公开(公告)号：US07144925B2

公开(公告)日：2006-12-05

申请号：US10476438

申请日：2002-05-09

申请人： Sandrine Burgun ,  Jonathan Kammerer ,  Chung P. Park ,  William G. Stobby ,  Suresh Subramonian

发明人： Sandrine Burgun ,  Jonathan Kammerer ,  Chung P. Park ,  William G. Stobby ,  Suresh Subramonian

IPC分类号： C08J9/00

CPC分类号： C08J9/0057 ,  C08J2201/03 ,  C08K3/2279

摘要： A macrocellular foam is described having improved cell size and Fire-test-response Characteristics, among other features, which is obtained by selecting a particle size less than 1 micron for the flame retardant adjuvant. The inventors found that the amount of fire retardant adjuvant can be increased for a given foam cell size or the foam cell size can be increased for a given amount of fire retardant adjuvant, allowing the production of foams having exceptionally large, well-formed, cells that have excellent Fire-test-response Characteristics. The benefits are especially noteworthy in relation to thermoplastic foams and inorganic flame retardation adjuvants, due to the unexpected reduction in the nucleation effect of the adjuvant. The foams are useful for improving the acoustic performance of products that are required to meet certain Fire-test-response Characteristics. It may be used in automotive and other transportation devices, building and construction, household and garden appliances, power tool and appliance and electrical supply housing, connectors, and aircraft as acoustic systems for sound absorption and insulation.

摘要翻译： 描述了具有改进的电池尺寸和耐火试验响应特性的宏观泡沫，以及通过选择阻燃助剂的小于1微米的粒度而获得的其它特征。 本发明人发现，对于给定的泡沫电池尺寸，阻燃助剂的量可以增加，或者对于给定量的阻燃助剂可以增加泡沫电池的尺寸，允许制造具有异常大的，形成良好的电池的泡沫 具有优良的耐火试验响应特性。 由于佐剂的成核作用的出人意料的降低，与热塑性泡沫和无机阻燃助剂有关的益处特别值得注意。 泡沫可用于提高满足某些防火测试响应特性所需的产品的声学性能。 它可以用于汽车和其他运输设备，建筑和建筑，家庭和园艺用具，电动工具，家电和电源外壳，连接器和飞机作为吸声和绝缘的声学系统。

公开(公告)号：US06720363B2

公开(公告)日：2004-04-13

申请号：US09782499

申请日：2001-02-13

申请人： Suresh Subramonian ,  Sandrine Burgun ,  Chung P. Park

发明人： Suresh Subramonian ,  Sandrine Burgun ,  Chung P. Park

IPC分类号： C08J900

CPC分类号： C08J9/0019 ,  C08J9/0061 ,  C08J2201/03 ,  C08J2323/02

摘要： A process for making a macrocellular acoustic foam is disclosed in which a foamable gel made of a blowing agent and a polymeric resin composition is subjected to an extrusion process at a die pressure greater than the prefoaming critical die pressure but less than or equal to four times that of said prefoaming critical die pressure and macrocellular foams obtainable by that process are also disclosed which are made of: A) one or more homopolymers of ethylene, one or more C3-C20 &agr;-olefin polymers, or a combination thereof; B) one or more halogenated flame retardants; C) optionally, one or more polymers other than that of Component A; and D) optionally, one or more flame retardant synergists.

摘要翻译： 公开了一种制造宏蜂窝泡沫的方法，其中由发泡剂和聚合物树脂组合物制成的可发泡凝胶在大于预发泡临界压模的模压下进行挤出加工，但小于或等于四倍 还公开了通过该方法可获得的所述预发泡临界模压和宏蜂窝泡沫的那些，其由以下制成：A）一种或多种乙烯均聚物，一种或多种C 3 -C 20α-烯烃聚合物或其组合; B）一种 或更多的卤化阻燃剂; C）任选的一种或多种不同于组分A的聚合物; 和D）任选的一种或多种阻燃增效剂。

公开(公告)号：US06590006B2

公开(公告)日：2003-07-08

申请号：US09782231

申请日：2001-02-13

申请人： Chung P. Park ,  Suresh Subramonian ,  Sandrine Burgun

发明人： Chung P. Park ,  Suresh Subramonian ,  Sandrine Burgun

IPC分类号： C08J936

CPC分类号： C08J9/0061 ,  C08J9/38 ,  C08J2205/05 ,  C08J2323/06 ,  C08J2423/00

摘要： Macrocellular polyolefin foams that can withstand temperatures above 110° C. are described for use in sound absorption and insulation applications, especially in elevated temperature and/or moist environments. These foams have a large cell size (≧1.5 mm), are open or closed-cell foams, and preferably have at least one perforation per square centimeter and/or a density less than 25 kg/m3. They are obtainable by extruding a high melt strength (HMS) polypropylene resin (PP), or preferably a blend of a HMS PP resin and a free radical polymerized ethylene polymer present in the blend in a weight ratio of at least 35:65, optionally another polymer such as a substantially random interpolymer, a cell size enlarging agent such a glycerol monostearate, an antioxidant, carbon black and/or flame retardant additives, using a volatile organic compound, e.g. isobutane, as blowing agent.

