公开(公告)号：US4513129A

公开(公告)日：1985-04-23

申请号：US601432

申请日：1984-04-18

申请人： Shinichi Nakagawa ,  Kiyohiko Ihara ,  Toshio Sogabe

发明人： Shinichi Nakagawa ,  Kiyohiko Ihara ,  Toshio Sogabe

IPC分类号： C08F210/00 ,  C08F10/00 ,  C08F14/00 ,  C08F14/24 ,  C08F210/02 ,  C08F214/00 ,  C08F214/24 ,  C08F214/26 ,  C08F12/20

CPC分类号： C08F214/265 ,  C08F210/02 ,  C08F214/24

摘要： A copolymer comprising monomeric units derived from ethylene, tetrafluoroethylene or chlorotrifluoroethylene and a fluorovinyl compound of the formula:CH.sub.2 .dbd.CFRf (I)wherein Rf is a C.sub.2 -C.sub.10 fluoroalkyl group, a molar ratio of ethylene and tetrafluoroethylene or chlorotrifluoroethylene being from 40:60 to 60:40 and the content of the fluorovinyl compound being from 0.1% to 10% by mole having improved thermal resistance and high temperature mechanical properties such as crack resistance.

摘要翻译： 一种共聚物，其包含衍生自乙烯，四氟乙烯或氯三氟乙烯的单体单元和下式的氟代乙烯基化合物：CH2 = CFRf（I）其中Rf是C2-C10氟代烷基，乙烯和四氟乙烯或氯三氟乙烯的摩尔比为40:60 至60:40，并且氟乙烯基化合物的含量为0.1％至10％摩尔，具有改进的耐热性和耐高温机械性能如抗裂性。

公开(公告)号：US06921797B2

公开(公告)日：2005-07-26

申请号：US10759282

申请日：2004-01-20

申请人： Yoshiyuki Tanaka ,  Masanori Kitaichi ,  Tomizo Sota ,  Tatsuya Morikawa ,  Toshio Sogabe ,  Mitsuru Kishine

发明人： Yoshiyuki Tanaka ,  Masanori Kitaichi ,  Tomizo Sota ,  Tatsuya Morikawa ,  Toshio Sogabe ,  Mitsuru Kishine

IPC分类号： C08F2/00 ,  C08F6/16 ,  C08F6/22 ,  C08F14/18 ,  C08F214/18 ,  C08F214/22 ,  C08F214/26 ,  C08F114/18

CPC分类号： C08F214/18 ,  C08F6/16 ,  C08F6/22 ,  C08F14/18 ,  C08F214/22 ,  C08F214/26 ,  C08F2/22 ,  C08L27/12

摘要： To provide a method of reducing contents of metal components of a fluorine-containing elastomer through preparation thereof and a molded article obtained from the fluorine-containing elastomer having sufficiently reduced contents of metal components. The method of reducing a metal content of the fluorine-containing elastomer through preparation thereof without using a metal oxide, in which among materials excluding a gaseous monomer which are used for polymerization of a fluorine-containing monomer, coagulation and drying, at least one of them contains substantially no metal component, and the fluorine-containing elastomer which has a metal content of not more than 50 ppm and is obtained by that method.

摘要翻译： 提供通过其制备减少含氟弹性体的金属成分含量的方法和由具有足够降低的金属成分含量的含氟弹性体得到的成型体。 通过其制备而不使用金属氧化物来降低含氟弹性体的金属含量的方法，其中除了用于含氟单体聚合的气态单体的物质，凝结和干燥之外的材料中，至少一种 它们基本上不含有金属成分，并且含有金属含量不超过50ppm并通过该方法获得的含氟弹性体。

公开(公告)号：US06703461B1

公开(公告)日：2004-03-09

申请号：US09646969

申请日：2000-09-25

申请人： Yoshiyuki Tanaka ,  Masanori Kitaichi ,  Tomizo Sota ,  Tatsuya Morikawa ,  Toshio Sogabe ,  Mitsuru Kishine

发明人： Yoshiyuki Tanaka ,  Masanori Kitaichi ,  Tomizo Sota ,  Tatsuya Morikawa ,  Toshio Sogabe ,  Mitsuru Kishine

IPC分类号： C08F11418

CPC分类号： C08F214/18 ,  C08F6/16 ,  C08F6/22 ,  C08F14/18 ,  C08F214/22 ,  C08F214/26 ,  C08F2/22 ,  C08L27/12

摘要： To provide a method of reducing contents of metal components of a fluorine-containing elastomer through preparation thereof and a molded article obtained from the fluorine-containing elastomer having sufficiently reduced contents of metal components. The method of reducing a metal content of the fluorine-containing elastomer through preparation thereof without using a metal oxide, in which among materials excluding a gaseous monomer which are used for polymerization of a fluorine-containing monomer, coagulation and drying, at least one of them contains substantially no metal component, and the fluorine-containing elastomer which has a metal content of not more than 50 ppm and is obtained by that method.

摘要翻译： 提供通过其制备减少含氟弹性体的金属成分含量的方法和由具有足够降低的金属成分含量的含氟弹性体得到的成型体。 通过其制备而不使用金属氧化物来降低含氟弹性体的金属含量的方法，其中除了用于含氟单体聚合的气态单体的物质，凝结和干燥之外的材料中，至少一种 它们基本上不含有金属成分，并且含有金属含量不超过50ppm并通过该方法获得的含氟弹性体。

公开(公告)号：US06642307B1

公开(公告)日：2003-11-04

申请号：US09807377

申请日：2001-04-12

申请人： Toshio Sogabe ,  Tatsuya Morikawa ,  Yoshiyuki Tanaka ,  Masanori Kitaichi ,  Mitsuru Kishine

发明人： Toshio Sogabe ,  Tatsuya Morikawa ,  Yoshiyuki Tanaka ,  Masanori Kitaichi ,  Mitsuru Kishine

IPC分类号： C08L2712

CPC分类号： C08F214/262 ,  C08F14/18 ,  C08F16/24 ,  C08F214/184 ,  C08F2/16

摘要： In the emulsion obtained by forcedly emulsifying by applying a high shearing force on the water insoluble liquid in the presence of a small amount of emulsifying agent, at least one of fluorine-containing monomers being in the form of gas at ordinary temperature at atmospheric pressure is emulsion-polymerized stably and efficiently. An amount of the emulsifying agent is an amount which does not change the number of water insoluble liquid particles in the emulsion during the polymerization.

摘要翻译： 在通过在少量乳化剂的存在下对水不溶性液体施加高剪切力强制乳化而得到的乳液中，常压常压下的气体形式的至少一种含氟单体为 乳液聚合稳定有效。 乳化剂的量是在聚合过程中不改变乳液中的水不溶性液体颗粒数量的量。