公开(公告)号：US08193272B2

公开(公告)日：2012-06-05

申请号：US12628258

申请日：2009-12-01

申请人： Seong Ho Kong ,  Sung Hee Ahn ,  Sung Duk Hwang ,  In Hwan Oh ,  Se Bum Son ,  Hye Jin Lee

发明人： Seong Ho Kong ,  Sung Hee Ahn ,  Sung Duk Hwang ,  In Hwan Oh ,  Se Bum Son ,  Hye Jin Lee

IPC分类号： C08K5/02 ,  C08K5/03

CPC分类号： C08K5/03 ,  C08K3/2279 ,  C08L51/04

摘要： The flame-retardant high impact vinyl aromatic resin composition of the present invention comprises (A) about 100 parts by weight of a rubber modified vinyl aromatic resin; (B) about 1 to about 30 parts by weight of a brominated diphenyl ethane mixture; and (C) about 1 to about 10 parts by weight of antimony oxide. The resin composition can have excellent fluidity as well as high impact strength and can provide a flame-retardant high impact vinyl aromatic resin composition having excellent workability and mechanical properties.

摘要翻译： 本发明的阻燃性高冲击性乙烯基芳香族树脂组合物包含（A）约100重量份的橡胶改性乙烯基芳香族树脂; （B）约1至约30重量份溴化二苯乙烷混合物; 和（C）约1至约10重量份的氧化锑。 树脂组合物可以具有优异的流动性和高的冲击强度，并且可以提供具有优异的可加工性和机械性能的阻燃性高冲击性乙烯基芳族树脂组合物。

公开(公告)号：US08354464B2

公开(公告)日：2013-01-15

申请号：US12632981

申请日：2009-12-08

申请人： Sung Hee Ahn ,  In Hwan Oh ,  Seong Ho Kong ,  Se Bum Son ,  Sung Duk Hwang ,  Hye Jin Lee

发明人： Sung Hee Ahn ,  In Hwan Oh ,  Seong Ho Kong ,  Se Bum Son ,  Sung Duk Hwang ,  Hye Jin Lee

IPC分类号： C08J5/02 ,  C07C22/00

CPC分类号： C09K21/08 ,  C07B39/00 ,  C07C17/12 ,  C08K5/03 ,  C07C25/18

摘要： A mixture of brominated diphenylethanes is prepared by brominating diphenylethanes, comprises hexabromodiphenylethane, heptabromodiphenylethane and octabromodiphenylethane, comprises about 55 to about 85% by weight hexabromodiphenylethane, and comprises about 0.01 to about 30% by weight diphenylethanes substituted with an odd number of bromines. The mixture of brominated diphenylethanes can provide improved compatibility with polymer resins, as well as impart excellent flame retardancy and improved weatherability and thermal stability.

摘要翻译： 溴化二苯乙烷的混合物是通过溴化二苯基乙烷，包括六溴二苯乙烷，七溴二苯基乙烷和八溴二苯基乙烷制备的，包含约55至约85重量％的六溴二苯乙烷，并且包含以奇数个溴取代的约0.01至约30重量％的二苯基乙烷。 溴化二苯乙烷的混合物可以提供改进的与聚合物树脂的相容性，并且赋予优异的阻燃性和改善的耐候性和热稳定性。

公开(公告)号：US08119720B2

公开(公告)日：2012-02-21

申请号：US12647620

申请日：2009-12-28

申请人： Se Bum Son ,  Sung Hee Ahn ,  Sung Duk Hwang ,  In Hwan Oh ,  Seong Ho Kong ,  Hye Jin Lee

发明人： Se Bum Son ,  Sung Hee Ahn ,  Sung Duk Hwang ,  In Hwan Oh ,  Seong Ho Kong ,  Hye Jin Lee

IPC分类号： C08K5/02

CPC分类号： C08L55/02 ,  C08K5/03 ,  C08K5/34924 ,  C08L25/12 ,  C08L67/02 ,  C08L2201/02 ,  C08L2205/03 ,  C08L2205/06 ,  C08L2666/02

摘要： A thermoplastic resin composition that can have improved flowability of the present invention comprises (A) about 1 to about 98% by weight of a functional group-containing vinyl copolymer resin reactive with polyester; (B) about 1 to about 98% by weight of an aromatic vinyl graft copolymer resin; (C) about 1 to about 98% by weight of a polyester resin; and (D) about 0.5 to about 30 parts by weight of a bromodiphenyl ethane mixture, based on the total weight of a base resin comprising (A), (B) and (C). The resin composition of the present invention can have flame retardancy, excellent impact resistance, and improved flowablity.

