公开(公告)号：US20160347707A1

公开(公告)日：2016-12-01

申请号：US15116699

申请日：2015-02-04

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Masahiro HOSHINO ,  Yuta KIKUCHI

IPC分类号： C07C231/10 ,  C07C249/04 ,  B01J23/46 ,  B01J21/16 ,  B01J21/06

CPC分类号： C07C231/10 ,  B01J21/063 ,  B01J21/16 ,  B01J23/462 ,  B01J27/02 ,  B01J31/02 ,  B01J31/0235 ,  B01J31/0247 ,  C07C249/04 ,  C07C251/44 ,  C07C2601/14 ,  Y02P20/582

摘要： A novel catalyst is provided which enables efficient production of an oxidation product by using an oxygen-induced oxidation reaction of an organic substrate. A novel method of using the catalyst enables efficient manufacturing of the oxidation product by oxidizing the organic substrate using oxygen. A catalyst used in the oxidation reaction of the organic substrate using oxygen contains compound (A), compounds (A) and (B), compounds (A) and (C), compounds (B) and (C), or compounds (A) and (B) and (C). A method for manufacturing the oxidation product using the catalyst involves bringing the organic substrate into contact with oxygen. Compound (A) is an inorganic peroxo acid, a salt of an inorganic peroxo acid, and/or N-halogenated succinimide, compound (B) is a nitroxide and/or a peroxide, and compound (C) is layered silicate.

摘要翻译： 提供了一种新颖的催化剂，其通过使用有机基底的氧诱导氧化反应有效地生产氧化产物。 使用该催化剂的新方法使得能够通过使用氧气氧化有机底物来有效地制造氧化产物。 在使用氧的有机底物的氧化反应中使用的催化剂包含化合物（A），化合物（A）和（B），化合物（A）和（C），化合物（B）和（C） ）和（B）和（C）。 使用该催化剂制造氧化产物的方法包括使有机基材与氧接触。 化合物（A）是无机过氧酸，无机过氧酸盐和/或N-卤化琥珀酰亚胺，化合物（B）是氮氧化物和/或过氧化物，化合物（C）是层状硅酸盐。

公开(公告)号：US20160075639A1

公开(公告)日：2016-03-17

申请号：US14779737

申请日：2014-03-17

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Masahiro HOSHINO ,  Yuta KIKUCHI

IPC分类号： C07C249/04 ,  C07D223/10

CPC分类号： C07C249/04 ,  C07C2601/14 ,  C07D223/10 ,  Y02P20/582 ,  C07C251/44

摘要： Provided is a method for efficiently producing an oxime, which is a method for producing an oxime by oxidizing, an amine, the method comprising a first contact step and a second contact step, wherein the second contact step is performed by bringing an additional amine into contact with oxygen in the presence of at least a part of an oxidation product obtained in the first contact step.

摘要翻译： 提供了一种有效生产肟的方法，肟是通过氧化胺制备肟的方法，该方法包括第一接触步骤和第二接触步骤，其中第二接触步骤通过将另外的胺进行 在至少一部分在第一接触步骤中获得的氧化产物的存在下与氧接触。

公开(公告)号：US20150353478A1

公开(公告)日：2015-12-10

申请号：US14655514

申请日：2013-12-12

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Masahiro HOSHINO ,  Yuta KIKUCHI ,  Sho TSUJIUCHI

IPC分类号： C07C249/04 ,  C07D201/04

CPC分类号： C07C249/04 ,  C07C2601/14 ,  C07D201/04 ,  C07C251/44

摘要： Provided is a method for producing an oxime compound with satisfactory selectivity. Provide is a method for producing an oxime represented by the following formula (II): wherein R1 and R2 are respectively the same as defined below, the method including oxidizing an amine represented by the following formula (I): wherein R1 and R2 each independently represents a hydrogen atom, an optionally substituted hydrocarbon group, or an optionally substituted heterocyclic group (provided that R1 and R2 are not simultaneously hydrogen atoms), orR1 and R2, together with the carbon atom to which R1 and R2 are attached, form an optionally substituted alicyclic hydrocarbon group having 3 to 12 carbon atoms [hereinafter sometimes referred to as the amine compound (I)],with oxygen in the presence of a layered silicate.

摘要翻译： 提供一种具有令人满意的选择性的肟化合物的制造方法。 提供一种生产由下式（II）表示的肟的方法：其中R1和R2分别与下述定义相同，该方法包括氧化由下式（I）表示的胺：其中R1和R2各自独立地 表示氢原子，任选取代的烃基或任选取代的杂环基（条件是R 1和R 2不同时为氢原子），或者R 1和R 2与连接R 1和R 2的碳原子一起形成 任选取代的具有3〜12个碳原子的脂环族烃基[以下有时称为胺化合物（I）]与层状硅酸盐存在下的氧。