摘要:
Negative active materials and rechargeable lithium batteries including the negative active materials are provided. The negative active material includes an intermetallic compound of Si and a metal, and a metal matrix including Cu and Al. The negative active material may provide a rechargeable lithium battery having high capacity and excellent cycle-life and cell efficiency.
摘要:
The negative electrode for a rechargeable lithium battery includes a current collector and a negative active material layer disposed on the current collector. The negative active material layer includes a metal-based negative active material and sheet-shaped graphite and has porosity of 20 to 80 volume %. The negative electrode for a rechargeable lithium battery can improve cell characteristics by inhibiting volume change and stress due to active material particle bombardment during charge and discharge, and by decreasing electrode resistance.
摘要:
Negative active materials for rechargeable lithium batteries are provided. One negative active material includes at least one Si active particle and a metal matrix surrounding the Si active particle. The metal matrix does not react with the Si active particle. The negative active material has a martensite phase when X-ray diffraction intensity is measured using a CuKα ray. The negative active material has improved efficiency and cycle-life.
摘要:
A negative electrode for rechargeable lithium batteries includes a current collector, a porous active material layer having a metal-based active material disposed on the current collector, and a high-strength binder layer on the porous active material layer. The high-strength binder layer has a strength ranging from 5 to 70 MPa. The negative active material for a rechargeable lithium battery according to the present invention can improve cycle-life characteristics by suppressing volume expansion and reactions of an electrolyte at the electrode surface.
摘要:
The negative electrode for a rechargeable lithium battery includes a current collector and a negative active material layer disposed on the current collector. The negative active material layer includes a metal-based negative active material and sheet-shaped graphite and has porosity of 20 to 80 volume %. The negative electrode for a rechargeable lithium battery can improve cell characteristics by inhibiting volume change and stress due to active material particle bombardment during charge and discharge, and by decreasing electrode resistance.
摘要:
A negative electrode for rechargeable lithium batteries includes a current collector, a porous active material layer having a metal-based active material disposed on the current collector, and a high-strength binder layer on the porous active material layer. The high-strength binder layer has a strength ranging from 5 to 70 MPa. The negative active material for a rechargeable lithium battery according to the present invention can improve cycle-life characteristics by suppressing volume expansion and reactions of an electrolyte at the electrode surface.
摘要:
Negative active materials and rechargeable lithium batteries including the negative active materials are provided. The negative active material includes an intermetallic compound of Si and a metal, and a metal matrix including Cu and Al. The negative active material may provide a rechargeable lithium battery having high capacity and excellent cycle-life and cell efficiency.
摘要:
Negative active materials for rechargeable lithium batteries are provided. One negative active material includes a metal matrix, and an intermetallic compound including a Si active metal and an additive metal dispersed in the metal matrix. The additive metal may be Ca, Mg, Na, K, Sr, Rb, Ba, Cs, or a combination thereof. The metal matrix may comprise Cu and Al. The negative active material may comprise a X(aM-bSi)—Y(cCu-dAl) material, where X is from about 30 to about 70 wt %, Y is from about 30 to about 70 wt %, X+Y is 100 wt %, a+b is 100 wt %, a is from about 20 to 80 wt %, b is from about 20 to 80 wt %, c+d is 100 wt %, c is from about 80 to about 95 wt %, d is from about 5 to about 20 wt %, and M may be Ca, Mg, Na, K, Sr, Rb, Ba, Cs, or a combination thereof.
摘要:
Negative active materials for rechargeable lithium batteries are provided. One negative active material includes a metal matrix, and an intermetallic compound including a Si active metal and an additive metal dispersed in the metal matrix. The intermetallic compound does not react with the metal matrix.
摘要:
An negative active material for a rechargeable lithium battery includes a nano-composite including a Si phase, a SiO2 phase, and a metal oxide phase of formulation MyO, where M is a metal with an oxidation number x, a free energy of oxygen-bond formation ranging from −900 kJ/mol to −2000 kJ/mol, x, and x·y=2. The negative active material for a rechargeable lithium battery according to the present invention can improve initial capacity, initial efficiency, and cycle-life characteristics by suppressing its initial irreversible reaction.