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公开(公告)号：US5223465A
公开(公告)日：1993-06-29
申请号：US776350
申请日：1991-11-18
摘要： The present invention aims at providing an olefin polymerization catalyst comprising, as a component, a transition metal compound having two ligands such as .beta.-diketone, etc. coordinated, and having excellent properties as a polymerization catalyst in the polymerization of olefins including styrene compounds. This olefin polymerization catalyst comprises:(a) a transition metal compound represented by the general formula, ##STR1## wherein M represents titanium, zirconium, hafnium or vanadium, Y.sup.1 and Y.sup.2 each represent, same or different, halogen atoms or alkyl groups containing 1 to 10 carbon atoms and R.sup.1, R.sup.2 and R.sup.3 each represent hydrogen atoms or hydrocarbon groups containing 1 to 10 carbon atoms, at least one of which is a hydrogen atom but all of which must not be hydrogen atoms, and(b) an organoaluminum compound, in particular, aluminoxane.
摘要翻译： PCT No.PCT / JP91 / 00345 Sec。 371日期1991年11月18日 102（e）1991年11月18日日期PCT 1991年3月13日PCT PCT。 出版物WO91 / 日本1991年9月19日。本发明旨在提供一种烯烃聚合催化剂，其包含作为组分的具有两个配位体如β-二酮等的配位的过渡金属化合物，并且具有优异的作为聚合催化剂的性能 烯烃聚合包括苯乙烯化合物。 该烯烃聚合催化剂包括：（a）由通式表示的过渡金属化合物，其中M表示钛，锆，铪或钒，Y1和Y2各自表示相同或不同的卤原子或含1个 至10个碳原子，R 1，R 2和R 3各自表示氢原子或含有1至10个碳原子的烃基，其中至少一个为氢原子，但全部不能为氢原子，（b）有机铝化合物 ，特别是铝氧烷。
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公开(公告)号：US5177043A
公开(公告)日：1993-01-05
申请号：US663850
申请日：1991-03-22
申请人： Naomi Koyama , Hiroyuki Furuhashi , Miyuki Usui , Tomoko Okano , Masahide Murata , Satoshi Ueki , Akira Nakano
发明人： Naomi Koyama , Hiroyuki Furuhashi , Miyuki Usui , Tomoko Okano , Masahide Murata , Satoshi Ueki , Akira Nakano
CPC分类号： C08F10/00 , Y10S526/904
摘要： This invention relates to a catalytic component for the polymerization of .alpha.-olefins and provides a catalytic component of magnesium support type capable of exhibiting a high stereoregularity while maintaining an improved strength as well as a high catalytic activity. The features thereof consist in a catalyst component for the polymerization of .alpha.-olefins obtained by contacting (A) a solid component comprising, as essential components, magnesium, titanium, a halogen and an electron-donating compound with (D) an olefin in the presence of (B) a trialkylaluminum and (C) a dimethoxy group-containing compound represented by the general formula R.sup.1 R.sup.2 Si(OCH.sub.3).sub.2 where R.sup.1 and R.sup.2 are, same or different, aliphatic hydrocarbon groups with 1 to 10 carbon atoms and having a volume, calculated by the quantum chemistry calculation, of 230 to 500 .ANG..sup.3 and an electron density of oxygen atoms in the methoxy group, calculated similarly, ranging from 0.685 to 0.800 A. U. (atomic unit) and a catalyst component for the polymerization of .alpha.-olefins obtained by contacting (A) a solid component comprising, as essential components, a metal oxide, magnesium, titanium, a halogen and an electron-donating compound with (D) an olefin in the presence of (B) a trialkylaluminum and (C) a dimethoxy group-containing compound represented by the general formula R.sup.1 R.sup.2 Si(OCH.sub.3).sub.2 where R.sup.1 and R.sup.2 are, same or different, aliphatic hydrocarbon groups with 1 to 10 carbon atoms and having a volume calculated by the quantum chemistry calculation, of 170 to 500 .ANG..sup.3 and an electron density of oxygen atoms in the methoxy group, calculated similarly, ranging from 0.690 to 0.800 A. U. (atomic unit) or the volume in the range of 200 to 500 .ANG..sup.3 and the electron density in the range of 0.685 to 0.800 A. U.
