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1.发明授权Solid polymeric substrate having adherent resin component derived from curable silylated polyurethane composition 有权具有衍生自可固化甲硅烷基化聚氨酯组合物的粘合树脂组分的固体聚合物基材公开(公告)号：US08153261B2
公开(公告)日：2012-04-10
申请号：US11515442
申请日：2006-09-01
申请人： Shayne J. Landon , Misty Huang , Bruce A. Waldman
发明人： Shayne J. Landon , Misty Huang , Bruce A. Waldman
IPC分类号： B32B27/40
CPC分类号： C08G18/755 , C08G18/10 , C08G18/4825 , C08G2190/00 , C09D175/08 , C09J175/08 , Y10T428/31551 , Y10T428/31562 , Y10T428/31573 , Y10T428/31583 , C08G18/718
摘要： A solid polymeric substrate having a resin derived from curable silylated polyurethane composition exhibiting superior properties adhered thereto. The silylated polyurethane is prepared by reacting a polyol component with a diisocyanate component to form a hydroxyl-terminated prepolymer and endcapping the prepolymer with an isocyanate silane.
摘要翻译： 一种固体聚合物基材，其具有衍生自粘附于其上的优异性能的可固化甲硅烷基化聚氨酯组合物的树脂。 甲硅烷基化聚氨酯通过使多元醇组分与二异氰酸酯组分反应以形成羟基封端的预聚物并用异氰酸酯硅烷封端预聚物来制备。
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2.发明申请Solid polymeric substrate having adherent resin component derived from curable silylated polyurethane composition 有权具有衍生自可固化甲硅烷基化聚氨酯组合物的粘合树脂组分的固体聚合物基材公开(公告)号：US20080057316A1
公开(公告)日：2008-03-06
申请号：US11515442
申请日：2006-09-01
申请人： Shayne J. Landon , Misty Huang , Bruce A. Waldman
发明人： Shayne J. Landon , Misty Huang , Bruce A. Waldman
CPC分类号： C08G18/755 , C08G18/10 , C08G18/4825 , C08G2190/00 , C09D175/08 , C09J175/08 , Y10T428/31551 , Y10T428/31562 , Y10T428/31573 , Y10T428/31583 , C08G18/718
摘要： A solid polymeric substrate having a resin derived from curable silylated polyurethane composition exhibiting superior properties adhered thereto. The silylated polyurethane is prepared by reacting a polyol component with a diisocyanate component to form a hydroxyl-terminated prepolymer and endcapping the prepolymer with an isocyanate silane.
摘要翻译： 一种固体聚合物基材，其具有衍生自粘附于其上的优异性能的可固化甲硅烷基化聚氨酯组合物的树脂。 甲硅烷基化聚氨酯通过使多元醇组分与二异氰酸酯组分反应以形成羟基封端的预聚物并用异氰酸酯硅烷封端预聚物来制备。
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公开(公告)号：US6001946A
公开(公告)日：1999-12-14
申请号：US933122
申请日：1997-09-18
CPC分类号： C08G18/10 , C08G2190/00
摘要： Certain members of the class of N-silylalkyl-aspartic acid esters, when used to endcap polyurethane polymers, offer moisture curable, one-part sealant formulations having significantly improved physical property improvements over other members of the same class of organofunctional silanes. More specifically, polyurethane polymers terminated with either the dibutyl or diethyl maleate/primary aminoalkyl silane addition product offer sealants which substantially outperform comparative sealants obtained using polymers endcapped with other olefinic carboxylate ester (dimethyl maleate, dimethyl crotonate) or nitrile (acrylonitrile)/primary aminoalkyl silane addition products. Additionally, sealant formulations incorporating the dibutyl or diethyl maleate/primary aminoalkyl silane terminated polymers demonstrate unexpected improvements in both elongation and tensile strength performance. The dibutyl maleate and dimethyl maleate based polymers give significant increase in tear resistance.
