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公开(公告)号：US4760203A
公开(公告)日：1988-07-26
申请号：US86431
申请日：1987-08-18
CPC分类号： C07C29/04
摘要： A direct hydration process for the production of isopropyl alcohol by reacting a propene-containing hydrocarbon stream with an aqueous stream in an interconnected series of reactors in the presence of an acidic cation exchange resin catalyst wherein the improvement comprises charging a propene-containing hydrocarbon stream to one end of a series of interconnected reactors and charging an aqueous stream to the opposite end of a series of interconnected reactors and directing the streams through the series of reactors so that the hydrocarbon stream and the aqueous stream flow in opposite directions with respect to the series of interconnected reactors and flow in parallel streams through each individual reactor is provided.
摘要翻译： 在酸性阳离子交换树脂催化剂存在下，通过在相互连接的反应器系列中使含丙烯的烃物流与含水物流反应，生产异丙醇的直接水合方法，其中改进之处在于将含丙烯的烃物流 一系列相互连接的反应器的一端，并将水流装入一系列相互连通的反应器的相对端，并引导物流通过该系列反应器，使得烃流和水流相对于该系列的相反方向流动 的互连反应器并且通过每个单独的反应器以平行流流动。
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公开(公告)号：US4760202A
公开(公告)日：1988-07-26
申请号：US86429
申请日：1987-08-18
IPC分类号： C07B61/00 , B01J31/00 , C07C27/00 , C07C29/04 , C07C31/10 , C07C31/12 , C07C31/125 , C07C67/00
CPC分类号： C07C29/04
摘要： Tertiary alcohols with 4 or 5 carbon atoms are produced by reacting an isoolefin-containing hydrocarbon stream with water in the presence of a strongly acidic, solid hydration catalyst in such a way that each of the two process streams, the hydrocarbon stream and the process water, is cascaded through several reactors connected in series such that one process stream is fed to one end of the line of reactors and the other process stream to the other end of the line of reactors, and the two process streams pass through the line of reactors in opposite directions, while they pass through the individual reactors as parallel currents.
摘要翻译： 具有4或5个碳原子的叔醇通过在强酸性固体水合催化剂存在下使含异烯烃的烃流与水反应，使得两种工艺流，烃流和工艺水中的每一种 ，通过串联连接的几个反应器级联，使得一个工艺流被供给到反应器管线的一端，另一个工艺流进入反应器管线的另一端，并且两个工艺流通过反应器管线 在相反的方向，当它们作为并联电流通过各个反应器时。
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3.发明授权Process for the continuous separation of water from methyl tert-butyl ether mixtures 失效从甲基叔丁基醚混合物中连续分离水的方法
公开(公告)号：US4943354A
公开(公告)日：1990-07-24
申请号：US326493
申请日：1989-03-17
申请人： Gunther Osterburg , Milan Prezelj
发明人： Gunther Osterburg , Milan Prezelj
IPC分类号： C07B63/00 , B01D3/34 , B01D3/36 , C07B31/00 , C07C27/00 , C07C29/80 , C07C31/12 , C07C41/00 , C07C41/42 , C07C43/04 , C07C45/00 , C07C45/82 , C07C45/84 , C07C49/10 , C07C67/00
CPC分类号： B01D3/34 , C07C29/80 , C07C41/42 , C07C45/002 , C07C45/84 , Y10S203/20
摘要： An energy saving process for purification of methyl tertbutyl ether by fractional distillation of a mixture containing dissolved water and C.sub.4 hydrocarbons characterized by phase separation of water and methyl tertiary butyl ether within the distillation column and withdrawal of the separated water phase from the column at a point below the point at which the mixture is supplied to the column.
摘要翻译： 用于通过分馏含有溶解水和C4烃的混合物来纯化甲基叔丁醚的节能过程，其特征在于在蒸馏塔内相分离水和甲基叔丁基醚，并在一点处将分离的水相从塔中取出 低于混合物供应到塔的点。
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4.发明授权
公开(公告)号：US4544776A
公开(公告)日：1985-10-01
申请号：US451707
申请日：1982-12-20
申请人： Gunther Osterburg , Milan Prezelj
发明人： Gunther Osterburg , Milan Prezelj
IPC分类号： C07C41/05 , C07C27/00 , C07C29/76 , C07C29/80 , C07C29/86 , C07C31/04 , C07C31/12 , C07C41/00 , C07C41/06 , C07C41/34 , C07C43/04 , C07C67/00 , C07C41/38 , C07C41/42
CPC分类号： C07C29/80 , C07C29/86 , C07C31/04 , C07C41/06 , C07C41/38 , Y10S203/06 , Y10S203/20
摘要： The reaction product from etherification of C.sub.4 -C.sub.7 isoolefins with methanol in the presence of an acidic catalyst is washed with water in the presence of inert hydrocarbons thereby removing methanol and a part of the tertiary alcohol. The aqueous extract solution bottoms is distilled to separate methanol as overhead. Tertiary alcohols are withdrawn as a side stream from a tray of the distillation column with a high concentration thereof and fed into the washing column.
摘要翻译： 在酸性催化剂存在下，C4-C7异烯烃与甲醇的醚化反应产物在惰性烃存在下用水洗涤，从而除去甲醇和一部分叔醇。 蒸馏水提取物溶液底部以分离甲醇作为塔顶馏出物。 三级醇作为侧流从蒸馏塔的塔盘中以高浓度排出，并进料到洗涤塔中。
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5.发明授权Process for separating the reaction products obtained from etherifying lower isoolefins with methanol 失效用甲醇分离由醚化的低级异烯烃获得的反应产物的方法
公开(公告)号：US4334964A
公开(公告)日：1982-06-15
申请号：US273171
申请日：1981-06-12
申请人： Milan Prezelj , Gunter Osterburg , Joachim E. Putz
发明人： Milan Prezelj , Gunter Osterburg , Joachim E. Putz
CPC分类号： C07C41/42 , C07C41/06 , Y10S203/20
摘要： A method for separating a mixture of reaction products produced in the catalytic etherification of a lower isoolefin with methanol wherein said reaction product comprises a mixture of ether, methanol, unreacted hydrocarbon and tertiary alcohol which comprises adding water to said reaction product to form a hydrocarbon phase containing said ether and an aqueous phase containing methanol and a tertiary alcohol, separating said hydrocarbon phase to recover a methyltertiary alkyl ether, introducing said alcohol-containing aqueous phase into a distillation column to separate a methanol fraction overhead, withdrawing a side stream rich in tertiary alcohol from said distillation column, stripping this side stream in a stripping column to separate a second methanol fraction overhead and a tertiary alcohol bottoms fraction and recycling the methanol overhead fraction from the stripping column to the upper part of the distillation column and recycling the overhead methanol fraction from the distillation column to the feed stream to said reactor.
摘要翻译： 一种用于分离在低级异烯烃与甲醇的催化醚化反应产生的反应产物的混合物的方法，其中所述反应产物包括醚，甲醇，未反应的烃和叔醇的混合物，其包括向所述反应产物中加入水以形成烃相 含有所述醚和含有甲醇和叔醇的水相，分离所述烃相以回收甲基叔烷基醚，将所述含醇水相引入蒸馏塔中以分离塔顶甲醇馏分，取出富含叔碳酸酯的侧流 从汽提塔中汽提该侧流，分离第二甲醇馏分和叔醇塔底馏分，并将甲醇塔顶馏分从汽提塔循环到蒸馏塔的上部，再循环塔顶甲醇 来自dist的分数 向所述反应器的进料流输送。
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