公开(公告)号：US20100216024A1

公开(公告)日：2010-08-26

申请号：US12651578

申请日：2010-01-04

申请人： Ryoji KANNO ,  Masaaki Hirayama ,  Takayuki Kaneko ,  Yuichiro Imanari ,  Kenji Nakane

发明人： Ryoji KANNO ,  Masaaki Hirayama ,  Takayuki Kaneko ,  Yuichiro Imanari ,  Kenji Nakane

IPC分类号： H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/24 ,  H01M4/88

CPC分类号： H01M4/505 ,  C01G45/125 ,  C01G51/42 ,  C01G53/42 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/525 ,  H01M10/052 ,  Y10T29/49108

摘要： The object of the present invention is to provide a method for producing simply a positive electrode active material which can further increase charge-discharge capacity of secondary batteries when the positive electrode active material is used for positive electrode of secondary batteries, particularly non-aqueous electrolyte secondary batteries. A method for producing a positive electrode active material includes the step of heat-treating a lithium mixed metal oxide represented by the formula Li2MO3 in the presence of a hydride wherein M is at least one element selected from the group consisting of Ti, V, Mn, Fe, Co and Ni.

摘要翻译： 本发明的目的是提供一种简单地制造正极活性物质的方法，当正极活性物质用于二次电池的正极时，特别是非水电解质，可以进一步提高二次电池的充放电容量 二次电池 一种正极活性物质的制造方法，其特征在于，在氢化物存在下，对由式Li2MO3表示的锂复合金属氧化物进行热处理的步骤，其中M为选自Ti，V，Mn ，Fe，Co和Ni。

公开(公告)号：US08486159B2

公开(公告)日：2013-07-16

申请号：US12651578

申请日：2010-01-04

申请人： Ryoji Kanno ,  Masaaki Hirayama ,  Takayuki Kaneko ,  Yuichiro Imanari ,  Kenji Nakane

发明人： Ryoji Kanno ,  Masaaki Hirayama ,  Takayuki Kaneko ,  Yuichiro Imanari ,  Kenji Nakane

IPC分类号： H01M4/82 ,  H01M4/13

CPC分类号： H01M4/505 ,  C01G45/125 ,  C01G51/42 ,  C01G53/42 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/525 ,  H01M10/052 ,  Y10T29/49108

摘要： The object of the present invention is to provide a method for producing simply a positive electrode active material which can further increase charge-discharge capacity of secondary batteries when the positive electrode active material is used for positive electrode of secondary batteries, particularly non-aqueous electrolyte secondary batteries. A method for producing a positive electrode active material includes the step of heat-treating a lithium mixed metal oxide represented by the formula Li2MO3 in the presence of a hydride wherein M is at least one element selected from the group consisting of Ti, V, Mn, Fe, Co and Ni.

摘要翻译： 本发明的目的是提供一种简单地制造正极活性物质的方法，当正极活性物质用于二次电池的正极时，特别是非水电解质，可以进一步提高二次电池的充放电容量 二次电池 一种正极活性物质的制造方法，其特征在于，在氢化物存在下，对由式Li2MO3表示的锂复合金属氧化物进行热处理的步骤，其中M为选自Ti，V，Mn ，Fe，Co和Ni。

公开(公告)号：US20120244413A1

公开(公告)日：2012-09-27

申请号：US13513885

申请日：2010-12-02

申请人： Satoshi Shimano ,  Kenji Nakane ,  Cedric Pitteloud ,  Kenji Takamori ,  Yuichiro Imanari

发明人： Satoshi Shimano ,  Kenji Nakane ,  Cedric Pitteloud ,  Kenji Takamori ,  Yuichiro Imanari

IPC分类号： H01M4/485 ,  H01M4/58 ,  H01M4/1315 ,  H01M2/16 ,  H01M4/505 ,  H01M4/525

CPC分类号： C01G1/02 ,  C01G45/1228 ,  C01G51/50 ,  C01G53/50 ,  C01P2002/54 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525

摘要： The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.

