摘要:
Disclosed herein is a positive electrode active material prepared by mixing a lithium-containing compound, a compound containing a transition metal to be put into a solid solution, and a compound containing a metallic element M2 different from the transition metal, and firing the mixture to form composite oxide particles, depositing a compound containing at least one element selected from among sulfur (S), phosphorus (P) and fluorine (F) on surfaces of the particles, and firing the particles, whereby each of the particles is provided with a concentration gradient such that the concentration of the metallic element M2 increases from the center toward the surface of the particle, and at least one element selected from among (S), (P) and (F) is made present in the form of being aggregated at the surfaces of the composite oxide particles.
摘要:
Disclosed herein is a positive electrode active material wherein at least one metallic element M1 different from a principal transition metal element A is present at least at part of a surface of a lithium-containing transition metal oxide containing the principal transition metal element A, and, further, a compound of a metallic element M2 different from the metallic element M1 is present in a coating manner or in the vicinity of the lithium-containing transition metal oxide.
摘要:
Disclosed herein is a positive electrode active material prepared by mixing a lithium-containing compound, a compound containing a transition metal to be put into a solid solution, and a compound containing a metallic element M2 different from the transition metal, and firing the mixture to form composite oxide particles, depositing a compound containing at least one element selected from among sulfur (S), phosphorus (P) and fluorine (F) on surfaces of the particles, and firing the particles, whereby each of the particles is provided with a concentration gradient such that the concentration of the metallic element M2 increases from the center toward the surface of the particle, and at least one element selected from among (S), (P) and (F) is made present in the form of being aggregated at the surfaces of the composite oxide particles.
摘要:
Disclosed herein is a positive electrode active material wherein at least one metallic element M1 different from a principal transition metal element A is present at least at part of a surface of a lithium-containing transition metal oxide containing the principal transition metal element A, and, further, a compound of a metallic element M2 different from the metallic element M1 is present in a coating manner or in the vicinity of the lithium-containing transition metal oxide.
摘要:
A secondary battery includes: a cathode; an anode; and an electrolytic solution. The cathode includes two or more kinds of lithium transition metal complex phosphate particles including lithium and one or two or more transition metals as constituent elements, and the composition of the one or two or more transition metals differs between the two or more kinds of lithium transition metal complex phosphate particles.
摘要:
A cathode includes a lithium transition metal complex compound including lithium, one, or two or more transition metals, magnesium, and oxygen as constituent elements. In a standardized X-ray absorption spectrum of the lithium transition metal complex compound measured by an X-ray absorption spectroscopic method, a first absorption edge having absorption edge energy E1 in X-ray absorption intensity of about 0.5 exits in a range where X-ray energy is from about 1303 eV to about 1313 eV both inclusive, in a discharged state in which a discharge voltage is about 3.0 V, and a second absorption edge having absorption edge energy E2 in X-ray absorption intensity of about 0.5 exits, in a charged state in which a charge voltage V is from about 4.3 V to about 4.5 V both inclusive. The absorption edge energies E1 and E2 and the charge voltage V satisfy a relation of E2−E1≧(V−4.25)×4.
摘要:
A lithium ion secondary battery capable of improving the lithium ion input-output characteristics. An active material capable of storing and releasing lithium ions is a Li complex oxide or a Li complex oxoacid salt. A plurality of primary particles have a particle size distribution with 1 nm
摘要:
A lithium ion secondary battery includes: a positive electrode; a negative electrode; and an electrolytic solution, at least one of the positive electrode and the negative electrode being capable of storing and releasing lithium ions, and containing an active material that satisfies predetermined conditions.
摘要:
A lithium ion secondary battery includes: a positive electrode; a negative electrode; and an electrolytic solution, at least one of the positive electrode and the negative electrode being capable of storing and releasing lithium ions, and containing an active material that satisfies predetermined conditions.
摘要:
A lithium ion secondary battery capable of improving the lithium ion input-output characteristics. An active material capable of storing and releasing lithium ions is a Li complex oxide or a Li complex oxoacid salt. A plurality of primary particles have a particle size distribution with 1 nm