公开(公告)号：US20110071255A1

公开(公告)日：2011-03-24

申请号：US12989331

申请日：2009-04-14

申请人： Sayaka Ooike ,  Akinori Kitamura ,  Hiroshi Suzuki

发明人： Sayaka Ooike ,  Akinori Kitamura ,  Hiroshi Suzuki

IPC分类号： C09D183/07 ,  C08G77/20

CPC分类号： C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C09D183/04

摘要： The present curable composition comprises an organosilicon compound produced by hydrolysis copolycondensation of (A) a silicon compound R0Si(R1)nX13-n [wherein R0 represents a (meth)acryloyl group; and X1 represents a hydrolyzable group] and (B) a silicon compound SiY14 [wherein Y1 represents a siloxane-bond forming group] under an alkaline condition at a ratio of compound (A) to compound (B) of 1:(0.3 to 1.8) by mol. The present process for producing an organosilicon compound comprises a reaction process of conducting alcohol exchange reaction of a silicon compound. SiY24 [wherein Y2 represents a siloxane-bond forming group] in 1-propanol to produce a composition; and a condensation process of adding a silicon compound R0Si(R1)nX23-n [wherein R0 represents a (meth)acryloyl group; and X2 represents a hydrolyzable group] to the composition to perform the hydrolysis copolycondensation of the silicon compounds under alkaline conditions.

摘要翻译： 本固化性组合物包含通过（A）硅化合物R0Si（R1）nX13-n [其中R0表示（甲基）丙烯酰基的水解共缩聚而制备的有机硅化合物; X表示可水解基团]和（B）在化合物（A）与化合物（B）的比例为1：（0.3〜1.8）的条件下，在碱性条件下，硅化合物SiY14 [其中Y1表示硅氧烷键形成基团] ）。 本发明的有机硅化合物的制造方法包括进行硅化合物的醇交换反应的反应方法。 SiY24 [其中Y2表示硅氧烷键形成基]在1-丙醇中以产生组合物; 和加入硅化合物R0Si（R1）nX23-n [其中R0表示（甲基）丙烯酰基的缩合方法; X2表示水解性基团]，在碱性条件下进行硅化合物的水解共缩聚。

公开(公告)号：US08329774B2

公开(公告)日：2012-12-11

申请号：US12812808

申请日：2009-01-09

申请人： Sayaka Ooike ,  Hiroshi Suzuki ,  Akinori Kitamura

发明人： Sayaka Ooike ,  Hiroshi Suzuki ,  Akinori Kitamura

IPC分类号： C08J3/28 ,  C07F7/02 ,  C08G77/00 ,  B05D3/02

CPC分类号： C08G77/14 ,  C08G77/045 ,  C08L83/06

摘要： The object of the present invention is to provide an organosilicon compound having an oxetanyl group, which has a high proportion of an inorganic part in the structure, which, after production thereof, is stable with no gelling, and which has excellent storage stability when it is formed into a composition, and a production method thereof and a curable composition. The organosilicon compound is a compound having an oxetanyl group obtained by a method including a process in which a silicon compound A represented by the formula (1) and a silicon compound B having four siloxane bond-forming groups are subjected to hydrolysis and condensation at a ratio of 0.3 to 2.8 mol of silicon compound B based on 1 mol of silicon compound A. [In the formula, R0 is an organic group having an oxetanyl group, R1 is an alkyl group having 1 to 6 carbon atoms, an aralkyl group having 7 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, or an organic group having an oxetanyl group, X is a hydrolyzable group, and n is 0 or 1.]

摘要翻译： 本发明的目的是提供一种具有氧杂环丁烷基的有机硅化合物，其结构中无机部分的比例高，其生产稳定而没有胶化，并且当其具有优异的储存稳定性 形成组合物及其制备方法和可固化组合物。 有机硅化合物是通过包括以下方法获得的具有氧杂环丁烷基的化合物，其中将由式（1）表示的硅化合物A和具有四个硅氧烷键形成基团的硅化合物B在其中进行水解和缩合 比例为0.3〜2.8摩尔的硅化合物B，基于1摩尔的硅化合物A. [式中，R 0为具有氧杂环丁烷基的有机基团，R 1为碳原子数1〜6的烷基，具有 碳原子数为7〜10，碳原子数6〜10的芳基或氧杂环丁烷基的有机基团，X为水解性基团，n为0或1。