摘要翻译： 本发明提供锂复合金属氧化物，锂复合金属氧化物和非水电解质二次电池的制造方法。 该方法包括在选择的一种或多种不活泼的助焊剂的存在下煅烧一种或多种M的化合物的混合物的步骤，其中M是选自镍，钴和锰的一种或多种元素和锂化合物 由A的氟化物，A的氯化物，A的碳酸盐，A的硫酸盐，A的硝酸盐，A的磷酸盐，A的氢氧化物，A的钼酸盐和A的钨酸盐组成的组， 其中A是选自Na，K，Rb，Cs，Ca，Mg，Sr和Ba中的一种或多种元素。 所述锂复合金属氧化物含有镍，钴和锰，BET比表面积为3m 2 / g〜15m 2 / g，平均粒径为0.1μm以上且小于1μm以下， 直径由激光衍射散射法确定。

公开(公告)号：US09240593B2

公开(公告)日：2016-01-19

申请号：US11912362

申请日：2006-04-21

申请人： Reiko Sasaki ,  Akiyoshi Nemoto ,  Kenji Nakane ,  Yuichiro Imanari ,  Kensaku Horie ,  Hiroshi Inukai

发明人： Reiko Sasaki ,  Akiyoshi Nemoto ,  Kenji Nakane ,  Yuichiro Imanari ,  Kensaku Horie ,  Hiroshi Inukai

IPC分类号： H01M4/88 ,  H01M4/52 ,  H01M4/36 ,  H01M4/48 ,  C01G51/00 ,  C01G53/00

CPC分类号： H01M4/523 ,  C01G51/42 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/366 ,  H01M4/483

摘要： There is provided a method for producing an active material for a nonaqueous secondary battery, including firing an adherend in which a compound containing an element A (at least one element selected from among B, Al, Ga, In, Si, Ge, Sn, Mg and transition metal elements) is adhered to a particle surface of a material capable of being doped and dedoped with lithium ions, in a water-containing atmosphere so that weight increasing rate of the adherend is in a range of 0.1% by weight or more and 5.0% by weight or less, and firing the adherend.

摘要翻译： 本发明提供一种非水系二次电池用活性物质的制造方法，其特征在于，烧成含有元素A（选自B，Al，Ga，In，Si，Ge，Sn， Mg和过渡金属元素）在含水气氛中粘附到能够掺杂和脱掺杂锂离子的材料的颗粒表面，使得被粘物的重量增加率在0.1重量％以上的范围内 5.0重量％以下，烧制被粘体。

公开(公告)号：US08703335B2

公开(公告)日：2014-04-22

申请号：US12679800

申请日：2008-09-26

申请人： Cedric Pitteloud ,  Yuichiro Imanari ,  Kenji Nakane

发明人： Cedric Pitteloud ,  Yuichiro Imanari ,  Kenji Nakane

IPC分类号： H01M4/13

CPC分类号： H01M4/485 ,  C01G45/1228 ,  C01G49/009 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052

摘要： A lithium mixed metal oxide comprising Ni, Mn and Fe and having a BET specific surface area of 2 m2/g or more and 30 m2/g or less. A method of producing a lithium mixed metal oxide, comprising bringing an aqueous solution containing Ni, Mn, Fe and Cl into contact with an alkali to obtain a coprecipitate, and calcining a mixture of the coprecipitate and a lithium compound by maintaining the mixture at a temperature of lower than 900° C. A positive electrode active material for nonaqueous electrolyte secondary battery, comprising the lithium mixed metal oxide described above or the lithium mixed metal oxide obtained by the method of producing a lithium mixed metal oxide described above as a main ingredient. A positive electrode for nonaqueous electrolyte secondary battery having the positive electrode active material for nonaqueous electrolyte secondary battery described above.

摘要翻译： 包含Ni，Mn和Fe并且BET比表面积为2m 2 / g以上且30m 2 / g以下的锂复合金属氧化物。 一种锂复合金属氧化物的制造方法，其特征在于，使含有Ni，Mn，Fe，Cl的水溶液与碱接触而得到共沉淀物，并将所述共沉淀物与锂化合物的混合物维持在 低于900℃的温度。一种用于非水电解质二次电池的正极活性材料，其包含上述锂复合金属氧化物或通过以上述锂复合金属氧化物的制备方法获得的锂复合金属氧化物作为主要成分 。 具有上述非水电解质二次电池用正极活性物质的非水电解质二次电池用正极。

