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    Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coating containing the same
    1.
    发明授权
    Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coating containing the same 有权
    一元多氟氧杂环丁烷低聚物，聚合物和共聚物以及含有它们的涂层

    公开(公告)号：US06927276B2

    公开(公告)日：2005-08-09

    申请号：US10316412

    申请日：2002-12-11

    申请人： Robert Medsker ,  Gary L. Jialanella ,  Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson

    发明人： Robert Medsker ,  Gary L. Jialanella ,  Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson

    IPC分类号： C08G18/50 ,  C08G18/67 ,  C08G65/22 ,  C09D175/16

    CPC分类号： C09D175/16 ,  C08G18/5015 ,  C08G18/672 ,  C08G65/226 ,  C08G18/50

    摘要： Monofunctional polyfluorooxetane oligomers, polymers, and copolymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.

    摘要翻译： 单官能聚氟乙烯低聚物，聚合物和共聚物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 除了作为引发剂外，一元醇还可以用作氟氧杂环丁烷或其它单体的溶剂，以制备具有低循环含量的低聚物，聚合物或共聚物。 合适的共聚单体通常包括各种环醚。 具有单个羟基端基的多氟全息聚氧乙烯低聚物，聚合物或共聚物可以用各种化合物进行官能化，以产生官能化的端基如丙烯酸酯，甲基丙烯酸酯，烯丙基，胺等，其官能化 低聚物或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化以提供润湿和表面性能的改进。

    Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coatings containing the same
    2.
    发明授权
    Monohydric polyfluorooxetane oligomers, polymers, and copolymers and coatings containing the same 有权
    一元多氟氧杂环丁烷低聚物，聚合物，共聚物和含有它们的涂料

    公开(公告)号：US06962966B2

    公开(公告)日：2005-11-08

    申请号：US09727637

    申请日：2000-12-01

    申请人： Robert Medsker ,  Gary L. Jialanella ,  Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson

    发明人： Robert Medsker ,  Gary L. Jialanella ,  Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson

    IPC分类号： C08G18/50 ,  C08G18/67 ,  C08G65/22 ,  C09D175/16

    CPC分类号： C09D175/16 ,  C08G18/5015 ,  C08G18/672 ,  C08G65/226 ,  C08G18/50

    摘要： Monofunctional polyfluorooxetane oligomers, polymers, and co-polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. In addition to serving as an initiator, the monoalcohol can also serve as a solvent for the fluorooxetane or other monomers to produce oligomers, polymers, or copolymers having low cyclic content. Suitable comonomers generally include various cyclic ethers. The polyfluorooxetane oligomer, polymer, or copolymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties.

    摘要翻译： 通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备单官能聚氟乙烯低聚物，聚合物和共聚物。 除了作为引发剂外，一元醇还可以用作氟氧杂环丁烷或其它单体的溶剂，以制备具有低循环含量的低聚物，聚合物或共聚物。 合适的共聚单体通常包括各种环醚。 具有单个羟基端基的多氟全息聚氧乙烯低聚物，聚合物或共聚物可以用各种化合物进行官能化，以产生官能化的端基如丙烯酸酯，甲基丙烯酸酯，烯丙基，胺等，其官能化 低聚物或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化以提供润湿和表面性能的改进。

    Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer
    3.
    发明授权
    Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer 有权
    一元多氟氧杂环丁烷聚合物和含有单官能多氟氧杂环丁烷聚合物的可辐射固化涂层

    公开(公告)号：US06727344B2

    公开(公告)日：2004-04-27

    申请号：US10108318

    申请日：2002-03-28

    申请人： Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson ,  Robert E. Medsker

    发明人： Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson ,  Robert E. Medsker

    IPC分类号： C08G6522

    CPC分类号： C09D175/16 ,  C08G18/5015 ,  C08G18/672 ,  C08G65/226 ,  Y10T428/31794 ,  C08G18/50

    摘要： Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.

    摘要翻译： 单官能聚氟乙烯低聚物和聚合物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 氟氧杂环丁烷低聚物或聚合物可以与通常的环醚共聚。 或者，具有单个羟基端基的多氟氧杂环丁烷低聚物或聚合物可以用各种化合物进行官能化，以产生官能化低聚物如丙烯酸酯，甲基丙烯酸酯，烯丙基胺，胺等官能端基 或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化，以提供以前由迁移的化学品如蜡和油提供的润湿和表面性能的改进。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。

    Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer
    4.
    发明授权
    Monohydric polyfluorooxetane polymer and radiation curable coatings containing a monofunctional polyfluorooxetane polymer 失效
    一元多氟氧杂环丁烷聚合物和含有单官能多氟氧杂环丁烷聚合物的可辐射固化涂层

    公开(公告)号：US06972317B2

    公开(公告)日：2005-12-06

    申请号：US10108916

    申请日：2002-03-28

    申请人： Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson ,  Robert E. Medsker

    发明人： Raymond J. Weinert ,  Guillermina C. Garcia ,  Aslam Malik ,  Roland Carlson ,  Robert E. Medsker

    IPC分类号： C08G18/50 ,  C08G18/67 ,  C08G65/22 ,  C09D175/16

    CPC分类号： C09D175/16 ,  C08G18/5015 ,  C08G18/672 ,  C08G65/226 ,  Y10T428/31794 ,  C08G18/50

    摘要： Monofunctional polyfluorooxetane oligomers and polymers are prepared by the cationic polymerization of fluorooxetane monomers with a monoalcohol. The fluorooxetane oligomers or polymers can be copolymerized with generally cyclic ethers. Alternatively, the polyfluorooxetane oligomer or polymer having a single hydroxyl end group can be functionalized with a variety of compounds so as to yield a functional end group such as an acrylate, a methacrylate, an allylic, an amine, etc., with the functionalized oligomer or polymer being suitable for use in radiation curable or thermal curable coating compositions. These functionalized polymers can be copolymerized and cured to provide improvements in wetting and surface properties that have previously been provided by migratory chemicals such as waxes and oils. The partially or fully fluorinated side groups of the fluorooxetanes are believed to be disproportionately present at the interfaces between the coating and the substrate and between the coating and the atmosphere.

    摘要翻译： 单官能聚氟乙烯低聚物和聚合物是通过氟代氧杂环丁烷单体与一元醇的阳离子聚合制备的。 氟氧杂环丁烷低聚物或聚合物可以与通常的环醚共聚。 或者，具有单个羟基端基的多氟氧杂环丁烷低聚物或聚合物可以用各种化合物进行官能化，以产生官能化低聚物等丙烯酸酯，甲基丙烯酸酯，烯丙基胺，胺等功能性端基 或聚合物适用于可辐射固化或热固化涂料组合物。 这些官能化聚合物可以共聚和固化，以提供以前由迁移的化学品如蜡和油提供的润湿和表面性能的改进。 认为氟氧杂环丁烷的部分或完全氟化的侧基不成比例地存在于涂层和基底之间以及涂层和大气之间的界面处。