公开(公告)号：US10428280B2

公开(公告)日：2019-10-01

申请号：US15321287

申请日：2014-06-26

申请人： S-OIL CORPORATION ,  KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Chan-Ju Song ,  Sang Cheol Paik ,  Sang-Goo Lee ,  Min Kee Choi ,  Myoung Yeob Kim

IPC分类号： B01J29/85 ,  C10G45/64 ,  B01J29/04 ,  B01J35/10 ,  B01J37/04 ,  C01B39/54 ,  B01J37/08 ,  C10G45/60 ,  C10G45/62 ,  B01J37/10 ,  B01J29/064 ,  B01J29/076 ,  B01J37/02

摘要： The present disclosure relates to a method for preparing a multi-level pore zeolite, including: (A) a step of mixing a silicon precursor, an aluminum precursor, a phosphorus precursor, a structure directing agent and water; a step of (B) adding phenylphosphonic acid, carbon black or a mixture thereof to the mixture prepared in the step (A) and mixing the same; a step of (C) crystallizing the mixture prepared in the step (B) by heat-treating the same; and a step of (D) calcining the crystallization product, and utilization of the prepared multi-level pore zeolite as a catalyst for hydroisomerization of normal paraffins. The catalyst exhibits improved isoparaffin yield when it is used as a catalyst for hydroisomerization of normal paraffins such as diesel or lube base oil by supporting an active metal component because residence time of reactants and products in the zeolite crystals are decreased due to mesopores and the proportion of external acid sites to total acid sites is low. Also, cloud point and pour point are effectively improved and high hydroisomerization reactivity is achieved without product loss.