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公开(公告)号：US5928502A
公开(公告)日：1999-07-27
申请号：US72763
申请日：1998-05-05
CPC分类号： C10G29/06
摘要： The invention comprises a method for reducing the amount of carboxylic acids in petroleum feeds comprising the steps of (a) adding to said petroleum feed a catalytic agent comprising an oil soluble or oil dispersible compound of a metal selected from the group consisting of Group VB, VIB, VIIB and VIII metals, wherein the amount of metal in said petroleum feed is at least about 5 wppm, (b) heating said petroleum feed with said catalytic agent in a reactor at a temperature of about 400 to about 800.degree. F. (about 204.44 to about 426.67.degree. C.) and a pressure of about atmospheric to about 1000 psig (about 6996.33 kPa) in the substantial absence of hydrogen, and (c) sweeping the reactor containing said petroleum feed and said catalytic agent with an inert gas to maintain the combined water and carbon dioxide partial pressure below about 50 psia (344.75 kPa).
摘要翻译： 本发明包括一种减少石油原料中羧酸含量的方法，包括以下步骤：（a）向所述石油原料中加入一种催化剂，该催化剂包含选自由VB组成的组的油溶性或油分散性金属化合物， VIB，VIIB和VIII族金属，其中所述石油原料中金属的量为至少约5wppm，（b）在反应器中在约400至约800°F的温度下用所述催化剂加热所述石油进料（ 约204.44至约426.67℃）和基本上不存在氢气的压力为约大气压至约1000psig（约6996.33kPa），和（c）用惰性气体吹扫含有所述石油进料和所述催化剂的反应器 以保持水分和二氧化碳的组合分压低于约50psia（344.75kPa）。
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公开(公告)号：US5891325A
公开(公告)日：1999-04-06
申请号：US132295
申请日：1998-08-11
CPC分类号： C10G31/06
摘要： The instant invention is directed to a process for reducing organic acids in petroleum feeds containing organic acids comprising: (a) thermally treating a petroleum feed containing organic acids in a thermal reaction zone comprising a plurality of stages in series, at a temperature and pressure sufficient to decompose at least a portion of said organic acids while sweeping said plurality of stages with an inert gas, to produce a volatile organic acid containing hydrocarbon fraction and a non-volatile hydrocarbon fraction; (b) treating said volatile hydrocarbon fraction to neutralize at least a portion of said organic acids therein and to produce a treated volatile hydrocarbon fraction; (c) collecting said non-volatile hydrocarbon fraction from said thermal reaction zone; and (d) blending said treated volatile hydrocarbon fraction of step (b) with said collected non-volatile hydrocarbon fraction.
摘要翻译： 本发明涉及一种用于还原含有机酸的石油进料中的有机酸的方法，包括：（a）在包括多个级的热反应区中含有有机酸的石油原料在足够的温度和压力下热处理 以在用惰性气体清扫所述多个阶段的同时分解至少一部分所述有机酸，以产生含有挥发性有机酸的烃馏分和非挥发性烃馏分; （b）处理所述挥发性烃馏分以中和其中的至少一部分所述有机酸并产生经处理的挥发性烃馏分; （c）从所述热反应区收集所述不挥发性烃馏分; 和（d）将所述经处理的步骤（b）的挥发性烃馏分与所收集的非挥发性烃馏分混合。
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公开(公告)号：US5914030A
公开(公告)日：1999-06-22
申请号：US72764
申请日：1998-05-05
摘要： The invention comprises a method for reducing the amount of carboxylic acids in petroleum feeds comprising the steps of (a) adding to said petroleum feed a catalytic agent comprising an oil soluble or oil dispersible compound of a metal selected from the group consisting of Group VB, VIB, VIIB and VIII metals, wherein the amount of metal in said petroleum feed is at least about 5 wppm, (b) heating said petroleum feed with said catalytic agent in a reactor at a temperature of about 400 to about 800.degree. F. (about 204.44 to about 426.67.degree. C.), under a hydrogen pressure of 15 psig to 1000 psig (204.75 to 6996.33 kPa), and (c) sweeping the reactor containing said petroleum feed and said catalytic agent with hydrogen-containing gas at a rate sufficient to maintain the combined water and carbon dioxide partial pressure below about 50 psia (about 344.75 kPa).
