摘要:
The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.
摘要:
The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.
摘要:
A lithium mixed metal oxide comprising Ni, Mn and Fe and having a BET specific surface area of 2 m2/g or more and 30 m2/g or less. A method of producing a lithium mixed metal oxide, comprising bringing an aqueous solution containing Ni, Mn, Fe and Cl into contact with an alkali to obtain a coprecipitate, and calcining a mixture of the coprecipitate and a lithium compound by maintaining the mixture at a temperature of lower than 900° C. A positive electrode active material for nonaqueous electrolyte secondary battery, comprising the lithium mixed metal oxide described above or the lithium mixed metal oxide obtained by the method of producing a lithium mixed metal oxide described above as a main ingredient. A positive electrode for nonaqueous electrolyte secondary battery having the positive electrode active material for nonaqueous electrolyte secondary battery described above.
摘要:
A lithium mixed metal oxide comprising Ni, Mn and Fe and having a BET specific surface area of 2 m2/g or more and 30 m2/g or less. A method of producing a lithium mixed metal oxide, comprising bringing an aqueous solution containing Ni, Mn, Fe and Cl into contact with an alkali to obtain a coprecipitate, and calcining a mixture of the coprecipitate and a lithium compound by maintaining the mixture at a temperature of lower than 900° C. A positive electrode active material for nonaqueous electrolyte secondary battery, comprising the lithium mixed metal oxide described above or the lithium mixed metal oxide obtained by the method of producing a lithium mixed metal oxide described above as a main ingredient. A positive electrode for nonaqueous electrolyte secondary battery having the positive electrode active material for nonaqueous electrolyte secondary battery described above. A nonaqueous electrolyte secondary battery having the positive electrode for nonaqueous electrolyte secondary battery described above.
摘要:
The object of the present invention is to provide a method for producing simply a positive electrode active material which can further increase charge-discharge capacity of secondary batteries when the positive electrode active material is used for positive electrode of secondary batteries, particularly non-aqueous electrolyte secondary batteries. A method for producing a positive electrode active material includes the step of heat-treating a lithium mixed metal oxide represented by the formula Li2MO3 in the presence of a hydride wherein M is at least one element selected from the group consisting of Ti, V, Mn, Fe, Co and Ni.
摘要:
There is provided a method for producing an active material for a nonaqueous secondary battery, including firing an adherend in which a compound containing an element A (at least one element selected from among B, Al, Ga, In, Si, Ge, Sn, Mg and transition metal elements) is adhered to a particle surface of a material capable of being doped and dedoped with lithium ions, in a water-containing atmosphere so that weight increasing rate of the adherend is in a range of 0.1% by weight or more and 5.0% by weight or less, and firing the adherend.
摘要:
The object of the present invention is to provide a method for producing simply a positive electrode active material which can further increase charge-discharge capacity of secondary batteries when the positive electrode active material is used for positive electrode of secondary batteries, particularly non-aqueous electrolyte secondary batteries. A method for producing a positive electrode active material includes the step of heat-treating a lithium mixed metal oxide represented by the formula Li2MO3 in the presence of a hydride wherein M is at least one element selected from the group consisting of Ti, V, Mn, Fe, Co and Ni.
摘要:
There is provided a method for producing an active material for a nonaqueous secondary battery, including firing an adherend in which a compound containing an element A (at least one element selected from among B, Al, Ga, In, Si, Ge, Sn, Mg and transition metal elements) is adhered to a particle surface of a material capable of being doped and dedoped with lithium ions, in a water-containing atmosphere so that weight increasing rate of the adherend is in a range of 0.1% by weight or more and 5.0% by weight or less, and firing the adherend.
摘要:
A nonaqueous electrolyte secondary battery comprising a positive electrode containing a granular positive electrode active material composed of a mixed metal oxide and an M3-containing compound (M3 represents one or more elements selected from the group consisting of Group 3B elements in the periodic table, and the M3-containing compound is different from said mixed metal oxide) placed in the form of particles or a layer on the surface of the mixed metal oxide, wherein the positive electrode active material has M1 (M1 represents one or more elements selected from the group consisting of alkali metal elements), M2 (M2 represents one or more elements selected from the group consisting of Mn, Fe, Co and Ni), M3 (M3 has the same meaning as that described above) and O on its surface, and when the molar ratio (M3/M2) of the number of M3 atoms (mol) to the number of M2 atoms (mol) on the surface of the positive electrode active material is represented by A and the BET specific surface area of the positive electrode active material is represented by S (m2/g), A and S satisfy the following formula (1): A/S≧1 (1), a negative electrode, a separator, and a nonaqueous electrolyte.
摘要:
Disclosed are an electrode and a battery comprising the electrode. The electrode comprises a nano composite comprising nano particles capable of being oxidized and reduced and a carbonaceous material covering the nano particles.