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    Imaging medium
    8.
    发明授权
    Imaging medium 失效
    成像介质

    公开(公告)号：US5453345A

    公开(公告)日：1995-09-26

    申请号：US141852

    申请日：1993-10-22

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    IPC分类号： B41M5/30 ,  B41M5/333 ,  C07C49/593 ,  G03C1/675 ,  G03C1/73 ,  G03F7/004 ,  G03C1/492 ,  G03C1/494 ,  G03C1/76

    CPC分类号： C07C49/593 ,  B41M5/30 ,  G03C1/73 ,  G03F7/0045 ,  Y10S430/145 ,  Y10S430/146

    摘要： Acid can be generated by exposing a mixture of a superacid precursor and a dye to actinic radiation of a first wavelength which does not, in the absence of the dye, cause decomposition of the superacid precursor to form the corresponding superacid, thereby causing absorption of the actinic radiation and decomposition of part of the superacid precursor, with formation of a protonated product derived from the dye, then irradiating the mixture with actinic radiation of a second wavelength, thereby causing decomposition of part of the remaining superacid precursor, with formation of unbuffered superacid. Preferably, following these irradiations, the imaging medium is heated while the superacid is admixed with a secondary acid generator capable of being thermally decomposed to form a second acid, the thermal decomposition of the secondary acid generator being catalyzed by the presence of the superacid. The acid generation process may be used for imaging by bringing the superacid or second acid into contact with an acid-sensitive material which changes color on contact with acid, or the superacid may be used to trigger polymerization, depolymerization or other reactions.

    摘要翻译： 可以通过将超强酸前体和染料的混合物暴露于第一波长的光化辐射而产生酸，在第一波长的光化辐射下，在不存在染料的情况下，超级酸性前体不会分解形成相应的超强酸，从而引起吸收 光化辐射和部分超酸前体的分解，形成衍生自染料的质子化产物，然后用第二波长的光化辐射照射混合物，从而导致部分剩余的超酸前体分解，形成无缓冲的超酸 。 优选地，在这些照射之后，加热成像介质，同时将超强酸与能够热分解形成第二酸的次级酸发生剂混合，二次酸产生剂的热分解由超强酸的存在催化。 酸生成方法可以通过使超酸或第二酸与酸接触改变颜色的酸敏感材料接触而使用，或者超酸可用于引发聚合，解聚或其它反应。

    Process for generation of unbuffered super-acid and for imaging
    9.
    发明授权
    Process for generation of unbuffered super-acid and for imaging 失效
    产生无缓冲超酸和成像的方法

    公开(公告)号：US5578424A

    公开(公告)日：1996-11-26

    申请号：US376037

    申请日：1995-01-20

    申请人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    发明人： Jurgen M. Grasshoff ,  John L. Marshall ,  Richard A. Minns ,  Anthony J. Puttick ,  Lloyd D. Taylor ,  Stephen J. Telfer

    IPC分类号： B41M5/30 ,  B41M5/333 ,  C07C49/593 ,  G03C1/675 ,  G03C1/73 ,  G03F7/004 ,  G03C1/725 ,  G03C1/735 ,  G03C5/00

    CPC分类号： C07C49/593 ,  B41M5/30 ,  G03C1/73 ,  G03F7/0045 ,  Y10S430/145 ,  Y10S430/146

    摘要： Acid can be generated by exposing a mixture of a superacid precursor and a dye to actinic radiation of a first wavelength which does not, in the absence of the dye, cause decomposition of the superacid precursor to form the corresponding superacid, thereby causing absorption of the actinic radiation and decomposition of part of the superacid precursor, with formation of a protonated product derived from the dye, then irradiating the mixture with actinic radiation of a second wavelength, thereby causing decomposition of part of the remaining superacid precursor, with formation of unbuffered superacid. Preferably, following these irradiations, the imaging medium is heated while the superacid is admixed with a secondary acid generator capable of being thermally decomposed to form a second acid, the thermal decomposition of the secondary acid generator being catalyzed by the presence of the superacid. The acid generation process may be used for imaging by bringing the superacid or second acid into contact with an acid-sensitive material which changes color on contact with acid, or the superacid may be used to trigger polymerization, depolymerization or other reactions.

    摘要翻译： 可以通过将超强酸前体和染料的混合物暴露于第一波长的光化辐射而产生酸，在第一波长的光化辐射下，在不存在染料的情况下，超级酸性前体不会分解形成相应的超强酸，从而引起吸收 光化辐射和部分超酸前体的分解，形成衍生自染料的质子化产物，然后用第二波长的光化辐射照射混合物，从而导致部分剩余的超酸前体分解，形成无缓冲的超酸 。 优选地，在这些照射之后，加热成像介质，同时将超强酸与能够热分解形成第二酸的次级酸发生剂混合，二次酸产生剂的热分解由超强酸的存在催化。 酸生成方法可以通过使超酸或第二酸与酸接触改变颜色的酸敏感材料接触而使用，或者超酸可用于引发聚合，解聚或其它反应。

    Process for generation of squaric acid and for imaging, and imaging medium for use therein
    10.
    发明授权
    Process for generation of squaric acid and for imaging, and imaging medium for use therein 失效
    用于生成方酸和成像的方法，以及用于其中的成像介质

    公开(公告)号：US5334489A

    公开(公告)日：1994-08-02

    申请号：US965162

    申请日：1992-10-23

    申请人： Jurgen M. Grasshoff ,  Mark R. Mischke ,  Stephen J. Telfer

    发明人： Jurgen M. Grasshoff ,  Mark R. Mischke ,  Stephen J. Telfer

    IPC分类号： B41M5/30 ,  B41M5/333 ,  C07C49/593 ,  G03C1/675 ,  G03C1/73 ,  G03F7/004 ,  G03C1/725 ,  G03C1/735 ,  G03C5/00

    CPC分类号： B41M5/30 ,  C07C49/593 ,  G03C1/73 ,  G03F7/0045

    摘要： Acid can be generated by exposing a superacid precursor to actinic radiation effective to generate superacid from the superacid precursor and heating the superacid in admixture with a squaric acid derivative in which there is bonded to the squaric acid ring, via an oxygen atom, an alkyl or alkylene group, a partially hydrogenated aryl or arylene group, or an aralkyl group. The superacid catalyzes decomposition of the squaric acid derivative, thus increasing the quantity of strong acid present in the medium. The resultant acid can be used to effect a color change in an acid-sensitive material, so providing an imaging process.

    摘要翻译： 可以通过将超强酸前体暴露于有效从超酸前体产生超强酸的光化辐射中，并且通过氧原子，烷基或烷基取代与方酸酸衍生物混合的方酸加热超酸，产生酸 亚烷基，部分氢化的芳基或亚芳基或芳烷基。 超酸催化方酸衍生物的分解，从而增加介质中存在的强酸的量。 所得酸可用于在酸敏感材料中进行颜色变化，从而提供成像过程。