摘要翻译： 本发明包括一种减少石油原料中羧酸含量的方法，包括以下步骤：（a）向所述石油原料中加入一种催化剂，该催化剂包含选自由VB组成的组的油溶性或油分散性金属化合物， VIB，VIIB和VIII族金属，其中所述石油原料中金属的量为至少约5wppm，（b）在反应器中在约400至约800°F的温度下用所述催化剂加热所述石油进料（ 约204.44至约426.67℃），在15psig至1000psig（204.75至6996.33kPa）的氢气压力下，和（c）以含有气体的含有气体的速率将含有所述石油进料和所述催化剂的反应器 足以将合并的水和二氧化碳分压保持在约50psia（约344.75kPa）以下。
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公开(公告)号：US5820750A
公开(公告)日：1998-10-13
申请号：US785372
申请日：1997-01-17
CPC分类号： C10G31/06
摘要： Petroleum acids, e.g., naphthenic acids, are removed from crudes or crude fractions by thermal treatment.
摘要翻译： 通过热处理从石油或粗馏分中除去石油酸，例如环烷酸。
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5.发明授权Viscosity reduction by heat soak-induced naphthenic acid decomposition in hydrocarbon oils 失效在烃油中通过热浸泡诱导的环烷酸分解降低粘度
公开(公告)号：US5976360A
公开(公告)日：1999-11-02
申请号：US999869
申请日：1997-10-10
摘要： The viscosity of hydrocarbon feeds in reduced from crudes or crude by thermal treatment.
摘要翻译： 通过热处理从原油或原油中减少烃进料的粘度。
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6.发明授权
公开(公告)号：US5879529A
公开(公告)日：1999-03-09
申请号：US900388
申请日：1997-07-15
CPC分类号： C10G32/02
摘要： The present invention provides for a method of decreasing the Conradson carbon content of metal containing petroleum streams by forming a mixture of the Conradson carbon containing petroleum fraction and an aqueous electrolysis medium containing an electron transfer agent, and passing an electric current through the mixture or optionally through the pretreated aqueous electrolysis medium at a voltage, sufficient to decrease the Concarbon content of the stream. The cathodic voltage is from 0 V to -3.0 V vs. SCE. The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries.
摘要翻译： 本发明提供了一种通过形成含有Conradson碳的石油馏分和含有电子转移剂的水性电解介质的混合物并使电流通过混合物或任选地包含含金属石油流的Conradson碳含量的方法 通过预处理的含水电解介质，其电压足以降低流的碳含量。 阴极电压为0 V至-3.0 V，相对于SCE。 本发明提供了一种提高石油饲料价值的方法，该方法传统上在炼油厂中使用有限。
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公开(公告)号：US5855764A
公开(公告)日：1999-01-05
申请号：US900391
申请日：1997-07-15
CPC分类号： C10G32/02
摘要： The present invention provides for a method of decreasing the metals content of metal containing petroleum streams by forming a mixture of the petroleum fraction containing those metals and an aqueous electrolysis medium containing electron transfer agent, and passing an electric current through the mixture or through the pretreated aqueous electrolysis medium at a voltage, sufficient to remove the metals such as Ni, V and Fe from the stream (i.e. to produce a petroleum fraction having decreased content of the metals). The cathodic voltage is from 0 V to -3.0 V vs. SCE. The invention provides a method for enhancing the value of petroleum feeds that traditionally have limited use in refineries due to their metals, e.g., Ni and V content.
摘要翻译： 本发明提供一种通过形成含有这些金属的石油馏分和含有电子转移剂的含水电解介质的混合物并使电流通过混合物或通过预处理的方法来降低含金属的石油流的金属含量的方法 水电解介质，其电压足以从流中除去诸如Ni，V和Fe的金属（即，产生具有降低的金属含量的石油馏分）。 阴极电压为0 V至-3.0 V，相对于SCE。 本发明提供了一种增强石油饲料价值的方法，其传统上由于其金属，例如Ni和V含量在炼油厂中的使用受限。
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公开(公告)号：US06258258B1
公开(公告)日：2001-07-10
申请号：US09399650
申请日：1999-09-21
申请人： Guido Sartori , David William Savage , William Neergaard Olmstead , Winston Karl Robbins , David Craig Dalrymple , Bruce Henry Ballinger
发明人： Guido Sartori , David William Savage , William Neergaard Olmstead , Winston Karl Robbins , David Craig Dalrymple , Bruce Henry Ballinger
IPC分类号： C10G1700
摘要： The present invention is a process for decreasing the acidity of a starting acidic crude oil by contacting an acidic crude with an effective excess of ammonia dissolved in said crude to form an ammonia-continuous oil discontinuous phase at a temperature and conditions sufficient to form the corresponding amide of the naphthenic acids. The process is useful in the processing of acidic crudes.
摘要翻译： 本发明是通过使酸性粗品与溶解在所述粗品中的有效过量的氨接触以在足以形成相应的温度和条件的温度和条件下形成氨连续的油不连续相来降低起始酸性原油的酸度的方法 酰胺的环烷酸。 该方法在酸性原油的加工中是有用的。
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