摘要翻译： N-甲硅烷基烷基 - 天冬氨酸酯类的某些成员当用于端基聚氨酯聚合物时，提供了与同类有机官能硅烷的其它成员相比具有明显改善的物理性能改善的可湿气固化的一部分密封剂配方。 更具体地说，用二丁基或二乙基马来酸酯/伯氨基烷基硅烷加成产物封端的聚氨酯聚合物提供密封剂，其基本上优于使用与其它烯烃羧酸酯（马来酸二甲酯，巴豆酸二甲酯）或腈（丙烯腈）/伯氨基烷基 硅烷加成产物。 另外，加入马来酸二丁酯或二乙基二烷基硅烷封端的聚合物的密封剂配方在伸长率和拉伸强度性能方面都表现出意想不到的改进。 马来酸二丁酯和马来酸二甲酯基聚合物显着提高了抗撕裂性。
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4.发明授权Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same 有权低VOC产生电位的可水解硅烷和含有它的含有树脂的组合物公开(公告)号：US08088940B2
公开(公告)日：2012-01-03
申请号：US11731577
申请日：2007-03-30
CPC分类号： C07F7/1804
摘要： In accordance with the present invention, a hydrolyzable silane of low VOC-generating potential is provided which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin, the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging groups; and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C. Further in accordance with the invention, a resinous composition of low VOC-generating potential is provided which comprises: a) a resinous composition property-enhancing amount of at least one hydrolyzable silane of low VOC-generating potential which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin (b), the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging group, and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C.; and, b) at least one organic resin containing at least one group capable of reacting with organofunctional group (i) of hydrolyzable silane (a) and/or with water.
摘要翻译： 根据本发明，提供了低VOC产生电位的可水解硅烷，其具有：（i）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与 有机官能团通过稳定的桥连键合到可水解甲硅烷基的硅原子上; 和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其组合的杂原子的可水解基团，在20℃下产生蒸气压低于0.1mm Hg的化合物的水解 ℃。此外，根据本发明，提供了低VOC产生电位的树脂组合物，其包括：a）树脂组合物性质增强量的至少一种低VOC产生电位的可水解硅烷，其具有：（i ）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与有机树脂（b）相互作用的基团，有机官能团通过稳定的键合到可水解甲硅烷基的硅原子上 桥连基团，和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其梳子的杂原子的可水解基团 在20℃下产生蒸气压低于0.1mm Hg的化合物的可水解基团的水解; 和b）至少一种含有至少一个能够与可水解硅烷（a）和/或与水的有机官能团（i）反应的基团的有机树脂。
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5.发明申请Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same 有权低VOC产生电位的可水解硅烷和含有它的含有树脂的组合物公开(公告)号：US20080237537A1
公开(公告)日：2008-10-02
申请号：US11731577
申请日：2007-03-30
CPC分类号： C07F7/1804
摘要： In accordance with the present invention, a hydrolyzable silane of low VOC-generating potential is provided which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin, the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging groups; and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C. Further in accordance with the invention, a resinous composition of low VOC-generating potential is provided which comprises: a) a resinous composition property-enhancing amount of at least one hydrolyzable silane of low VOC-generating potential which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin (b), the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging group, and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C; and, b) at least one organic resin containing at least one group capable of reacting with organofunctional group (i) of hydrolyzable silane (a) and/or with water.
