摘要:
A pulsed NMR analysis system and process comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which components functions are determined using non-linear regression techniques to correlate the curve components to the target nuclei.
摘要:
Pulsed NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay (FID) curves (C), from which fast Gaussian, slower modified Gaussian and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the FID curve components to the physical quantities of the target nuclei.
摘要:
A pulsed NMR analysis system and process comprising an air curtain (137), sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C) , from which components functions are determined using linear or nonlinear regression techniques to correlate the curve components to the target nuclei and to flow rates in plastic including MI and FRR for polyethylene and MF for polypropylene.
摘要:
A pulsed nmr analysis system for polymers materials extracted from industrial processes at a mobility enhancing temperature (at or above glass transition temperature for amorphous polymers, at the crystalline transition temperature for crystalline and semi-crystalline polymers). The sample is measured via nmr techniques and results correlated to viscosity and melt index or melt flow (which are related to average molecular weights). The nmr system (in or out of resonance) includes: sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which components functions are determined using linear or non-linear regression techniques to correlate the curve components to the target nuclei and to flow rates in plastics. Substantial improvement of correlation of nmr derived constants and equations of a free induction decay curve with the foregoing polymer properties is obtained via (1) conducting the nmr process at a mobility enhancing temperature (normally elevated compared to the industrial process temperature of the industrial process) and (2) holding temperature substantially constant at such elevated temperature.
摘要:
Pulsed NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay (FID) curves (C), from which fast Gaussian, slower modified Gaussian or preferably slower Gaussian, and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the FID curve components to the physical quantities of the target nuclei.
摘要:
Pulsed NMR system for industrial purposes comprising sample throughput system (P, LI, V1, V2) magnetic field adjustment (120, 124) and thermal adjustment (134-138 and 142-146). The resonance is established by a coil (100), excited by a transceiver (104) and interacting with the sample and the magnetic field at resonance to establish received and digitized free induction decay curve forms (C) which are automatically analyzed into Gaussian and exponential components--providing simplified high speed computation means with repetitive test sequence and thermal controls that systematically minimize errors to assure reliable determination of target nuclei quantities in successive samples from an industrial process and utilizing Hahn spin echo based equipment to automatically adjust the analysis of one or more of the analyzed components.
摘要:
Pulsed NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which Abragam, Gaussian, and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the curve components to the target nuclei.
摘要:
Pulsed NMR system for industrial measurements comprising sample throughout system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which Abragam, Gaussianand exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the curve components to the target nuclei.
摘要:
Magnestic resonance system for industrial purposes comprising sample throughput system (P, LI, V1, V2) magnetic field adjustment (120, 124) and thermal adjustment (134-138 and 142-146). The resonance is established by a coil (100), excited by a transceiver (104) and interacting with the sample and the magnetic field at resonance to establish received and digitized free induction decay curve forms (C) which are synthesized into bound (Gaussian) and unbound (exponential) components--pairing simplified high speed computation means with repetitive test sequence and thermal controls that systematically minimize errors to assure reliable determination of target nuclei quantities in successive samples from an industrial process.
摘要:
Particle analysis apparatus (10) in combination with a triboelectric probe (P) and including means (18, 20, 22, 24, 26) to analyze individual particle collisions with the probe as a useful measure of flow conditions--of a fluid with suspended solid particles--in the region of the probe.