公开(公告)号：US08008375B2

公开(公告)日：2011-08-30

申请号：US11989798

申请日：2007-05-23

申请人： Seung-Yeop Kwak ,  Sang-Jae Jung ,  Jae-Woo Chung

发明人： Seung-Yeop Kwak ,  Sang-Jae Jung ,  Jae-Woo Chung

IPC分类号： C08B37/00 ,  C08L3/02 ,  C08L5/16 ,  C08L5/00 ,  A61K8/73 ,  C08F251/02

CPC分类号： C08F14/06 ,  C08F2/20

摘要： The present invention relates to a PVC product containing cyclodextrin derivative particles and capable of suppressing migration of a plasticizer and a method for manufacturing the same, which includes (S1) preparing cyclodextrin derivative particles, in which a hydroxyl functional group is replaced by a predetermined compound; (S2) inputting the cyclodextrin derivative particles, a water-based dispersion medium and a vinyl chloride monomer into a high-pressure reactor and performing polymerization to obtain cyclodextrin derivative particles-capsulated PVC particles, in which a plurality of the cyclodextrin derivative particles are dispersedly capsulated in PVC particles; and (S3) mixing the cyclodextrin derivative particles-capsulated PVC particles with a low molecular weight liquid plasticizer and molding the mixture in a predetermined shape using heat.

摘要翻译： 本发明涉及含有环糊精衍生物颗粒并能够抑制增塑剂迁移的PVC产品及其制造方法，其包括（S1）制备环糊精衍生物颗粒，其中羟基官能团被预定的化合物 ; （S2）将环糊精衍生物颗粒，水性分散介质和氯乙烯单体输入到高压反应器中并进行聚合，得到分散有多个环糊精衍生物颗粒的环糊精衍生物颗粒包封的PVC颗粒 封装在PVC颗粒中; 和（S3）将环糊精衍生物颗粒包覆的PVC颗粒与低分子量液体增塑剂混合，并使用热量将该混合物成型为预定形状。

公开(公告)号：US20100092376A1

公开(公告)日：2010-04-15

申请号：US11989631

申请日：2007-05-29

申请人： Seung-Yeop Kwak ,  Jae-Woo Chung

发明人： Seung-Yeop Kwak ,  Jae-Woo Chung

IPC分类号： C01G23/053

CPC分类号： C01G23/047 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

摘要： A method is provided for manufacturing porous titanium dioxide with uniform pore sizes within several nanometers by means of a template and a titanium precursor. In this method, a cyclodextrin or cyclodextrin derivative is used as a template for forming pores, and the cyclodextrin or then derivative reacts with the titanium precursor in a sulfuric acid solution. The manufacturing method according to the present invention allows the control of pore size and morphology using various kinds of cyclodextrin or cyclodextrin derivatives, supports a facile removal of the cyclodextrin used as the template, and is capable of manufacturing anatase type porous titanium dioxide with excellent photoactivity without a separate sintering process.

摘要翻译： 提供了一种通过模板和钛前体制造在几纳米内具有均匀孔径的多孔二氧化钛的方法。 在该方法中，使用环糊精或环糊精衍生物作为形成孔的模板，并且环糊精或其衍生物与硫酸溶液中的钛前体反应。 根据本发明的制造方法允许使用各种环糊精或环糊精衍生物控制孔径和形态，支持轻松去除用作模板的环糊精，并且能够制备具有优异光活性的锐钛矿型多孔二氧化钛 没有单独的烧结过程。

