公开(公告)号：US20150376138A1

公开(公告)日：2015-12-31

申请号：US14767533

申请日：2014-02-18

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Yasuyuki NAKAE ,  Akio MANABE ,  Takashi MIYAMOTO

IPC: C07D237/14 ,  C07C67/475 ,  C07C69/675 ,  C07D237/08

CPC classification number: C07D237/14 ,  C07C67/475 ,  C07C69/675 ,  C07D237/08

Abstract: The present invention provides a process for producing a compound of the formula (1) wherein X represents a hydrogen atom, etc., and Y represents a hydrogen atom, etc., which comprises step 1 of reacting a compound of the formula (2) and a compound of the formula (3) in the presence of a Lewis acid wherein R represents a hydrogen atom, etc., to obtain an adduct, and step 2 of reacting the adduct obtained in the step 1 and hydrazine to obtain the compound of the formula (1).

Abstract translation: 本发明提供了制备式（1）化合物的方法，其中X表示氢原子等，Y表示氢原子等，其包括使式（2）的化合物与式 和式（3）的化合物在路易斯酸存在下，其中R表示氢原子等，得到加合物，步骤2使步骤1中得到的加合物与肼反应，得到化合物 公式（1）。

公开(公告)号：US20160060225A1

公开(公告)日：2016-03-03

申请号：US14779383

申请日：2014-03-17

Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED

Inventor： Akio MANABE

IPC: C07D237/14 ,  C07D307/60

CPC classification number: C07D237/14 ,  C07D237/16 ,  C07D307/60

Abstract: A compound represented by formula (2) wherein X represents a hydrogen atom, a fluorine atom, a chlorine atom or a bromine atom, and Y represents a hydrogen atom, a fluorine atom, a chlorine atom or a bromine atom,is reacted with a brominating agent and an alkanol having 1 to 6 carbon atoms in the presence of a base to obtain a compound represented by formula (3) wherein R represents a C1 to C6 alkyl group, and X and Y represent the same meaning as described above,and then the compound represented by the formula (3) is reacted with hydrazine, whereby a compound represented by formula (1) wherein X and Y represent the same meaning as described above, which is useful as a production intermediate of a fungicide, can be obtained.

Abstract translation: 由式（2）表示的化合物，其中X表示氢原子，氟原子，氯原子或溴原子，Y表示氢原子，氟原子，氯原子或溴原子，与 溴化剂和具有1至6个碳原子的链烷醇，以获得由式（3）表示的化合物，其中R表示C1至C6烷基，X和Y表示与上述相同的含义， 然后将由式（3）表示的化合物与肼反应，由此得到其中X和Y表示与上述相同含义的式（1）表示的化合物，其可用作杀真菌剂的生产中间体 。