公开(公告)号：US06710199B2

公开(公告)日：2004-03-23

申请号：US10157495

申请日：2002-05-30

申请人： Shinji Tsuyutani ,  Kengo Shibata ,  Kazunori Aizawa ,  Masaru Sakata ,  Mitsugu Morishita

发明人： Shinji Tsuyutani ,  Kengo Shibata ,  Kazunori Aizawa ,  Masaru Sakata ,  Mitsugu Morishita

IPC分类号： C07F909

CPC分类号： C07F9/025

摘要： A process for preparing a phosphoric ester having reduced odor, comprising contacting a phosphoric ester with at least one of an inert gas and steam at 100° to 160° C. in a packed tower; a process for preparing a phosphoric ester having reduced odor, comprising repeating a set of processes comprising (A) heating a phosphoric ester, and contacting the heated phosphoric ester with at least one of an inert gas and steam; and (B) cooling the phosphoric ester obtained in the step (A); a process for preparing a phosphoric ester having reduced odor, comprising adding water to a phosphoric ester, and distilling water from the phosphoric ester under reduced pressure; and a process for preparing a phosphoric ester having reduced odor, comprising reacting an organic hydroxy compound with a phosphorylation agent, while introducing an inert gas into the mixture of the organic hydroxy compound and the phosphorylation agent. The phosphoric ester is useful for, for instance, a shampoo, a cleaning agent, a facial cleansing agent, an emulsifier, and the like.

摘要翻译： 一种制备具有减少气味的磷酸酯的方法，包括使磷酸酯与惰性气体中的至少一种和蒸汽在100℃至160℃下在填料塔中接触; 一种制备具有减少气味的磷酸酯的方法，包括重复一系列方法，包括（A）加热磷酸酯，并使加热的磷酸酯与惰性气体和蒸汽中的至少一种接触; 和（B）冷却步骤（A）中获得的磷酸酯; 一种制备具有减少气味的磷酸酯的方法，包括向磷酸酯中加入水，并在减压下从磷酸酯中蒸馏出水; 以及制备具有减少气味的磷酸酯的方法，包括使有机羟基化合物与磷酸化剂反应，同时将惰性气体引入有机羟基化合物和磷酸化剂的混合物中。 磷酸酯可用于例如洗发剂，清洁剂，面部清洁剂，乳化剂等。

公开(公告)号：US5883280A

公开(公告)日：1999-03-16

申请号：US793805

申请日：1997-03-20

申请人： Shinji Tsuyutani ,  Kengo Shibata ,  Kiyoshi Aimono

发明人： Shinji Tsuyutani ,  Kengo Shibata ,  Kiyoshi Aimono

IPC分类号： C07F9/02 ,  C07F9/09 ,  C07F9/11

CPC分类号： C07F9/11 ,  C07F9/025 ,  C07F9/09 ,  C07F9/091

摘要： An organic hydroxyl compound is reacted with polyphosphoric acid under such conditions that the ratio, as defined by formula (1), has a value exceeding 3.2; and phosphorus pentaoxide is added to the reaction product thus obtained in such an amount that the ratio, as defined by formula (1), has a value in the range of from 2.8 to 3.2: ##EQU1## If necessary, the obtained reaction product is deodorized by the removal of the organic hydroxyl compound unreacted therefrom. The process does not give any product of high-viscous gel and therefore enables the industrially easy manufacture of a phosphoric monoester having an extremely high purity, a lowered orthophosphoric acid content, and a good odor.

摘要翻译： PCT No.PCT / JP95 / 01890 Sec。 371日期1997年3月20日 102（e）1997年3月20日PCT PCT 1995年9月20日PCT公布。 公开号WO96 / 09305 日期1997年3月28日在有机羟基化合物与多磷酸反应的条件下，如式（1）所定义的比值超过3.2; 向由此获得的反应产物中加入五氧化二磷，其量使得由式（1）定义的比值在2.8至3.2的范围内。（1）如果需要， 通过除去未反应的有机羟基化合物对反应产物进行除臭。 该方法不给出任何高粘度凝胶产物，因此能够在工业上容易地制造具有极高纯度，降低的正磷酸含量和良好气味的磷酸单酯。

公开(公告)号：US06673885B1

公开(公告)日：2004-01-06

申请号：US10049521

申请日：2002-04-15

申请人： Kengo Shibata ,  Haruya Minou ,  Haruyuki Sato ,  Toshinao Ukena ,  Yoshinao Kono

发明人： Kengo Shibata ,  Haruya Minou ,  Haruyuki Sato ,  Toshinao Ukena ,  Yoshinao Kono

IPC分类号： C08F2010

CPC分类号： C08G65/3322 ,  C04B24/2647 ,  C04B2103/408 ,  C08F220/04 ,  C08F220/28 ,  C08F265/04 ,  C08F283/06 ,  C08F290/06 ,  Y10S526/932 ,  C08F220/06

摘要： Disclosed in the present invention is a process for preparing a (meth)acrylic acid-based polymer having a stable quality and suitable as a dispersant for cement. That is, the present invention provides a process for preparing a (meth)acrylic acid-based polymer, comprising the steps of the stage 1 of introducing (meth)acrylic acid and a polyalkylene glycol monoalkyl ether at a molar ratio in the range of 3:l to 50:1, subjecting them to an esterification reaction in the presence of an acid catalyst and a polymerization inhibitor and deactivating the acid catalyst with an alkaline agent in order to obtain an esterification product containing a (meth)acrylate and (meth)acrylic acid residues and the stage 2 of copolymerizing the (meth)acrylate and the (meth)acrylic acid residues at a pH value in the range of 1.5 to 3.5.

摘要翻译： 在本发明中公开了一种制备具有稳定质量并适合作为水泥分散剂的（甲基）丙烯酸类聚合物的方法。 也就是说，本发明提供了制备（甲基）丙烯酸类聚合物的方法，包括以下步骤：将摩尔比为3的导入（甲基）丙烯酸和聚亚烷基二醇单烷基醚的步骤1 ：1〜50:1，在酸催化剂和阻聚剂的存在下进行酯化反应，并用碱性试剂使酸催化剂失活，得到含有（甲基）丙烯酸酯和（甲基）丙烯酸酯的酯化产物， 丙烯酸残基和使（甲基）丙烯酸残基在1.5至3.5的范围内共聚的阶段2。