公开(公告)号：US20080200592A1

公开(公告)日：2008-08-21

申请号：US12011837

申请日：2008-01-29

申请人： Seung-Yeop Kwak ,  Byong-Yong Yu ,  Jae-Woo Chung

发明人： Seung-Yeop Kwak ,  Byong-Yong Yu ,  Jae-Woo Chung

IPC分类号： C08L5/16

CPC分类号： C08L27/06 ,  C08K5/0016 ,  C08L5/16 ,  C08L2666/26

摘要： The present invention relates to a plasticizer composition containing cyclodextrin derivatives, a flexible PVC composition with suppression of the migration of plasticizer containing this plasticizer composition, and a manufacturing method of the PVC composition. The manufacturing method includes the steps of: (S1) preparing a cyclodextrin derivative, in which hydrogens of a cyclodextrin are substituted with a certain compound; (S2) mixing the cyclodextrin derivative, PVC and a low molecular weight liquid plasticizer to form a plastisol; and (S3) heating the plastisol into liquid and cooling the plastisol. This manufacturing method uses cyclodextrin derivatives, in which cyclodextrins are modified with certain compounds, and these derivatives form a complex with the low molecular weight liquid plasticizer to suppress plasticizer migration. Thus, this method thereby allows mass-production of the flexible PVC with suppressed plasticizer migration in a simple and economical manner without using a solvent.

摘要翻译： 本发明涉及含有环糊精衍生物的增塑剂组合物，抑制含有该增塑剂组合物的增塑剂的迁移的柔性PVC组合物，以及PVC组合物的制造方法。 制造方法包括以下步骤：（S1）制备环糊精衍生物，其中环糊精的氢被某种化合物取代; （S2）混合环糊精衍生物，PVC和低分子量液体增塑剂以形成增塑溶胶; 和（S3）将增塑溶胶加热成液体并冷却增塑溶胶。 该制造方法使用环糊精衍生物，其中环糊精被某些化合物改性，并且这些衍生物与低分子量液体增塑剂形成复合物以抑制增塑剂迁移。 因此，该方法可以在不使用溶剂的情况下以简单且经济的方式批量生产具有抑制的增塑剂迁移的柔性PVC。

公开(公告)号：US20090286908A1

公开(公告)日：2009-11-19

申请号：US11989798

申请日：2007-05-23

申请人： Seung-Yeop Kwak ,  Sang-Jae Jung ,  Jao-Woo Chung

发明人： Seung-Yeop Kwak ,  Sang-Jae Jung ,  Jao-Woo Chung

IPC分类号： C08L5/16 ,  B29C51/00

CPC分类号： C08F14/06 ,  C08F2/20

摘要： The present invention relates to a PVC product containing cyclodextrin derivative particles and capable of suppressing migration of a plasticizer and a method for manufacturing the same, which includes (S1) preparing cyclodextrin derivative particles, in which a hydroxyl functional group is replaced by a predetermined compound; (S2) inputting the cyclodextrin derivative particles, a water-based dispersion medium and a vinyl chloride monomer into a high-pressure reactor and performing polymerization to obtain cyclodextrin derivative particles-capsulated PVC particles, in which a plurality of the cyclodextrin derivative particles are dispersedly capsulated in PVC particles; and (S3) mixing the cyclodextrin derivative particles-capsulated PVC particles with a low molecular weight liquid plasticizer and molding the mixture in a predetermined shape using heat.

摘要翻译： 本发明涉及含有环糊精衍生物颗粒并能够抑制增塑剂迁移的PVC产品及其制造方法，其包括（S1）制备环糊精衍生物颗粒，其中羟基官能团被预定的化合物 ; （S2）将环糊精衍生物颗粒，水性分散介质和氯乙烯单体输入到高压反应器中并进行聚合，得到分散有多个环糊精衍生物颗粒的环糊精衍生物颗粒包封的PVC颗粒 封装在PVC颗粒中; 和（S3）将环糊精衍生物颗粒包覆的PVC颗粒与低分子量液体增塑剂混合，并使用热量将该混合物成型为预定形状。

