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    Process for reducing total acid number of crude oil
    1.
    发明授权
    Process for reducing total acid number of crude oil 失效
    减少原油总酸值的方法

    公开(公告)号：US5928502A

    公开(公告)日：1999-07-27

    申请号：US72763

    申请日：1998-05-05

    申请人： Roby Bearden ,  Saul Charles Blum ,  William Neergaard Olmstead

    发明人： Roby Bearden ,  Saul Charles Blum ,  William Neergaard Olmstead

    IPC分类号： C10G29/06 ,  C10G17/00

    CPC分类号： C10G29/06

    摘要： The invention comprises a method for reducing the amount of carboxylic acids in petroleum feeds comprising the steps of (a) adding to said petroleum feed a catalytic agent comprising an oil soluble or oil dispersible compound of a metal selected from the group consisting of Group VB, VIB, VIIB and VIII metals, wherein the amount of metal in said petroleum feed is at least about 5 wppm, (b) heating said petroleum feed with said catalytic agent in a reactor at a temperature of about 400 to about 800.degree. F. (about 204.44 to about 426.67.degree. C.) and a pressure of about atmospheric to about 1000 psig (about 6996.33 kPa) in the substantial absence of hydrogen, and (c) sweeping the reactor containing said petroleum feed and said catalytic agent with an inert gas to maintain the combined water and carbon dioxide partial pressure below about 50 psia (344.75 kPa).

    摘要翻译： 本发明包括一种减少石油原料中羧酸含量的方法，包括以下步骤：（a）向所述石油原料中加入一种催化剂，该催化剂包含选自由VB组成的组的油溶性或油分散性金属化合物， VIB，VIIB和VIII族金属，其中所述石油原料中金属的量为至少约5wppm，（b）在反应器中在约400至约800°F的温度下用所述催化剂加热所述石油进料（ 约204.44至约426.67℃）和基本上不存在氢气的压力为约大气压至约1000psig（约6996.33kPa），和（c）用惰性气体吹扫含有所述石油进料和所述催化剂的反应器 以保持水分和二氧化碳的组合分压低于约50psia（344.75kPa）。

    Process for reducing total acid number of crude oil
    2.
    发明授权
    Process for reducing total acid number of crude oil 失效
    减少原油总酸值的方法

    公开(公告)号：US5891325A

    公开(公告)日：1999-04-06

    申请号：US132295

    申请日：1998-08-11

    申请人： Roby Bearden ,  Saul Charles Blum ,  William Neergaard Olmstead ,  Winston Karl Robbins

    发明人： Roby Bearden ,  Saul Charles Blum ,  William Neergaard Olmstead ,  Winston Karl Robbins

    IPC分类号： C10G53/12 ,  C10G19/073 ,  C10G31/06 ,  C10G55/04 ,  C10G17/00 ,  C10G19/02

    CPC分类号： C10G31/06

    摘要： The instant invention is directed to a process for reducing organic acids in petroleum feeds containing organic acids comprising: (a) thermally treating a petroleum feed containing organic acids in a thermal reaction zone comprising a plurality of stages in series, at a temperature and pressure sufficient to decompose at least a portion of said organic acids while sweeping said plurality of stages with an inert gas, to produce a volatile organic acid containing hydrocarbon fraction and a non-volatile hydrocarbon fraction; (b) treating said volatile hydrocarbon fraction to neutralize at least a portion of said organic acids therein and to produce a treated volatile hydrocarbon fraction; (c) collecting said non-volatile hydrocarbon fraction from said thermal reaction zone; and (d) blending said treated volatile hydrocarbon fraction of step (b) with said collected non-volatile hydrocarbon fraction.

    摘要翻译： 本发明涉及一种用于还原含有机酸的石油进料中的有机酸的方法，包括：（a）在包括多个级的热反应区中含有有机酸的石油原料在足够的温度和压力下热处理 以在用惰性气体清扫所述多个阶段的同时分解至少一部分所述有机酸，以产生含有挥发性有机酸的烃馏分和非挥发性烃馏分; （b）处理所述挥发性烃馏分以中和其中的至少一部分所述有机酸并产生经处理的挥发性烃馏分; （c）从所述热反应区收集所述不挥发性烃馏分; 和（d）将所述经处理的步骤（b）的挥发性烃馏分与所收集的非挥发性烃馏分混合。

    Process for reducing total acid number of crude oil
    4.
    发明授权
    Process for reducing total acid number of crude oil 失效
    减少原油总酸值的方法

    公开(公告)号：US5914030A

    公开(公告)日：1999-06-22

    申请号：US72764

    申请日：1998-05-05

    申请人： Roby Bearden ,  Saul Charles Blum ,  William Neergaard Olmstead

    发明人： Roby Bearden ,  Saul Charles Blum ,  William Neergaard Olmstead

    IPC分类号： C10G45/04 ,  C10G45/16 ,  C10G17/00

    CPC分类号： C10G45/16 ,  C10G45/04

    摘要： The invention comprises a method for reducing the amount of carboxylic acids in petroleum feeds comprising the steps of (a) adding to said petroleum feed a catalytic agent comprising an oil soluble or oil dispersible compound of a metal selected from the group consisting of Group VB, VIB, VIIB and VIII metals, wherein the amount of metal in said petroleum feed is at least about 5 wppm, (b) heating said petroleum feed with said catalytic agent in a reactor at a temperature of about 400 to about 800.degree. F. (about 204.44 to about 426.67.degree. C.), under a hydrogen pressure of 15 psig to 1000 psig (204.75 to 6996.33 kPa), and (c) sweeping the reactor containing said petroleum feed and said catalytic agent with hydrogen-containing gas at a rate sufficient to maintain the combined water and carbon dioxide partial pressure below about 50 psia (about 344.75 kPa).

    摘要翻译： 本发明包括一种减少石油原料中羧酸含量的方法，包括以下步骤：（a）向所述石油原料中加入一种催化剂，该催化剂包含选自由VB组成的组的油溶性或油分散性金属化合物， VIB，VIIB和VIII族金属，其中所述石油原料中金属的量为至少约5wppm，（b）在反应器中在约400至约800°F的温度下用所述催化剂加热所述石油进料（ 约204.44至约426.67℃），在15psig至1000psig（204.75至6996.33kPa）的氢气压力下，和（c）以含有气体的含有气体的速率将含有所述石油进料和所述催化剂的反应器 足以将合并的水和二氧化碳分压保持在约50psia（约344.75kPa）以下。