摘要翻译： 本发明可以具有改善的流动性的热塑性树脂组合物包含（A）约1至约98重量％的与聚酯反应的含官能团的乙烯基共聚物树脂; （B）约1至约98重量％的芳族乙烯基接枝共聚物树脂; （C）约1至约98重量％的聚酯树脂; 和（D）基于包含（A），（B）和（C）的基础树脂的总重量的约0.5至约30重量份的溴二苯基乙烷混合物。 本发明的树脂组合物可以具有阻燃性，优异的耐冲击性和改善的流动性。

公开(公告)号：US08329804B2

公开(公告)日：2012-12-11

申请号：US12613584

申请日：2009-11-06

申请人： In Hwan Oh ,  Sung Hee Ahn ,  Sung Duk Hwang ,  Se Bum Son ,  Seong Ho Kong ,  Hye Jin Lee

发明人： In Hwan Oh ,  Sung Hee Ahn ,  Sung Duk Hwang ,  Se Bum Son ,  Seong Ho Kong ,  Hye Jin Lee

IPC分类号： C08K5/02 ,  C08L25/00

CPC分类号： C09K21/08 ,  C08K5/03 ,  C08K5/3492 ,  C08L25/12 ,  C08L55/02 ,  C08L2666/24

摘要： A flame retardant thermoplastic resin composition comprises 100 parts by weight of a rubber-modified aromatic vinyl copolymer resin (A) and about 10 to about 30 parts by weight of a brominated diphenyl ethane mixture (B) including about 55 to about 85% by weight of hexabromodiphenyl ethane. The rubber modified aromatic vinyl copolymer resin (A) according to the present invention is a polymer resin wherein grafted rubbery polymers are dispersed in the form of particles in a matrix of vinyl copolymer. The rubber-modified aromatic vinyl copolymer resin (A) includes grafted rubbery polymers in an amount of about 10 to about 100% by weight and the matrix of vinyl copolymer in an amount of about 0 to about 90% by weight. The brominated diphenyl ethane mixture (B) may have about 1 to about 25% by weight of diphenyl ethane having an odd number of bromine substituents.

摘要翻译： 阻燃热塑性树脂组合物包含100重量份的橡胶改性的芳族乙烯基共聚物树脂（A）和约10至约30重量份的包含约55至约85重量％的溴化二苯乙烷混合物（B） 六溴二苯乙烷。 根据本发明的橡胶改性芳族乙烯基共聚物树脂（A）是其中接枝橡胶状聚合物以乙烯基共聚物基质中的颗粒形式分散的聚合物树脂。 橡胶改性的芳族乙烯基共聚物树脂（A）包括约10至约100重量％的接枝橡胶聚合物和约0至约90重量％的乙烯基共聚物基体。 溴化二苯乙烷混合物（B）可以具有约1至约25重量％的具有奇数个溴取代基的二苯基乙烷。

公开(公告)号：US09018312B2

公开(公告)日：2015-04-28

申请号：US11965013

申请日：2007-12-27

申请人： Se Bum Son ,  Sung Hee Ahn ,  In Hwan Oh ,  Sung Duk Hwang

发明人： Se Bum Son ,  Sung Hee Ahn ,  In Hwan Oh ,  Sung Duk Hwang

IPC分类号： C08K5/02 ,  C08K5/136 ,  C08K5/06 ,  C08K3/10 ,  B29D22/00 ,  C08L55/02 ,  C08F279/02 ,  C08F279/04 ,  C08L25/12 ,  C08L51/04 ,  C08L63/00 ,  C08L67/02 ,  C08K3/22 ,  C08K5/03 ,  C08L83/04

CPC分类号： C08L55/02 ,  C08F279/02 ,  C08F279/04 ,  C08K3/2279 ,  C08K5/03 ,  C08K5/06 ,  C08L25/12 ,  C08L51/04 ,  C08L63/00 ,  C08L67/02 ,  C08L83/04 ,  Y10T428/1397 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14

摘要： A thermoplastic resin composition with improved impact resistance can include (A) about 30 to about 99 parts by weight of an epoxy group-containing styrenic polymer comprising (A1) about 5 to about 100% by weight of an epoxy group-containing vinyl copolymer containing about 0.001 to about 5.0 mol % of an epoxy compound; and (A2) about 0 to about 95% by weight of a rubber modified styrenic copolymer resin; (B) about 1 to about 70 parts by weight of a polyester resin; (C) about 0.001 to about 10 parts by weight of a silicone oil, per 100 parts by weight of a base resin comprising (A) and (B); (D) about 3 to about 20 parts by weight of a bromine-containing flame retardant, per 100 parts by weight of a base resin comprising (A) and (B); and (E) about 0.1 to about 6 parts by weight of a flame retardant aid, per 100 parts by weight of a base resin comprising (A) and (B).

