High ion exchange capacity polyelectrolytes having high crosslink
densities and caustic stability
    1.
    发明授权
    High ion exchange capacity polyelectrolytes having high crosslink densities and caustic stability 失效
    具有高交联密度和苛性碱稳定性的高离子交换容量聚电解质

    公开(公告)号:US5284879A

    公开(公告)日:1994-02-08

    申请号:US857910

    申请日:1992-03-26

    IPC分类号: B01J41/14 C08F12/34 C08J5/22

    摘要: A water or alcohol-water soluble divinyl monomer having anion exchange group(s) and a free exchangable anion is disclosed. These bifunctional divinyl monomers are capable of forming ion exchange materials (membranes and ion exchange resin beads) upon polymerization with added vinyl catalysts which convert them into insoluble and infusible polymers. They are also capable of being co-polymerized with other ion exchange (ion containing) monomers to give unique anion exchange resins or membranes.

    摘要翻译: 公开了具有阴离子交换基团和自由交换阴离子的水或醇 - 水溶性二乙烯基单体。 这些双功能二乙烯基单体在加入乙烯基催化剂聚合时能够形成离子交换材料(膜和离子交换树脂珠),将其转化为不溶性和不可渗透的聚合物。 它们还能够与其他离子交换(含离子)单体共聚以提供独特的阴离子交换树脂或膜。

    High ion exchange capacity polyelectrolytes having high crosslink
densities and caustic stability
    4.
    发明授权
    High ion exchange capacity polyelectrolytes having high crosslink densities and caustic stability 失效
    具有高交联密度和苛性碱稳定性的高离子交换容量聚电解质

    公开(公告)号:US5118717A

    公开(公告)日:1992-06-02

    申请号:US479491

    申请日:1990-02-13

    IPC分类号: B01J41/14 C08F12/34 C08J5/22

    摘要: A water or alcohol-water soluble divinyl monomer having anion exchange group(s) and a free exchangeable anion is disclosed. These bifunctional divinyl monomers are capable of forming ion exchange materials (membranes and ion exchange resin beads) upon polymerization with added vinyl catalysts which convert them into insoluble and infusible polymers. They are also capable of being co-polymerized with other ion exchange (ion containing) monomers to give unique anion exchange resins or membranes.

    摘要翻译: 公开了具有阴离子交换基团和自由交换阴离子的水或醇 - 水溶性二乙烯基单体。 这些双功能二乙烯基单体在加入乙烯基催化剂聚合时能够形成离子交换材料(膜和离子交换树脂珠),将其转化为不溶性和不可渗透的聚合物。 它们还能够与其他离子交换(含离子)单体共聚以提供独特的阴离子交换树脂或膜。

    Novel bipolar membranes and process of manufacture
    5.
    发明授权
    Novel bipolar membranes and process of manufacture 失效
    新型双极膜及其制造工艺

    公开(公告)号:US4851100A

    公开(公告)日:1989-07-25

    申请号:US189263

    申请日:1988-05-02

    IPC分类号: C08J5/22

    摘要: Improved bipolar membranes comprised of two laminates, one a long term base stable thermoset anion exchange membrane and the other a strongly solvent bonded (solvent cast) thermoplastic water insoluble cation exchange membrane. The membranes have a useful level of acid and base efficiencies at low water splitting voltages, along with high current densities.

    摘要翻译: 改进的双极膜由两个层压板组成,一个是长期碱稳定的热固性阴离子交换膜,另一个是强溶剂粘合(溶剂浇铸)热塑性水不溶性阳离子交换膜。 膜在低水分离电压以及高电流密度下具有有用的酸和碱效率水平。

    Electrodialysis membranes of high interstitial molality based upon
methacrylate ester derivatives
    6.
    发明授权
    Electrodialysis membranes of high interstitial molality based upon methacrylate ester derivatives 失效
    基于甲基丙烯酸酯衍生物的高间质摩尔浓度的电渗析膜

    公开(公告)号:US4231855A

    公开(公告)日:1980-11-04

    申请号:US16994

    申请日:1979-03-02

    IPC分类号: B01D69/02 C08J5/22 B01D13/02

    摘要: This invention relates to cross-linked copolymers of methacrylate esters containing ionogenic functional groups capable of being converted into high efficiency electro-dialysis membranes. Such totally aliphatic polymer membranes have been found to give electrical resistances which can be as low as one half that of membranes previously synthesized as well as higher interstitial molality. This reduced resistance, in concert with a high degree of chemical and physical stability enables water desalination by electrodialysis to be performed over longer periods of useful membrane life and at a lower expenditure of electrical energy per thousand gallons of water desalted.

    摘要翻译: 本发明涉及能够转化成高效电渗析膜的含有离子发生官能团的甲基丙烯酸酯的交联共聚物。 已经发现这样的全脂族聚合物膜具有可以低达先前合成的膜的一半以及较高间隙的摩尔数的电阻。 这种降低的电阻,与高度的化学和物理稳定性协调一致,可以通过电渗析在较长时间的有用膜寿命中进行水脱盐,并且以每千加仑的水脱盐的电能消耗较少。