公开(公告)号：US06747092B2

公开(公告)日：2004-06-08

申请号：US10001205

申请日：2001-12-04

申请人： Seung-Yeop Kwak ,  Jeong-Soo Choi

发明人： Seung-Yeop Kwak ,  Jeong-Soo Choi

IPC分类号： C08L2706

CPC分类号： C08K5/10 ,  C08L27/06 ,  C08L67/02 ,  C08L2666/14

摘要： The present invention discloses aliphatic polyester compound having highly branched structure for polyvinylchloride plasticizer and polyvinylchloride blend containing the same. Aliphatic polyester compound having highly branched structure for polyvinylchloride plasticizer according to the present invention is formed by self-condensation polymerization of monomer having one carboxy functional group and two hydroxy functional groups. Since such aliphatic polyester having highly branched structure has superior compatibility with polyvinylchloride and never flows out contrary to the conventional liquid plasticizer having low molecular weight of phthalate, etc., the problems such as the disturbance of endocrine system of human body and the destruction of ecosystem due to the efflux of plasticizer is not caused and since the same has superior efficiency of plasticization, it is possible to give polyvinylchloride sufficient flexibility.

摘要翻译： 本发明公开了具有高分支结构的聚氯乙烯增塑剂和含有它们的聚氯乙烯共混物的脂族聚酯化合物。 通过具有一个羧基官能团和两个羟基官能团的单体的自缩聚形成本发明的聚氯乙烯增塑剂具有高支化结构的脂肪族聚酯化合物。 由于这种具有高支化结构的脂肪族聚酯与聚氯乙烯具有优异的相容性，并且不会与常规的邻苯二甲酸酯等分子量低的液体增塑剂相反地流出，所以诸如人体内分泌系统的紊乱和生态系统的破坏等问题 由于不会引起增塑剂的流出，并且由于具有优异的增塑效果，因此可以赋予聚氯乙烯足够的柔韧性。

公开(公告)号：US07884152B2

公开(公告)日：2011-02-08

申请号：US11989630

申请日：2007-05-23

申请人： Seung-Yeop Kwak ,  Se-Bum Son ,  Sang-Wook Chun

发明人： Seung-Yeop Kwak ,  Se-Bum Son ,  Sang-Wook Chun

IPC分类号： C08K3/34

CPC分类号： C08J5/005 ,  B82Y30/00 ,  C08J2367/02

摘要： The present invention relates to a manufacturing method of organic modifier-free exfoliated nano clay-polymer composite. The manufacturing method of organic modifier-free exfoliated nano clay-polymer composite includes (S1) dispersing layered clay nanoparticles and dissolving a thermoplastic polymer in an acidic solvent; (S2) adding the product of step (S1) to a polymer non-solvent incapable of dissolving the polymer, but capable of dissolving the organic modifier separated from the organized layered clay nanoparticles; and (S3) separating an organic modifier-free exfoliated nano clay-polymer composite from the product of step (S2). The inventive manufacturing method can maximally improve the physical properties of composites through the addition of the exfoliated clay nanoparticles by removing the organic modifier that may deteriorate physical properties of the composite from the exfoliated clay nanoparticles dispersed therein.

摘要翻译： 本发明涉及不含有机改性剂的剥离纳米粘土 - 聚合物复合材料的制造方法。 无机改性纳米粘土 - 聚合物复合材料的制造方法包括（S1）分散层状粘土纳米粒子并将热塑性聚合物溶解在酸性溶剂中; （S2）将步骤（S1）的产物加入到不能溶解聚合物的聚合物非溶剂中，但能够溶解从有组织的层状粘土纳米颗粒分离的有机改性剂; 和（S3）从步骤（S2）的产物中分离出不含有机改性剂的剥离的纳米粘土 - 聚合物复合材料。 本发明的制造方法可以通过除去可能劣化复合材料从其中分散的剥离粘土纳米粒子的物理性质的有机改性剂，最大限度地改善复合材料的物理性能。

