公开(公告)号：US20150139896A1

公开(公告)日：2015-05-21

申请号：US14396622

申请日：2013-04-19

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Mohamed Sabri Abdelghani ,  Mustapha Karime ,  Zeeshan Nawaz ,  Abdullah Mohammad Al-Qahtani

IPC: C07C5/48 ,  C01B3/38 ,  C07C5/333

CPC classification number: C07C5/48 ,  C01B3/386 ,  C01B2203/0261 ,  C01B2203/0277 ,  C01B2203/0855 ,  C01B2203/107 ,  C01B2203/1088 ,  C07C5/3337 ,  C07C2529/068 ,  C10G35/04

Abstract: A solar energy based continuous process and reactor system for the production of an alkene by dehydrogenation of the corresponding alkane is performed in a reactor which process comprises alternatingly performing a first mode and a second mode in the same reactor, wherein the first mode is a non-oxidative dehydrogenation wherein the non-oxidative dehydrogenation is performed by contacting the alkane with a suitable dehydrogenation catalyst at a temperature of at least 500° C. to produce the corresponding alkene and hydrogen and wherein the second mode is an oxidative dehydrogenation wherein the oxidative dehydrogenation is performed by contacting the alkane with a suitable dehydrogenation catalyst and an oxidation agent at a temperature from 300 to 500° C. to produce the corresponding alkene wherein the dehydrogenation catalyst for the oxidative dehydrogenation and the non-oxidative dehydrogenation are the same, wherein the heat for the first mode is provided by a solar energy source.

Abstract translation: 用于通过相应烷烃脱氢生产烯烃的基于太阳能的连续方法和反应器系统在反应器中进行，该反应器包括在同一反应器中交替执行第一模式和第二模式，其中第一模式是非 氧化脱氢，其中所述非氧化脱氢是通过在至少500℃的温度下使所述烷烃与合适的脱氢催化剂接触以产生相应的烯烃和氢气进行的，其中所述第二模式是氧化脱氢，其中所述氧化脱氢 是通过使烷烃与合适的脱氢催化剂和氧化剂在300-500℃的温度下接触来制备相应的烯烃，其中用于氧化脱氢和非氧化脱氢的脱氢催化剂是相同的，其中 用于第一模式的热量由太阳能源提供 。