摘要翻译： 描述了能够承受高于110℃的温度的大量聚烯烃泡沫，用于吸音和绝缘应用，特别是在高温和/或潮湿环境中。 这些泡沫具有大的泡孔尺寸（> = 1.5mm），是开孔或闭孔泡沫，并且优选地具有每平方厘米至少一个穿孔和/或小于25kg / m 3的密度。 它们可以通过以至少35:65的重量比挤出高熔体强度（HMS）聚丙烯树脂（PP），或优选HUB PP树脂和共混物中存在的自由基聚合的乙烯聚合物的共混物，任选地 使用挥发性有机化合物的另一种聚合物，例如基本上无规的互聚物，细胞尺寸扩大剂如甘油单硬脂酸酯，抗氧化剂，炭黑和/或阻燃添加剂，例如 异丁烷，作为发泡剂。

公开(公告)号：US20080058437A1

公开(公告)日：2008-03-06

申请号：US11663800

申请日：2005-10-07

申请人： Sandrine Burgun ,  Suresh Subramonian

发明人： Sandrine Burgun ,  Suresh Subramonian

IPC分类号： C08L23/12

CPC分类号： C08J9/14 ,  C08J9/0061 ,  C08J2201/03 ,  C08J2205/05 ,  C08J2323/12 ,  C08J2423/00 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/10 ,  C08L2203/14 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/06

摘要： Foam a polymer blend of (a) a high melt strength polypropylene (HMS PP); (b) a linear or substantially linear polypropylene that has a melting point within ten degrees Celsius of (a), a melt flow rate that is significantly different than (a) and that is miscible with (a); and, optionally, (c) a polyethylene that is immiscible with (a) produces a polymeric foam having an average cell size of at least four millimeters and that has an inherent open-celled content of at least 40 percent. The HMS PP makes up 60 weight percent(wt %) or more and 90 wt % or less of the total combined weight of (a) and (b). Component (c) makes up 60 wt % or less of the total polymer blend weight.

摘要翻译： 泡沫（a）高熔体强度聚丙烯（HMS PP）的聚合物共混物; （b）具有（a）熔点在10摄氏度内的线性或基本上线性的聚丙烯，熔体流动速率与（a）明显不同并且与（a）混溶; 和（c）与（a）不混合的聚乙烯，其产生具有至少四毫米的平均泡孔尺寸并且具有至少40％的固有的开孔含量的聚合物泡沫。 HMS PP占（a）和（b）的总组合重量的60重量％（wt％）以上且90重量％以下。 组分（c）占总聚合物共混物重量的60重量％或更少。

公开(公告)号：US07759404B2

公开(公告)日：2010-07-20

申请号：US11663800

申请日：2005-10-07

申请人： Sandrine Burgun ,  Suresh Subramonian

发明人： Sandrine Burgun ,  Suresh Subramonian

IPC分类号： C08L47/00 ,  C08J9/00 ,  C08F110/00

CPC分类号： C08J9/14 ,  C08J9/0061 ,  C08J2201/03 ,  C08J2205/05 ,  C08J2323/12 ,  C08J2423/00 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/10 ,  C08L2203/14 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2666/02 ,  C08L2666/06

摘要： Foam a polymer blend of (a) a high melt strength polypropylene (HMS PP); (b) a linear or substantially linear polypropylene that has a melting point within ten degrees Celsius of (a), a melt flow rate that is significantly different than (a) and that is miscible with (a); and, optionally, (c) a polyethylene that is immiscible with (a) produces a polymeric foam having an average cell size of at least four millimeters and that has an inherent open-celled content of at least 40 percent. The HMS PP makes up 60 weight percent (wt %) or more and 90 wt % or less of the total combined weight of (a) and (b). Component (c) makes up 60 wt % or less of the total polymer blend weight.

摘要翻译： 泡沫（a）高熔体强度聚丙烯（HMS PP）的聚合物共混物; （b）具有（a）熔点在10摄氏度内的线性或基本上线性的聚丙烯，熔体流动速率与（a）明显不同且与（a）混溶）。 和（c）与（a）不混合的聚乙烯，其产生具有至少四毫米的平均泡孔尺寸并且具有至少40％的固有的开孔含量的聚合物泡沫。 HMS PP占（a）和（b）的总组合重量的60重量％（wt％）以上且90重量％以下。 组分（c）占总聚合物共混物重量的60重量％或更少。