费托衍生的石蜡的熔点在15-40℃的范围内 。
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公开(公告)号：US07705060B2
公开(公告)日：2010-04-27
申请号：US12096409
申请日：2006-12-06
申请人： Arend Hoek , Lip Piang Kueh
发明人： Arend Hoek , Lip Piang Kueh
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , C10G2/332 , C10G2300/1022 , C10G2300/301
摘要： The present invention provides a method to start a steady state process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons from synthesis gas, which method comprises the steps of: (i) providing an activated catalyst in tubes of a fixed bed reactor, preferably a multitubular fixed bed reactor, the catalyst being suitable to convert synthesis gas to normally gaseous, normally liquid and optionally normally solid hydrocarbons; (ii) contacting the activated catalyst with a liquid to obtain a wetted activated catalyst; (iii) contacting the wetted activated catalyst with synthesis gas and catalytically converting the synthesis gas at an elevated temperature and pressure to obtain the normally gaseous, normally liquid and optionally normally solid hydrocarbons.
摘要翻译： 本发明提供了一种从合成气中开始生产常态气态，通常为液态和任选通常为固体烃的稳态过程的方法，该方法包括以下步骤：（i）在固定床反应器的管中提供活化催化剂， 优选为多管式固定床反应器，该催化剂适用于将合成气转化为通常为气态，通常为液态和任选通常为固体烃; （ii）使活化的催化剂与液体接触以获得润湿的活化催化剂; （iii）使润湿的活化催化剂与合成气接触并在升高的温度和压力下催化转化合成气以获得通常为气态的，通常为液体的和任选的通常为固体的烃。
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公开(公告)号：US07670476B2
公开(公告)日：2010-03-02
申请号：US11667912
申请日：2005-11-18
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： Process to optimize the yield of gas oils from a Fischer-Tropsch derived feed by performing the following steps: (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a gas oil fraction from the two reaction products obtained in steps (a) and (b).
摘要翻译： 通过执行以下步骤来优化来自费 - 托衍生的原料的瓦斯油的产率的方法：（a）对部分费 - 托衍生的进料进行加氢转化/加氢异构化步骤; （b）以大于步骤（a）中的转化率的转化率对费 - 托进料的另一部分进行加氢转化/加氢异构化步骤; 和（c）通过蒸馏分离来自步骤（a）和（b）中获得的两种反应产物的粗柴油馏分。
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公开(公告)号：US20070193923A1
公开(公告)日：2007-08-23
申请号：US10561477
申请日：2004-07-02
申请人： Jan Dierickx , Arend Hoek , Lip Piang Kueh
发明人： Jan Dierickx , Arend Hoek , Lip Piang Kueh
CPC分类号： C10G2/32 , C10G45/00 , C10G45/02 , C10G2400/10
摘要： A process to prepare a waxy Raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.
摘要翻译： 一种通过进行以下步骤制备蜡状提余液产物的方法：（a）使沸点高于540℃的化合物的重量比的费 - 托衍生产物和在370和540℃之间沸腾的化合物大于2 加氢转化步骤和（b）将步骤（a）的流出物分馏以获得在燃料范围内沸腾的产物和沸点在350和600℃之间的蜡状提余物产物。
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公开(公告)号：US07727378B2
公开(公告)日：2010-06-01
申请号：US10561477
申请日：2004-07-02
IPC分类号： C10G73/02
CPC分类号： C10G2/32 , C10G45/00 , C10G45/02 , C10G2400/10
摘要： A process to prepare a waxy raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.
摘要翻译： 一种通过进行以下步骤制备蜡状提余物产物的方法：（a）使沸点高于540℃的化合物的重量比和370至540℃之间的化合物的费 - 托衍生产物经受大于2 加氢转化步骤和（b）将步骤（a）的流出物分馏以获得在燃料范围内沸腾的产物和沸点在350和600℃之间的蜡状提余物产物。
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公开(公告)号：US07655134B2
公开(公告)日：2010-02-02
申请号：US11667911
申请日：2005-11-18
IPC分类号： C10G65/16
CPC分类号： C10G65/00 , C10G65/043 , C10G65/16
摘要： Process to optimize the yield of base oils from a Fischer-Tropsch derived feed by performing the following steps (a) performing a hydroconversion/hydroisomerization step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerization step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a fraction boiling in the base oil range from the two reaction products obtained in steps (a) and (b) and performing a pour point reducing step on said fraction.
摘要翻译： 通过执行以下步骤（a）对部分费 - 托衍生的进料进行加氢转化/加氢异构化步骤来优化来自费 - 托衍生的原料的基础油的产率的方法; （b）以大于步骤（a）中的转化率的转化率对费 - 托进料的另一部分进行加氢转化/加氢异构化步骤; 和（c）通过蒸馏分离在基础油中沸腾的馏分，其中步骤（a）和（b）中获得的两种反应产物和对所述级分进行倾点降低步骤。
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公开(公告)号：US20080314800A1
公开(公告)日：2008-12-25
申请号：US11667911
申请日：2005-11-18
IPC分类号： C10G35/04
CPC分类号： C10G65/00 , C10G65/043 , C10G65/16
摘要： Process to optimize the yield of base oils from a Fischer-Tropsch derived feed by performing the following steps (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydro-conversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a fraction boiling in the base oil range from the two reaction products obtained in steps (a) and (b) and performing a pour point reducing step on said fraction.
摘要翻译： 通过进行以下步骤（a）对部分费 - 托衍生的进料进行加氢转化/加氢异构化步骤来优化来自费 - 托衍生的原料的基础油的产率的方法; （b）以大于步骤（a）中的转化率的转化率对费 - 托进料的另一部分进行加氢转化/加氢异构化步骤; 和（c）通过蒸馏分离在基础油中沸腾的馏分，其中步骤（a）和（b）中获得的两种反应产物和对所述级分进行倾点降低步骤。
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