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公开(公告)号：US4960743A
公开(公告)日：1990-10-02
申请号：US273397
申请日：1988-11-18
CPC分类号： C08F10/00
摘要： A method for the production of a catalyst carrier for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX [wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X stands for a halogen atom], and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n [wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M stands for a boron, carbon, aluminum, silicon, or phosphorus atom, R.sup.1 stands for a hydrocarbon group having 1 to 20 carbon atoms, and m stands for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied], to contact (D) a halogen-containing alcohol.
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公开(公告)号：US4950630A
公开(公告)日：1990-08-21
申请号：US273400
申请日：1988-11-18
CPC分类号： C08F10/00
摘要： A method for the production of a catalyst component for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX [wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X stands for a halogen atom], and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n [wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M stands for a boron, carbon, aluminum, silicon, or phosphorus atom, R.sup.1 stands for a hydrocarbon group having 1 to 20 carbon atoms, and m stands for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied], to contact (d) a halogen-containing alcohol and then contact (E) an electron donor type compound and (F) a titanium compound.
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公开(公告)号：US4942148A
公开(公告)日：1990-07-17
申请号：US256514
申请日：1988-10-12
CPC分类号： C08F10/00 , Y10S526/904
摘要： A catalyst component for olefin polymerization, prepared by bringing a titanium-containing solid which comprises (a) a metal oxide, (b) an organomagnesium compound represented by the following general formula:R.sup.1 MgR.sup.2wherein R.sup.1 and R.sup.2 each represents a hydrocarbon group containing from 1 to 20 carbon atoms, a halogen atom, or an OR.sup.3 group in which R.sup.3 represents a hydrocarbon group containing from 1 to 12 carbon atoms, provided that R.sup.1 and R.sup.2 do not represent a halogen atom at the same time, (c) an electron donor compound, and (d) a titanium compound having contacted with each other, into contact with (e) an .alpha.-olefin containing 3 carbon atoms or more in the presence of (f) an organoaluminum compound, to thereby contain a poly(.alpha.-olefin) in an amount of from 0.1 to 100 g per gram of said titanium-containing solid.
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6.发明授权Method for production of catalyst component for olefin polymerization (P-1292) 失效烯烃聚合催化剂组分的生产方法（P-1292）
公开(公告)号：US4814311A
公开(公告)日：1989-03-21
申请号：US132735
申请日：1987-12-14
CPC分类号： C08F10/00
摘要： A method for the production of a catalyst component for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX, wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X for a halogen atom, and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n, wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M for a boron, carbon, silicon, aluminum, or phosphorus atom, R.sup.1 for a hydrocarbon group having 1 to 20 carbon atoms, and m for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied, to contact (D) a halogen-containing alcohol and then contact (E) a titanium compound.
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7.发明授权
公开(公告)号：US4754006A
公开(公告)日：1988-06-28
申请号：US80736
申请日：1987-08-03
CPC分类号： C08F10/00
摘要： A process for producing catalyst ingredient for use in olefin polymerization which comprises contacting (A) a magnesium hydrocarbyloxide and (B) a silicon compound having hydrogen-silicon bonds in the presence of a hydrocarbon medium, contacting the thus obtained solid product with (C) a halogenated titanium compound in the presence or absence of a hydrocarbon medium and then adding to contact (D) an electron donating compound.