公开(公告)号：US5593588A

公开(公告)日：1997-01-14

申请号：US569903

申请日：1995-12-08

申请人： Jae-Jin Kim ,  Chang-Keun Kim ,  Seung-Yeop Kwak

发明人： Jae-Jin Kim ,  Chang-Keun Kim ,  Seung-Yeop Kwak

IPC分类号： B01D69/12 ,  B01D71/48 ,  B01D71/56 ,  B01D29/00

CPC分类号： B01D69/125 ,  B01D71/48 ,  B01D71/76 ,  B01D71/56

摘要： A composite reverse osmosis membrane may advantageously be prepared by the process comprising applying porous support layer onto a nonwoven fabric and then forming an ultrathin active layer of an aromatic polyester superposed thereon, the active layer being prepared by the interfacial polymerization of an aqueous solution of polyhydric phenol and a solution of aromatic acyl halide dissolved in an organic solvent; or applying a porous support layer onto a nonwoven fabric and then forming an ultrathin active layer of a copolymer of aromatic polyester and aromatic polyamide superposed thereon, the active layer being prepared by the interfacial polymerization of a mixed aqueous solution of polyhydric phenol and an aromatic amine with a solution of aromatic acyl halide dissolved in an organic solvent. The composite membrane of the present invention has improvements in properties, such as water-permeability, chlorine-resistance, oxidation stability, salt rejection rate, and durability.

摘要翻译： 复合反渗透膜可有利地通过以下方法制备，该方法包括在无纺织物上施加多孔支撑层，然后形成叠置在其上的芳族聚酯的超薄活性层，活性层通过多元醇水溶液的界面聚合制备 苯酚和溶解在有机溶剂中的芳族酰卤的溶液; 或将多孔支撑层施加到无纺织物上，然后形成叠置在其上的芳族聚酯和芳族聚酰胺的共聚物的超薄活性层，活性层通过多元酚和芳族胺的混合水溶液的界面聚合制备 与芳族酰基卤溶解在有机溶剂中的溶液。 本发明的复合膜具有透水性，耐氯性，氧化稳定性，耐盐析性和耐久性等性能的改善。

公开(公告)号：US20090281214A1

公开(公告)日：2009-11-12

申请号：US12086037

申请日：2005-12-07

申请人： Seung-Yeop Kwak ,  Sung-Ho Kim ,  Seok-Bong Lee

发明人： Seung-Yeop Kwak ,  Sung-Ho Kim ,  Seok-Bong Lee

IPC分类号： C08L3/02 ,  C09K3/00

CPC分类号： C08F14/06 ,  C08J3/18 ,  C08J2327/06 ,  C08L5/16 ,  C08L27/06 ,  C08F2/00 ,  C08L2666/26

摘要： Disclosed are plasticizer compositions including cyclodextrin derivatives, a flexible PVC composition with suppression of the migration of a plasticizer containing the same, and a manufacturing method thereof. The manufacturing method of the flexible PVC composition of the present invention includes steps of (S1) preparing cyclodextrin derivatives; (S2) mixing the cyclodextrin derivatives, PVC and a low molecular weight liquid plasticizer to form a plastisol; and (S3) heating the plastisol to form a solution and cooling the solution. The manufacturing method of the present invention may be useful to mass-produce flexible PVC with suppression of the migration of a plasticizer in a simple and economic manner without using solvents since the cyclodextrin derivatives are used as a compound that can suppress the migration of a plasticizer The flexible PVC has an effect of reducing an amount of the migrated plasticizer without deterioration in its physical properties.

摘要翻译： 公开了包含环糊精衍生物的增塑剂组合物及其制备方法，该组合物抑制含有该增塑剂的增塑剂的迁移。 本发明的柔性PVC组合物的制造方法包括（S1）制备环糊精衍生物的步骤; （S2）混合环糊精衍生物，PVC和低分子量液体增塑剂以形成增塑溶胶; 和（S3）加热增塑溶胶以形成溶液并冷却溶液。 本发明的制造方法可用于大量生产柔性PVC，同时以简单经济的方式抑制增塑剂的迁移而不使用溶剂，因为环糊精衍生物可用作可抑制增塑剂迁移的化合物 柔性PVC具有减少迁移的增塑剂的量而不降低其物理性能的效果。