公开(公告)号：US20100248032A1

公开(公告)日：2010-09-30

申请号：US12679800

申请日：2008-09-26

申请人： Cedric Pitteloud ,  Yuichiro Imanari ,  Kenji Nakane

发明人： Cedric Pitteloud ,  Yuichiro Imanari ,  Kenji Nakane

IPC分类号： H01M4/505 ,  H01M4/525 ,  C01D1/02 ,  H01M4/88

CPC分类号： H01M4/485 ,  C01G45/1228 ,  C01G49/009 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052

摘要： A lithium mixed metal oxide comprising Ni, Mn and Fe and having a BET specific surface area of 2 m2/g or more and 30 m2/g or less. A method of producing a lithium mixed metal oxide, comprising bringing an aqueous solution containing Ni, Mn, Fe and Cl into contact with an alkali to obtain a coprecipitate, and calcining a mixture of the coprecipitate and a lithium compound by maintaining the mixture at a temperature of lower than 900° C. A positive electrode active material for nonaqueous electrolyte secondary battery, comprising the lithium mixed metal oxide described above or the lithium mixed metal oxide obtained by the method of producing a lithium mixed metal oxide described above as a main ingredient. A positive electrode for nonaqueous electrolyte secondary battery having the positive electrode active material for nonaqueous electrolyte secondary battery described above. A nonaqueous electrolyte secondary battery having the positive electrode for nonaqueous electrolyte secondary battery described above.

摘要翻译： 包含Ni，Mn和Fe并且BET比表面积为2m 2 / g以上且30m 2 / g以下的锂复合金属氧化物。 一种锂复合金属氧化物的制造方法，其特征在于，使含有Ni，Mn，Fe，Cl的水溶液与碱接触而得到共沉淀物，并将所述共沉淀物与锂化合物的混合物维持在 低于900℃的温度。一种用于非水电解质二次电池的正极活性材料，其包含上述锂复合金属氧化物或通过以上述锂复合金属氧化物的制备方法获得的锂复合金属氧化物作为主要成分 。 具有上述非水电解质二次电池用正极活性物质的非水电解质二次电池用正极。 一种具有上述非水电解质二次电池用正极的非水电解质二次电池。

公开(公告)号：US20090314984A1

公开(公告)日：2009-12-24

申请号：US11912362

申请日：2006-04-21

申请人： Reiko Sasaki ,  Akiyoshi Nemoto ,  Kenji Nakane ,  Yuichiro Imanari ,  Kensaku Horie ,  Hiroshi Inukai

发明人： Reiko Sasaki ,  Akiyoshi Nemoto ,  Kenji Nakane ,  Yuichiro Imanari ,  Kensaku Horie ,  Hiroshi Inukai

IPC分类号： H01M4/36 ,  H01M4/48

CPC分类号： H01M4/523 ,  C01G51/42 ,  C01G53/42 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/366 ,  H01M4/483

摘要： There is provided a method for producing an active material for a nonaqueous secondary battery, including firing an adherend in which a compound containing an element A (at least one element selected from among B, Al, Ga, In, Si, Ge, Sn, Mg and transition metal elements) is adhered to a particle surface of a material capable of being doped and dedoped with lithium ions, in a water-containing atmosphere so that weight increasing rate of the adherend is in a range of 0.1% by weight or more and 5.0% by weight or less, and firing the adherend.

摘要翻译： 本发明提供一种非水系二次电池用活性物质的制造方法，其特征在于，烧成含有元素A（选自B，Al，Ga，In，Si，Ge，Sn， Mg和过渡金属元素）在含水气氛中粘附到能够掺杂和脱掺杂锂离子的材料的颗粒表面，使得被粘物的重量增加率在0.1重量％以上的范围内 5.0重量％以下，烧制被粘体。

公开(公告)号：US09822015B2

公开(公告)日：2017-11-21

申请号：US13513885

申请日：2010-12-02

申请人： Satoshi Shimano ,  Kenji Nakane ,  Cedric Pitteloud ,  Kenji Takamori ,  Yuichiro Imanari

发明人： Satoshi Shimano ,  Kenji Nakane ,  Cedric Pitteloud ,  Kenji Takamori ,  Yuichiro Imanari

IPC分类号： H01M4/525 ,  H01M4/52 ,  H01M4/485 ,  H01M4/48 ,  C01G1/02 ,  H01M4/505 ,  C01G45/12 ,  C01G51/00 ,  C01G53/00

CPC分类号： C01G1/02 ,  C01G45/1228 ,  C01G51/50 ,  C01G53/50 ,  C01P2002/54 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525

摘要： The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.