公开(公告)号：US08829142B2

公开(公告)日：2014-09-09

申请号：US12989331

申请日：2009-04-14

申请人： Sayaka Ooike ,  Akinori Kitamura ,  Hiroshi Suzuki

发明人： Sayaka Ooike ,  Akinori Kitamura ,  Hiroshi Suzuki

IPC分类号： C08G77/08 ,  C08G77/14 ,  C09D183/04 ,  C08G77/18 ,  C08G77/20

CPC分类号： C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C09D183/04

摘要： The present curable composition comprises an organosilicon compound produced by hydrolysis copolycondensation of (A) a silicon compound R0Si(R1)nX13-n [wherein R0 represents a (meth)acryloyl group; and X1 represents a hydrolyzable group] and (B) a silicon compound SiY14 [wherein Y1 represents a siloxane-bond forming group] under an alkaline condition at a ratio of compound (A) to compound (B) of 1:(0.3 to 1.8) by mol. The present process for producing an organosilicon compound comprises a reaction process of conducting alcohol exchange reaction of a silicon compound. SiY24 [wherein Y2 represents a siloxane-bond forming group] in 1-propanol to produce a composition; and a condensation process of adding a silicon compound R0Si(R1)nX23-n [wherein R0 represents a (meth)acryloyl group; and X2 represents a hydrolyzable group] to the composition to perform the hydrolysis copolycondensation of the silicon compounds under alkaline conditions.

摘要翻译： 本固化性组合物包含通过（A）硅化合物R0Si（R1）nX13-n [其中R0表示（甲基）丙烯酰基的水解共缩聚而制备的有机硅化合物; X表示可水解基团]和（B）在化合物（A）与化合物（B）的比例为1：（0.3〜1.8）的条件下，在碱性条件下，硅化合物SiY14 [其中Y1表示硅氧烷键形成基团] ）。 本发明的有机硅化合物的制造方法包括进行硅化合物的醇交换反应的反应方法。 SiY24 [其中Y2表示硅氧烷键形成基]在1-丙醇中以产生组合物; 和加入硅化合物R0Si（R1）nX23-n [其中R0表示（甲基）丙烯酰基的缩合方法; X2表示水解性基团]，在碱性条件下进行硅化合物的水解共缩聚。

公开(公告)号：US20110054063A1

公开(公告)日：2011-03-03

申请号：US12812808

申请日：2009-01-09

申请人： Sayaka Ooike ,  Hiroshi Suzuki ,  Akinori Kitamura

发明人： Sayaka Ooike ,  Hiroshi Suzuki ,  Akinori Kitamura

IPC分类号： C08G77/00 ,  C07F7/02 ,  B05D3/02

CPC分类号： C08G77/14 ,  C08G77/045 ,  C08L83/06

摘要： The object of the present invention is to provide an organosilicon compound having an oxetanyl group, which has a high proportion of an inorganic part in the structure, which, after production thereof, is stable with no gelling, and which has excellent storage stability when it is formed into a composition, and a production method thereof and a curable composition. The organosilicon compound is a compound having an oxetanyl group obtained by a method including a process in which a silicon compound A represented by the formula (1) and a silicon compound B having four siloxane bond-forming groups are subjected to hydrolysis and condensation at a ratio of 0.3 to 2.8 mol of silicon compound B based on 1 mol of silicon compound A. [In the formula, R0 is an organic group having an oxetanyl group, R1 is an alkyl group having 1 to 6 carbon atoms, an aralkyl group having 7 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, or an organic group having an oxetanyl group, X is a hydrolyzable group, and n is 0 or 1.]

摘要翻译： 本发明的目的是提供一种具有氧杂环丁烷基的有机硅化合物，其结构中无机部分的比例高，其生产稳定而没有胶化，并且当其具有优异的储存稳定性 形成组合物及其制备方法和可固化组合物。 有机硅化合物是通过包括以下方法获得的具有氧杂环丁烷基的化合物，其中将由式（1）表示的硅化合物A和具有四个硅氧烷键形成基团的硅化合物B在其中进行水解和缩合 比例为0.3〜2.8摩尔的硅化合物B，基于1摩尔的硅化合物A. [式中，R 0为具有氧杂环丁烷基的有机基团，R 1为碳原子数1〜6的烷基，具有 碳原子数为7〜10，碳原子数6〜10的芳基或氧杂环丁烷基的有机基团，X为水解性基团，n为0或1。