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公开(公告)号：US5130283A
公开(公告)日：1992-07-14
申请号：US635632
申请日：1991-01-07
申请人： Masahide Murata , Hiroyuki Furuhashi , Akira Nakano , Teruo Yashiro , Seizaburo Kanazawa , Masafumi Imai
发明人： Masahide Murata , Hiroyuki Furuhashi , Akira Nakano , Teruo Yashiro , Seizaburo Kanazawa , Masafumi Imai
CPC分类号： C08F10/00
摘要： According to the present invention, there is provided a catalyst component of metal oxide support type which has a high catalytic activity, that is, a little catalyst residue in a polymer, as well as improved catalytic grain strength sufficient for practical use and which hardly deteriorates even after storage for a long time. The catalyst component is obtained by contacting(a) a metal oxide with(b) a dihydrocarbyl magnesium, then contacting the resulting composition with(c) a compound represented by the general formula X.sup.1 .sub.n M(OR.sup.1).sub.m-n wherein X.sup.1 is a hydrogen atom, halogen atom or a hydrocarbon group of 1 to 20 carbon atoms, M is a boron, carbon, aluminum, silicon or phosphorus atom, R.sup.1 is a hydrocarbon group of 1 to 20 carbon atoms, m is the atomic valence of M and m>n.gtoreq.0, and(d) a titanium alkoxide represented by the general formula Ti(OR.sup.2).sub.4 wherein R.sup.2 is a hydrocarbon group of 1 to 12 carbon atoms, and then contacting the resulting solid with (e) an olefin in the presence of (f) an organoaluminum compound, then with (g) a halogen-containing alcohol and further with (h) an electron donating compound and (i) a titanium compound.
摘要翻译： PCT No.PCT / JP90 / 00632 Sec。 371日期1991年1月7日 102（e）日期1991年1月7日PCT提交1990年5月17日PCT公布。 WO90 / 14365 PCT公开号 日本1990年11月29日。根据本发明，提供了具有高催化活性的金属氧化物载体型催化剂组分，即聚合物中少量催化剂残余物，以及足够的催化剂颗粒强度 用于实际使用，并且即使在长时间储存后也几乎不劣化。 催化剂组分通过使（a）金属氧化物与（b）二烃基镁接触，然后使所得组合物与（c）由通式X1nM（OR1）mn表示的化合物接触，其中X1是氢原子， 卤原子或碳原子数1〜20的烃基，M为硼，碳，铝，硅或磷原子，R1为碳原子数1〜20的烃基，m为M的原子价，m> n > / = 0，和（d）由通式Ti（OR2）4表示的钛醇盐，其中R2是1至12个碳原子的烃基，然后在所存在的条件下使所得固体与（e）烯烃接触， （f）有机铝化合物，然后与（g）含卤素的醇进一步与（h）给电子化合物和（i）钛化合物反应。
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公开(公告)号：US4814312A
公开(公告)日：1989-03-21
申请号：US132751
申请日：1987-12-14
CPC分类号： C08F10/00
摘要： A method for the production of a catalyst component for use in the polymerization of an olefin, which method comprises causing a magnesium-containing solid obtained by contact of (A) magnesium metal, (B) a halogenated hydrocarbon represented by the general formula, RX [wherein R stands for an alkyl, aryl, or cycloalkyl group having 1 to 20 carbon atoms and X for a halogen atom], and (C) a compound of the general formula, X.sub.n.sup.1 M(OR.sup.1).sub.m-n [wherein X.sup.1 stands for a hydrogen atom, a halogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, M for a boron, carbon, silicon, aluminum, or phosphorus atom, R.sup.1 for a hydrocarbon group having 1 to 20 carbon atoms, and m for the valency of said atom M, providing that m>n.gtoreq.0 is satisfied], to contact (D) a halogen-containing alcohol and then contact (E) an electron donor type compound and (F) a titanium compound.
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10.发明授权
公开(公告)号：US4737481A
公开(公告)日：1988-04-12
申请号：US944103
申请日：1986-12-17
CPC分类号： C08F10/00
摘要： A process for producing catalyst ingredient for use in olefin polymerization which comprises contacting (A) a magnesium hydrocarbyloxide and (B) a silicon compound having hydrogen-silicon bonds in the presence of a hydrocarbon medium, contacting the thus obtained solid product (C) a halogenated titanium compound in the presence or absence of a hydrocarbon medium and then adding to contact (D) an electron donating compound.
摘要翻译： 一种用于生产用于烯烃聚合的催化剂成分的方法，其包括在烃介质存在下使（A）镁烃氧化物和（B）具有氢 - 硅键的硅化合物接触，使得到的固体产物（C）a 在存在或不存在烃介质的情况下将卤代钛化合物加入到接触（D）给电子化合物中。
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