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    Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same
    1.
    发明授权
    Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same 有权
    低VOC产生电位的可水解硅烷和含有它的含有树脂的组合物

    公开(公告)号：US08088940B2

    公开(公告)日：2012-01-03

    申请号：US11731577

    申请日：2007-03-30

    申请人： Misty W. Huang ,  Antonio Chaves ,  Bruce A. Waldman ,  Shayne J. Landon

    发明人： Misty W. Huang ,  Antonio Chaves ,  Bruce A. Waldman ,  Shayne J. Landon

    IPC分类号： C07F7/08 ,  C08L9/00

    CPC分类号： C07F7/1804

    摘要： In accordance with the present invention, a hydrolyzable silane of low VOC-generating potential is provided which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin, the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging groups; and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C. Further in accordance with the invention, a resinous composition of low VOC-generating potential is provided which comprises: a) a resinous composition property-enhancing amount of at least one hydrolyzable silane of low VOC-generating potential which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin (b), the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging group, and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C.; and, b) at least one organic resin containing at least one group capable of reacting with organofunctional group (i) of hydrolyzable silane (a) and/or with water.

    摘要翻译： 根据本发明，提供了低VOC产生电位的可水解硅烷，其具有：（i）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与 有机官能团通过稳定的桥连键合到可水解甲硅烷基的硅原子上; 和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其组合的杂原子的可水解基团，在20℃下产生蒸气压低于0.1mm Hg的化合物的水解 ℃。此外，根据本发明，提供了低VOC产生电位的树脂组合物，其包括：a）树脂组合物性质增强量的至少一种低VOC产生电位的可水解硅烷，其具有：（i ）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与有机树脂（b）相互作用的基团，有机官能团通过稳定的键合到可水解甲硅烷基的硅原子上 桥连基团，和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其梳子的杂原子的可水解基团 在20℃下产生蒸气压低于0.1mm Hg的化合物的可水解基团的水解; 和b）至少一种含有至少一个能够与可水解硅烷（a）和/或与水的有机官能团（i）反应的基团的有机树脂。

    Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same
    3.
    发明申请
    Hydrolyzable silanes of low VOC-generating potential and resinous compositions containing same 有权
    低VOC产生电位的可水解硅烷和含有它的含有树脂的组合物

    公开(公告)号：US20080237537A1

    公开(公告)日：2008-10-02

    申请号：US11731577

    申请日：2007-03-30

    申请人： Misty W. Huang ,  Antonio Chaves ,  Bruce A. Waldman ,  Shayne J. Landon

    发明人： Misty W. Huang ,  Antonio Chaves ,  Bruce A. Waldman ,  Shayne J. Landon

    IPC分类号： C08L93/00 ,  C07F7/08 ,  C07F7/10

    CPC分类号： C07F7/1804

    摘要： In accordance with the present invention, a hydrolyzable silane of low VOC-generating potential is provided which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin, the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging groups; and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C. Further in accordance with the invention, a resinous composition of low VOC-generating potential is provided which comprises: a) a resinous composition property-enhancing amount of at least one hydrolyzable silane of low VOC-generating potential which possesses: (i) at least one organofunctional group, said group being a non-bulky electron-withdrawing group and/or a group which interacts with an organic resin (b), the organofunctional group being bonded to a silicon atom of a hydrolyzable silyl group through a stable bridging group, and (ii) at least one hydrolyzable group bonded to silicon and containing at least two heteroatoms selected from the group consisting of oxygen, nitrogen and their combinations, hydrolysis of the hydrolyzable group generating a compound having a vapor pressure lower than 0.1 mm Hg at 20° C; and, b) at least one organic resin containing at least one group capable of reacting with organofunctional group (i) of hydrolyzable silane (a) and/or with water.

    摘要翻译： 根据本发明，提供了低VOC产生电位的可水解硅烷，其具有：（i）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与 有机官能团通过稳定的桥连键合到可水解甲硅烷基的硅原子上; 和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其组合的杂原子的可水解基团，在20℃下产生蒸气压低于0.1mm Hg的化合物的水解 ℃。此外，根据本发明，提供了低VOC产生电位的树脂组合物，其包括：a）树脂组合物性质增强量的至少一种低VOC产生电位的可水解硅烷，其具有：（i ）至少一个有机官能团，所述基团是非大体积的吸电子基团和/或与有机树脂（b）相互作用的基团，有机官能团通过稳定的键合到可水解甲硅烷基的硅原子上 桥连基团，和（ii）至少一个与硅键合并且含有至少两个选自氧，氮及其梳子的杂原子的可水解基团 在20℃下产生蒸气压低于0.1mmHg的化合物的可水解基团的水解; 和b）至少一种含有至少一个能够与可水解硅烷（a）和/或与水的有机官能团（i）反应的基团的有机树脂。

    Latex sealants containing epoxysilanes
    6.
    发明授权
    Latex sealants containing epoxysilanes 有权
    含有环氧硅烷的胶乳密封剂

    公开(公告)号：US6001907A

    公开(公告)日：1999-12-14

    申请号：US209141

    申请日：1998-12-10

    申请人： Misty W. Huang

    发明人： Misty W. Huang

    IPC分类号： C08K5/5435 ,  C09D133/06 ,  C09J183/12 ,  C09K3/10 ,  C08J5/15

    CPC分类号： C09K3/10 ,  C08K5/5435 ,  C09D133/06 ,  C08L2201/52 ,  C09K2200/0494 ,  C09K2200/0625

    摘要： Sealant compositions comprising a latex polymer and an epoxysilane of the formula ##STR1## in which R.sup.1 is a difunctional alkyl bridge with 2 to 6 carbon atoms,each R.sup.2 group is the same or different and each is a C.sub.1 to C.sub.12 alkyl or aryl group, or a C.sub.1 to C.sub.6 alkoxy groupeach R.sup.3 group is the same or different and each is a C.sub.2 to C.sub.6 alkyl group,n is 2 or 1,R.sup.4, R.sup.5, and R.sup.6 are each hydrogen or a C.sub.1 to C.sub.6 alkyl group,R.sup.7 is an alkyl group having from one to four carbon atoms, or aralkyl, or an aryl group having six to ten carbon atoms, andc has a value of zero or one;wherein the epoxysilane is added to the polymer neat or as a non-aqueous solution.

    摘要翻译： 包含胶乳聚合物和下式的环氧硅烷的密封剂组合物，其中R 1是具有2至6个碳原子的双官能烷基桥，每个R 2基团相同或不同，并且各自为C 1至C 12烷基或芳基，或C 1 至C6烷氧基，每个R 3基团相同或不同，并且各自为C 2至C 6烷基，n为2或1，R 4，R 5和R 6各自为氢或C 1至C 6烷基，R 7为烷基 具有1至4个碳原子，或芳烷基或具有6至10个碳原子的芳基，c具有0或1的值; 其中将环氧硅烷全部或非水溶液加入到聚合物中。