公开(公告)号：US08852805B2

公开(公告)日：2014-10-07

申请号：US13515726

申请日：2010-12-15

申请人： Maiko Saka ,  Yuichiro Imanari

发明人： Maiko Saka ,  Yuichiro Imanari

IPC分类号： H01M4/50 ,  H01M4/525 ,  H01M2/16 ,  H01M4/505 ,  H01M4/36 ,  C01G53/00 ,  C01G45/12 ,  B82Y30/00

CPC分类号： H01M4/505 ,  B82Y30/00 ,  C01G45/1242 ,  C01G53/50 ,  C01P2002/32 ,  C01P2002/54 ,  C01P2002/76 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  H01M4/364 ,  H01M4/525 ,  Y02E60/122

摘要： The present invention provides an electrode active material, an electrode and a non-aqueous electrolyte secondary battery. The electrode active material contains the following powder (A) and powder (B):(A) a powder of a lithium mixed metal oxide that is represented by the following formula (1) and has a layered rock-salt type crystal structure, the powder having a BET specific surface area of from 3 m2/g to 30 m2/g, Li(Ni1−(x+y)MnxFey)O2  (1) wherein x is within a range of more than 0 to less than 1, y is within a range of more than 0 to not more than 0.1, and x+y is within a range of more than 0 to less than 1; (B) a powder of a lithium mixed metal oxide that has a spinel type crystal structure. The electrode contains the electrode active material. The non-aqueous electrolyte secondary battery includes the electrode as a positive electrode.

摘要翻译： 本发明提供电极活性物质，电极和非水电解质二次电池。 电极活性物质含有下述粉末（A）和粉末（B）：（A）由下式（1）表示的锂复合金属氧化物粉末，具有层状岩盐型晶体结构， 具有3m 2 / g至30m 2 / g的BET比表面积的粉末，Li（Ni1-（x + y）Mn x Fey）O 2（1）其中x在0至小于1的范围内，y 在大于0至不大于0.1的范围内，x + y在大于0至小于1的范围内; （B）具有尖晶石型晶体结构的锂复合金属氧化物粉末。 电极含有电极活性物质。 非水电解质二次电池包括作为正极的电极。

公开(公告)号：US20130157108A1

公开(公告)日：2013-06-20

申请号：US13820612

申请日：2011-09-02

申请人： Kenji Takamori ,  Yuichiro Imanari

发明人： Kenji Takamori ,  Yuichiro Imanari

IPC分类号： H01M4/131

CPC分类号： H01M4/131 ,  C01G45/1221 ,  C01G51/44 ,  C01G51/50 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/50 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/40 ,  H01M2/1686 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M2004/021

摘要： The present invention provides a non-aqueous electrolyte secondary battery capable of exhibiting high discharge capacity maintenance rate at a high current rate, a lithium composite metal oxide useful therefor, and a method for producing the lithium composite metal oxide. This lithium composite metal oxide comprises Ni, Mn, Co, and Fe, and the BET specific surface area thereof is 3 m2/g to 15 m2/g. According to the present invention, a non-aqueous electrolyte secondary battery which exhibits high discharge capacity maintenance rate at a high current rate compared to a conventional lithium secondary battery can be obtained, and thus the secondary battery is very useful especially for applications where high discharge capacity maintenance rate at a high current rate is required, that is, non-aqueous electrolyte secondary batteries for automobiles or for power tools such as electric tools.

摘要翻译： 本发明提供能够以高电流率显示高放电容量维持率的非水电解质二次电池，可用于其的锂复合金属氧化物，以及锂复合金属氧化物的制造方法。 该锂复合金属氧化物包含Ni，Mn，Co，Fe，BET比表面积为3m 2 / g〜15m 2 / g。 根据本发明，可以获得与常规锂二次电池相比以高电流速率显示高放电容量维持率的非水电解质二次电池，因此二次电池非常有用，特别是对于高放电 需要高电流速率的容量维持率，即汽车用非水电解质二次电池，电动工具等电动工具。