摘要翻译： 具有改善的耐冲击性的热塑性树脂组合物可包括（A）约30至约99重量份的含环氧基的苯乙烯聚合物，其包含（A1）约5至约100重量％的含环氧基的乙烯基共聚物，其含有 约0.001至约5.0mol％的环氧化合物; 和（A2）约0至约95重量％的橡胶改性的苯乙烯共聚物树脂; （B）约1至约70重量份的聚酯树脂; （C）每100重量份包含（A）和（B）的基础树脂，约0.001至约10重量份的硅油; （D）每100重量份包含（A）和（B）的基础树脂约3至约20重量份的含溴阻燃剂; 和（E）每100重量份包含（A）和（B）的基础树脂约0.1至约6重量份的阻燃助剂。

公开(公告)号：US07981960B2

公开(公告)日：2011-07-19

申请号：US12037123

申请日：2008-02-26

申请人： Sung Hee Ahn ,  Se Bum Son ,  In Hwan Oh ,  Sung Duk Hwang

发明人： Sung Hee Ahn ,  Se Bum Son ,  In Hwan Oh ,  Sung Duk Hwang

IPC分类号： C08L63/00 ,  C08K5/05

CPC分类号： C08G59/3209 ,  C08K3/2279 ,  C08K5/02 ,  C08K5/06 ,  C08K5/3492 ,  C08L51/04 ,  C08L63/00 ,  C08L67/00 ,  C08L2666/02

摘要： A thermoplastic resin composition can include (A) about 30 to about 99 parts by weight of an epoxy group-containing styrenic polymer comprising (A1) about 5 to about 100% by weight of an epoxy group-containing vinyl copolymer and (A2) about 0 to about 95% by weight of a rubber modified styrenic copolymer resin; and (B) about 1 to about 70 parts by weight of a polyester resin. The resin composition may further comprise (C) about 3 to about 20 parts by weight of a bromine-containing flame retardant, per 100 parts by weight of a base resin comprising (A) and (B); and (D) about 0.1 to about 6 parts by weight of a flame retardant aid, per 100 parts by weight of a base resin comprising (A) and (B).

摘要翻译： 热塑性树脂组合物可包含（A）约30至约99重量份的含环氧基的苯乙烯聚合物，其包含（A1）约5至约100重量％的含环氧基乙烯基共聚物和（A2）约 0至约95重量％的橡胶改性的苯乙烯共聚物树脂; 和（B）约1至约70重量份的聚酯树脂。 相对于100重量份的包含（A）和（B）的基础树脂，树脂组合物还可以包含（C）约3至约20重量份的含溴阻燃剂。 和（D）每100重量份包含（A）和（B）的基础树脂约0.1至约6重量份的阻燃助剂。

公开(公告)号：US07977421B2

公开(公告)日：2011-07-12

申请号：US12512134

申请日：2009-07-30

申请人： Sung Hee Ahn ,  Se Bum Son ,  In Hwan Oh ,  Sung Duk Hwang ,  Seong Ho Kong ,  Hye Jin Lee ,  Jin Pyung Jeong

发明人： Sung Hee Ahn ,  Se Bum Son ,  In Hwan Oh ,  Sung Duk Hwang ,  Seong Ho Kong ,  Hye Jin Lee ,  Jin Pyung Jeong

IPC分类号： C08K5/03

CPC分类号： C09K21/08 ,  C08K5/03 ,  C08K2201/014

摘要： A brominated diphenyl ethane mixture of the present invention comprises about 0 to about 2% by weight of pentabromodiphenyl ethane, about 55 to 85% by weight of hexabromodiphenyl ethane, about 1 to 20% by weight of heptabromodiphenyl ethane, about 1 to 25% by weight of octabromodiphenyl ethane, about 0 to about 10% by weight of nonabromodiphenyl ethane, and about 0 to about 5% by weight of decabromodephenyl ethane. The brominated diphenyl ethane mixture can be added to thermoplastic resin as a flame retardant, can exhibit excellent compatibility with thermoplastic resins, can minimize the generation of environmental problems, and can obtain excellent impact resistance, thermal stability, weatherability and flowability as well as improved flame resistance.

