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    Ethylene oligomerization
    2.
    发明授权
    Ethylene oligomerization 失效

    公开(公告)号：US3647914A

    公开(公告)日：1972-03-07

    申请号：US3647914D

    申请日：1969-11-04

    Applicant: SHELL OIL CO

    Inventor： GLOCKNER PETER W ,  KEIM WILHELM ,  MASON RONALD F

    IPC: C07C2/34 ,  C07C3/10

    CPC classification number: C07C2/34 ,  C07C2531/22 ,  C07C2531/24

    Abstract: ETHYLENE IS OLIGOMERIZED TO A MIXTURE OF OLEFINIC PRODUCTS OF HIGH LINEARITY IN THE PRESENCE OF A NICKEL CHELATE OF A BIDENTATE LINGAND HAVING A TERTIARY ORGANOPHOSPHORUS MOIETY AND A FUNCTIONAL GROUP SELECTED FROM HYDROXYMETHYL, MERCAPTOMETHYL, HYDROCARBOYL AND HYDROCARBYLOXYCARBONYL SUBSTITUTED ON A CARBON ATOM ATTACNED DIRECTLY TO THE PHOSPHORUS ATOM OF THE ORGANOPHOSPHOURS MOIETY.

    Alpha-olefin production
    7.
    发明授权
    Alpha-olefin production 失效
    ALPHA-OLEFIN生产

    公开(公告)号：US3676523A

    公开(公告)日：1972-07-11

    申请号：US3676523D

    申请日：1971-07-16

    Applicant: SHELL OIL CO

    Inventor： MASON RONALD F

    IPC: C07C2/36 ,  C07C3/10

    CPC classification number: C07C2/36 ,  C07C2531/14 ,  C07C2531/24 ,  Y10S585/906

    Abstract: Ethylene is oligomerized to linear, alpha-olefins by reacting ethylene in liquid phase solution in the presence of a catalyst composition produced by contacting in the presence of ethylene (1) a simple divalent nickel salt (2) a boron hydride reducing agent and (3) an o-dihydrocarbylphosphinobenzoic acid or alkali metal salt thereof.

    Abstract translation: 乙烯在液相溶液中通过在乙烯存在下（1）简单的二价镍盐（2）硼氢化物还原剂和（3）的存在下接触而产生的催化剂组合物使乙烯低聚成线性α-烯烃 ）邻二烃基膦基苯甲酸或其碱金属盐。

    Oxo alcohols using catalysts comprising ditertiary phosphines
    8.
    发明授权
    Oxo alcohols using catalysts comprising ditertiary phosphines 失效
    使用包含文献磷酸酯的催化剂的OXO酒精

    公开(公告)号：US3527818A

    公开(公告)日：1970-09-08

    申请号：US3527818D

    申请日：1968-06-05

    Applicant: SHELL OIL CO

    Inventor： MASON RONALD F ,  WINKLE JOHN L VAN

    IPC: B01J31/16 ,  B01J31/20 ,  B01J31/24 ,  C07C29/16 ,  C07F9/6568 ,  C07F15/06

    CPC classification number: C07F9/65683 ,  B01J31/20 ,  B01J31/2414 ,  B01J2531/845 ,  C07C29/16 ,  C07C31/125

    Abstract: 1,127,965. Hydrocarbylene-his (monophosphabicyclo hydrocarbons); cobalt-containing complexes. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 24 Nov., 1966 [26 Nov., 1965], No. 52662/66. Heading C2C. [Also in Division B1] Novel hydrocarbylene - bis (monophosphabicyclo hydrocarbons) where the hydrocarbylene group may contain one or more functional groups as substituents and in which, in each bicyclic structure, the phosphorus atom, being linked to the hydrocarbylene group, is a member of a ring without being a bridge-head atom and the smallest phosphorus-containing ring consists of at least 5 atoms, are prepared by reacting a secondary phosphine, preferably a bicyclic heterocyclic secondary phosphine, with a polyolefinic compound containing at least two isolated ethylenic bonds in the presence of a free-radical-generating catalyst and in the absence of substantial amounts of oxygen. Specified catalysts are azonitriles, a dialkyl or diacyl peroxide, actinic radiation and high energy or ionizing radiation. Typical products may be represented by the formula where Q is hydrocarbylene, y, z, y 1 and z 1 each represent integers of 1 or more and y + z = 3 and y 1 + z 1 = 3, R is hydrogen or C 1-4 alkyl. Specified functional substituents are carbonyl, carboxyl, nitro, amino, hydroxy, cyano, sulphonyl and sulphoxyl. The compounds may also be prepared by reacting a diprimary hydrocarbylene phosphine with a cyclo-octadiene in the presence of a free radical-generating catalyst and in the substantial absence of oxygen. The novel compounds are used as phosphine ligands in complexes containing cobalt, e.g. cobalt carbonyl. Such complexes are used as catalysts for the production of alcohols and/or aldehydes by the reaction of olefins with CO and H 2 , and the catalysts may be prepared in situ, e.g. from cobalt octanoate. The hydroformylation of 1-dodecene is described.

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