摘要翻译： 根据本发明，提供了低VOC产生电位的可水解硅烷，其具有：（i）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与 有机官能团通过稳定的桥连键合到可水解甲硅烷基的硅原子上; 和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其组合的杂原子的可水解基团，在20℃下产生蒸气压低于0.1mm Hg的化合物的水解 ℃。此外，根据本发明，提供了低VOC产生电位的树脂组合物，其包括：a）树脂组合物性质增强量的至少一种低VOC产生电位的可水解硅烷，其具有：（i ）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与有机树脂（b）相互作用的基团，有机官能团通过稳定的键合到可水解甲硅烷基的硅原子上 桥连基团，和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其梳子的杂原子的可水解基团 在20℃下产生蒸气压低于0.1mmHg的化合物的可水解基团的水解; 和b）至少一种含有至少一个能够与可水解硅烷（a）和/或与水的有机官能团（i）反应的基团的有机树脂。
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6.发明授权Crosslinkable silane-terminated polymer and sealant composition made with same 有权可交联的硅烷封端聚合物和密封剂组合物公开(公告)号：US07417105B2
公开(公告)日：2008-08-26
申请号：US11292045
申请日：2005-12-01
申请人： Shayne J. Landon , Bruce A. Waldman
发明人： Shayne J. Landon , Bruce A. Waldman
IPC分类号： C08L75/04
CPC分类号： C08G18/10 , C08G2190/00 , C08K5/54 , C09J175/04 , C08G18/714
摘要： A crosslinkable silane-terminated polymer is provided which includes the reaction product of an isocyanate-terminated prepolymer and a silane possessing a plurality of hydrolysable sites and at least one active hydrogen-containing group which is reactive for isocyanate, the silane upon hydrolysis produces a reduced amount of volatile organic compound compared to that produced by the hydrolysis of a silane possessing an equivalent number of hydrolyzable sites all of which are hydrolyzable alkoxy groups.
摘要翻译： 提供了一种可交联的硅烷端基聚合物，其包括异氰酸酯封端的预聚物与具有多个可水解位点的硅烷和至少一个对异氰酸酯具有反应活性的含氢基团的反应产物， 挥发性有机化合物与通过水解具有相当数量的可水解位点的硅烷产生的挥发性有机化合物的量相比，所有可水解的位点都是可水解的烷氧基。
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公开(公告)号：US06375789B1
公开(公告)日：2002-04-23
申请号：US09547527
申请日：2000-04-12
IPC分类号： C09J18300
CPC分类号： C08K5/54 , C08G18/289 , C08G18/3206 , C08G18/3225 , C08G18/718 , C08G2150/20 , Y10S524/904
摘要： Powder coating formulations include as a component thereof a silane formula I: where R1 is a hydrocarbon, acyl, alkylsilyl or alkoxysilyl group; R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent organic linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with silanes of formula I.
摘要翻译： 粉末涂料制剂包括作为其组分的硅烷式I：其中R 1是烃，酰基，烷基甲硅烷基或烷氧基甲硅烷基; R2是一价烃基; R3是亚烷基，任选被一个或多个醚氧原子间隔; a是0或1; Z是直接键或二价有机连接基团; X是m价有机基团或H; m为1-20。 硅烷可用作交联剂，特性改性剂和/或粘合促进剂。 粉末粘合剂可以类似地用式I的硅烷形成。
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8.发明授权Use of emulsified silane coupling agents as primers to improve adhesives of sealants, adhesives and coatings 有权使用乳化硅烷偶联剂作为底漆来改善密封剂，粘合剂和涂料的粘合剂公开(公告)号：US06294620B1
公开(公告)日：2001-09-25
申请号：US09524632
申请日：2000-03-14
IPC分类号： C08G1800
CPC分类号： C09K3/1021 , C08L83/16 , C09D4/00 , C09D7/00 , C09D183/06 , C09D183/08 , C09J5/02 , C09J11/06 , C09J2483/00 , C09K3/10 , C09K2200/0494 , C09K2200/0625 , C08G77/04
摘要： Emulsions comprising a water insoluble or semi-soluble silane or mixtures of such silanes have been found useful when used alone or formulated into aqueous primer systems to improve the adhesion of sealants, adhesives or coatings to a variety of substrates. These aqueous primers are suitable for both inorganic and organic substrates having either porous or non-porous surfaces. In many cases they have been found to outperform solvent based primers. Primers of this type can be used with a variety of waterborne or solvent based sealants, adhesives or coatings including acrylic or polyurethane latexes, high solid polyurethanes, epoxies and silicones. When used with waterborne systems, it is not necessary to wait for the primer to dry before application of the sealant, adhesive or coating.