公开(公告)号：US07468226B2

公开(公告)日：2008-12-23

申请号：US10590728

申请日：2005-02-26

申请人： Seung-Yeop Kwak ,  Jae-Deok Jeon

发明人： Seung-Yeop Kwak ,  Jae-Deok Jeon

IPC分类号： H01M10/40

CPC分类号： H01M10/0525 ,  H01M10/0565 ,  Y02T10/7011

摘要： A solvent-free polymer electrolyte and a secondary battery employing the electrolyte are provided. The electrolyte includes: a porous film, including a first polymer and a second oligomer, the first polymer being at least one selected from the group consisting of poly (vinylidene fluoride-co-hexafluoropropylene) copolymers, polyvinylidenefluorides, polymethylmethacrylates, polyacrylonitriles, polyethyleneoxides, and celluloses having a polyether chain, and the second oligomer being at least one selected from the group consisting of poly(ethylene oxide-co-ethylene carbonate) copolymers with at least one terminal groups substituted by a halogen atom and polyethyleneglycols with at least one terminal group substituted by a halogen atom. An electrolyte comprising the second oligomer and a lithium salt is present in the pores of the porous film.

摘要翻译： 提供无溶剂的聚合物电解质和使用电解质的二次电池。 所述电解质包括：多孔膜，包括第一聚合物和第二低聚物，所述第一聚合物是选自聚偏二氟乙烯 - 共 - 六氟丙烯共聚物，聚偏二氟乙烯，聚甲基丙烯酸甲酯，聚丙烯腈，聚氧化乙烯和 具有聚醚链的纤维素，并且所述第二低聚物是选自具有至少一个被卤素原子取代的末端基的聚（环氧乙烷 - 碳酸亚乙酯）共聚物和至少一个末端基团的聚乙二醇中的至少一种 被卤素原子取代。 包含第二低聚物和锂盐的电解质存在于多孔膜的孔中。

公开(公告)号：US20080038642A1

公开(公告)日：2008-02-14

申请号：US10590728

申请日：2005-02-26

申请人： Seung-Yeop Kwak ,  Jae-Deok Jeon

发明人： Seung-Yeop Kwak ,  Jae-Deok Jeon

IPC分类号： H01M6/18

CPC分类号： H01M10/0525 ,  H01M10/0565 ,  Y02T10/7011

摘要： Provided are a solvent-free polymer electrolyte and a secondary battery employing the same. The solvent-free polymer electrolyte includes: a porous film including a first polymer and a second oligomer, the first the group consisting of poly(vinylidene fluoride-co-hexafluoropropylene) copolymers, polyvinylidenefluorides, polymethylmethacrylates, polyacry-lonitriles, polyethyleneoxides, and celluloses having a polyether chain and the second oligomer being at least one selected from the group consisting of poly(ethylene oxide-co-ethylene carbonate) copolymers with at least one terminal groups substituted by a halogen atom and polyethyleneglycols with at least one terminal groups substituted by a halogen atom; and an electrolyte present in the pores of the porous film and including the second oligomer and a lithium salt. Since the solvent-free polymer electrolyte contains no liquid organic electrolyte, it is not accompanied by problems caused by leakage or evaporation of an organic solvent, unlike a gel-type polymer electrolyte. Furthermore, the solvent-free polymer electrolyte has enhanced ionic conductivity as compared to a conventional solvent-free polymer electrolyte.

摘要翻译： 提供无溶剂的聚合物电解质和使用其的二次电池。 无溶剂的聚合物电解质包括：包含第一聚合物和第二低聚物的多孔膜，第一种是由聚（偏二氟乙烯 - 共 - 六氟丙烯）共聚物，聚偏二氟乙烯，聚甲基丙烯酸甲酯，聚丙烯腈，聚氧乙烯醚和纤维素组成的组， 聚醚链，所述第二低聚物是选自具有至少一个被卤素原子取代的末端基团的聚（环氧乙烷 - 碳酸亚乙酯）共聚物和至少一个被一个被卤素原子取代的末端基团的聚乙二醇组成的组中的至少一种 卤素原子; 以及存在于多孔膜的孔中并包含第二低聚物和锂盐的电解质。 由于无溶剂的聚合物电解质不含有液体有机电解质，因此与凝胶型聚合物电解质不同，不伴随有机溶剂的泄漏或蒸发引起的问题。 此外，与常规的无溶剂聚合物电解质相比，无溶剂的聚合物电解质具有增强的离子电导率。