摘要翻译： 本发明的溴化二苯乙烷混合物包含约0至约2重量％的五溴二苯基乙烷，约55至约85重量％的六溴代二苯基乙烷，约1至约20重量％的七溴代二苯基乙烷，约1至约 25重量％的八溴代二苯基乙烷，约0至约10重量％的非溴二苯乙烷和约0至约5重量％的十溴二苯乙烷。 溴化二苯乙烷混合物可以作为阻燃剂添加到热塑性树脂中，可以显示出与热塑性树脂的良好相容性，可以最小化环境问题的产生，并且可以获得优异的耐冲击性，热稳定性，耐候性和流动性以及改进的火焰 抵抗性。

公开(公告)号：US07964661B2

公开(公告)日：2011-06-21

申请号：US12538266

申请日：2009-08-10

申请人： Se Bum Son ,  Sung Hee Ahn ,  In Hwan Oh ,  Sung Duk Hwang

发明人： Se Bum Son ,  Sung Hee Ahn ,  In Hwan Oh ,  Sung Duk Hwang

IPC分类号： C08K3/10 ,  C08K5/00

CPC分类号： C08L25/14 ,  C08K3/2279 ,  C08K5/03 ,  C08K5/06 ,  C08K5/3492 ,  C08K13/02 ,  C08L55/02 ,  C08L67/02 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/02

摘要： A flame resistant thermoplastic resin composition having improved impact resistance and chemical resistance is provided. The flame resistant thermoplastic resin composition includes about 100 parts by weight of a base resin; about 3 to about 20 parts by weight of a halogen-containing flame retardant (C); and about 0.1 to about 6 parts by weight of an antimony-containing flame retarding aid (D). The base resin includes about 20 to about 99% by weight of an epoxy group-containing rubber modified aromatic vinyl based resin (A) comprising about 1 to about 99% by weight of an epoxy-containing rubber modified aromatic vinyl based copolymer (Al), about 1 to about 99% by weight of an epoxy-containing vinyl copolymer (A2), and about 0 to about 98% by weight of an aromatic vinyl based copolymer (A3), and about 1 to about 80% by weight of a polyester resin (B).

摘要翻译： 提供了具有改进的耐冲击性和耐化学性的阻燃热塑性树脂组合物。 阻燃热塑性树脂组合物包含约100重量份的基础树脂; 约3至约20重量份的含卤阻燃剂（C）; 和约0.1至约6重量份的含锑阻燃助剂（D）。 基础树脂包括约20至约99重量％的含环氧基橡胶改性芳族乙烯基系树脂（A），其包含约1至约99重量％的含环氧橡胶改性的芳族乙烯基共聚物（Al） ，约1至约99重量％的含环氧乙烯基共聚物（A2）和约0至约98重量％的芳族乙烯基类共聚物（A3）和约1至约80重量％的 聚酯树脂（B）。

公开(公告)号：US08334332B2

公开(公告)日：2012-12-18

申请号：US12884576

申请日：2010-09-17

申请人： Se Bum Son ,  Sung Hee Ahn ,  In Hwan Oh

发明人： Se Bum Son ,  Sung Hee Ahn ,  In Hwan Oh

IPC分类号： C08K3/10 ,  C08K5/00

CPC分类号： C08L33/12 ,  C08K3/2279 ,  C08K5/03 ,  C08L19/00 ,  C08L55/02 ,  C08L2201/02

摘要： A flame-retardant thermoplastic resin composition that can have excellent color tone according to the present invention comprises a base resin comprising (A) about 50 to about 99% by weight of a rubber modified aromatic vinyl resin; and (B) about 1 to about 50% by weight of an acryl resin; and further comprising (C) about 1 to about 30 parts by weight of a bromodiphenyl ethane mixture, based on about 100 parts by weight of the base resin comprising (A) and (B); and (D) about 1 to about 10 parts by weight of an antimony oxide, based on about 100 parts by weight of the base resin comprising (A) and (B). The resin composition of the present invention can have improved physical properties and color properties as well as flame resistance.

摘要翻译： 根据本发明可以具有优异色调的阻燃热塑性树脂组合物包括基础树脂，其包含（A）约50至约99重量％的橡胶改性芳族乙烯基树脂; 和（B）约1至约50重量％的丙烯酸树脂; 并且还包含基于约100重量份的包含（A）和（B）的基础树脂的（C）约1至约30重量份的溴二苯乙烷混合物; 和（D）基于约100重量份的包含（A）和（B）的基础树脂，约1至约10重量份的氧化锑。 本发明的树脂组合物可以具有改善的物理性能和颜色特性以及耐火性。