Absorbent composition for the selective absorption of hydrogen sulfide

    公开(公告)号:US11071944B2

    公开(公告)日:2021-07-27

    申请号:US14402382

    申请日:2013-05-29

    申请人: SHELL OIL COMPANY

    摘要: An absorbent composition that is useful in the selective removal of hydrogen sulfide relative to carbon dioxide from gaseous mixtures that comprise both hydrogen sulfide and carbon dioxide and the use thereof. The absorbent composition includes an amine mixture of an amination reaction product of tert-butylamine with a polydispersed polyethylene glycol (PEG) mixture having an average molecular weight within a certain specified range of molecular weights. The amination reaction product may also comprise a first sterically hindered amine and a second sterically hindered amine. The absorbent composition, preferably, includes an organic co-solvent, such as a sulfone compound. A method is also provided for improving the operation of certain gas absorption processes by utilizing the absorbent composition.

    ABSORBENT COMPOSITION FOR THE SELECTIVE ABSORPTION OF HYDROGEN SULFIDE
    3.
    发明申请
    ABSORBENT COMPOSITION FOR THE SELECTIVE ABSORPTION OF HYDROGEN SULFIDE 审中-公开
    用于选择性吸收氢硫化物的吸收组合物

    公开(公告)号:US20150157975A1

    公开(公告)日:2015-06-11

    申请号:US14402382

    申请日:2013-05-29

    申请人: SHELL OIL COMPANY

    IPC分类号: B01D53/14

    摘要: An absorbent composition that is useful in the selective removal of hydrogen sulfide relative to carbon dioxide from gaseous mixtures that comprise both hydrogen sulfide and carbon dioxide and the use thereof. The absorbent composition includes an amine mixture of an amination reaction product of tert-butylamine with a polydispersed polyethylene glycol (PEG) mixture having an average molecular weight within a certain specified range of molecular weights. The amination reaction product may also comprise a first sterically hindered amine and a second sterically hindered amine. The absorbent composition, preferably, includes an organic co-solvent, such as a sulfone compound. A method is also provided for improving the operation of certain gas absorption processes by utilizing the absorbent composition.

    摘要翻译: 可用于从包含硫化氢和二氧化碳的气态混合物中相对于二氧化碳选择性除去硫化氢的吸收剂组合物及其用途。 吸收剂组合物包括叔丁胺与多分散聚乙二醇(PEG)混合物的胺化反应产物的胺混合物,其平均分子量在特定的分子量范围内。 胺化反应产物还可以包含第一空间位阻胺和第二空间位阻胺。 吸收剂组合物优选包括有机共溶剂,例如砜化合物。 还提供了一种通过利用吸收剂组合物改进某些气体吸收过程的操作的方法。

    METHOD OF IMPROVING A PROCESS FOR THE SELECTIVE ABSORPTION OF HYDROGEN SULFIDE
    4.
    发明申请
    METHOD OF IMPROVING A PROCESS FOR THE SELECTIVE ABSORPTION OF HYDROGEN SULFIDE 审中-公开
    改进选择性吸收氢硫化物的方法

    公开(公告)号:US20150122125A1

    公开(公告)日:2015-05-07

    申请号:US14402464

    申请日:2013-05-29

    申请人: SHELL OIL COMPANY

    IPC分类号: B01D53/14

    摘要: An absorbent composition that is useful in the selective removal of hydrogen sulfide relative to carbon dioxide from gaseous mixtures that comprise both hydrogen sulfide and carbon dioxide and the use thereof. The absorbent composition includes an amine mixture of an amination reaction product of tert-butylamine with a polydispersed polyethylene glycol (PEG) mixture having an average molecular weight within a certain specified range of molecular weights. The amination reaction product may also comprise a first sterically hindered amine and a second sterically hindered amine. The absorbent composition, preferably, includes an organic co-solvent, such as a sulfone compound. A method is also provided for improving the operation of certain gas absorption processes by utilizing the absorbent composition.

    摘要翻译: 可用于从包含硫化氢和二氧化碳的气态混合物中相对于二氧化碳选择性除去硫化氢的吸收剂组合物及其用途。 吸收剂组合物包括叔丁胺与多分散聚乙二醇(PEG)混合物的胺化反应产物的胺混合物,其平均分子量在特定的分子量范围内。 胺化反应产物还可以包含第一空间位阻胺和第二空间位阻胺。 吸收剂组合物优选包括有机共溶剂,例如砜化合物。 还提供了一种通过利用吸收剂组合物改进某些气体吸收过程的操作的方法。