摘要翻译： 已经发现包含水不溶性或半溶性硅烷或这种硅烷的混合物的乳液在单独使用或配制成水性底漆体系时可用，以改善密封剂，粘合剂或涂料对各种基材的粘合性。 这些水性底漆适用于具有多孔或无孔表面的无机和有机底物。 在许多情况下，它们被发现优于基于溶剂的引物。 这种类型的引物可用于各种水性或溶剂型密封剂，粘合剂或涂料，包括丙烯酸或聚氨酯胶乳，高固体聚氨酯，环氧树脂和硅酮。 当与水性体系一起使用时，在使用密封剂，粘合剂或涂料之前，不必等待底漆干燥。
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9.发明授权公开(公告)号：US06534568B1
公开(公告)日：2003-03-18
申请号：US09446609
申请日：2000-04-19
IPC分类号： C08K906
CPC分类号： C08K5/54 , C08G18/289 , C08G18/3206 , C08G18/3225 , C08G18/718 , C08G2150/20 , Y10S524/904
摘要： Powder coating or adhesive formulations include as a component thereof a silane of formula (I) or hydrolyzates or condensates thereof where R1 is a hydrocarbon, acyl, alkylsilyl, or alkoxysilyl group, R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with the silanes of formula (I). Fillers or pigments, such as titanium dioxide fillers, which are treated with silanes, especially silanes having alkyl, epoxy, acryl, methacryl, polyether, amino, acid anhydride, hydroxyalkyl, carbamato or ureido functionality, may also be usefully employed in powder coating formulations.
摘要翻译： 粉末涂料或粘合剂制剂包括作为其组分的式（I）的硅烷或其水解产物或缩合物，其中R 1是烃，酰基，烷基甲硅烷基或烷氧基甲硅烷基，R 2是单价烃基; R3是亚烷基，任选地被一个或多个醚氧原子间隔; a是0或1; Z是直接键或二价连接基团; X是m价有机基团或H; m为1-20。 硅烷可用作交联剂，特性改性剂和/或粘合促进剂。 粉末粘合剂可以类似地与式（I）的硅烷形成。 用硅烷处理的填料或颜料，例如二氧化钛填料，特别是具有烷基，环氧基，丙烯基，甲基丙烯酰基，聚醚，氨基，酸酐，羟基烷基，氨基甲酰基或脲基官能团的硅烷也可用于粉末涂料配方 。
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公开(公告)号：US06197912B1
公开(公告)日：2001-03-06
申请号：US09427829
申请日：1999-10-27
IPC分类号： C08G7704
CPC分类号： C08G18/10 , C08G2190/00 , C08G18/289
摘要： Moisture curable polymers having terminal or pendant silyl groups of the formula: where R1 represents an alkyl group having 1 to 10 carbon atoms, optionally interupted with one or more ether oxygen atoms, or a group of the formula R2 represents a C1 to C6 alkoxy group or a C6-C8 aryloxy group; R3 represents an alkyl or an aryl group; T represents a branched or cyclic alkylene radical of 4 to 10 carbons, which may be optionally interrupted by one or more ether oxygen atoms; X is an alkylene group of 3-10 carbon atoms, which may be linear, branched or cyclic; and a is 0, 1 or 2, may be prepared by reacting (A) a compound having at least two isocyanate groups thereon with (B) a silane of formula (3): Moisture cured sealant formulations formulated with the polymers exhibit improved thermal stability, elongation, and tear resistance.
摘要翻译： 具有下式的末端或侧甲硅烷基的水溶性聚合物：其中R 1表示具有1至10个碳原子的烷基，任选地与一个或多个醚氧原子相连，或者式R 2的基团表示C1至C6烷氧基或 C 6 -C 8芳氧基; R 3表示烷基或芳基; T表示4〜10个碳的支链或环状亚烷基，其可任选被一个或多个醚氧原子间隔; X为亚烷基3 -10个碳原子，其可以是直链，支链或环状的;和a是0,1或2，可以通过（A）具有至少两个异氰酸酯基的化合物与（B）式（3）的硅烷反应来制备 ）：用聚合物配制的水分固化密封剂配方表现出改善的热稳定性，伸长率和抗撕裂性。
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